File name: Pandora125s1_Cordoba_20200523_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142857.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200523_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200523T114554.0Z 7448.490209 249 1 50.06 2 82.51 59.97 90.41 65.26 0.00 1 0.00 1 0 25 5.138e-01 3.168e-02 3.568e-01 1.858e-02 7.583588e-01 1.046404e-02 7.519527e-03 -6.000000e+00 2.924700e-01 224.82 -2.00 3.11 -2.00 322.22 0.00e+00 1.022960e-04 5.668253e-03 3.121101e-03 -6.000000e+00 1.374591e-02 284.03 -2.00 20.00 -2.00 321.72 0.00e+00 7.115 0.003 302.00 328.00 3 7.6765e-02 4.1086e-02 7.8796e-02 -6.0000e+00 7.2595e-01 1.1153e+00 5.1384e-02 4.3345e-02 -6.0000e+00 7.9543e-01 -1.4214e+00 3.6033e-02 1.9344e-02 -6.0000e+00 4.7107e-01 5.5891e-01 1.7513e-02 5.6087e-03 -6.0000e+00 2.0062e-01 2.2497e-04 -1.6032e-03 5.4599e-04 7.8476e-05 -6.0000e+00 1.3763e-02 3.5204e-03 0.0000e+00 12 8 8 10 0 0 53.62 20.97 0.56 0.00352 -0.00853 119 24 1 5 0 420.607 26.62 19.99 20.97 900000 -66469 2560 -25961 121237 -34379 286512 -94949 -16314 -78441 900000 -67228 110629 55804 -64327 96683 8808 900000 32960 900000 13251 900000 3162 117508 -23261 103902 12381 -39429 14004 -46532 900000 -25045 186200 6612 900000 26908 102657 74425 31700 23935 55121 127358 51006 25164 58382 73839 37858 156873 22290 116490 87128 25807 16971 50188 3998 67668 25322 2849 23136 15944 20762 -6597 81296 6626 49500 12353 21121 -1417 29571 14039 24280 16894 8229 24001 -1701 14124 -20118 21787 -12787 19324 -4845 17027 -5783 2983 1826 4267 2268 -1039 223 -8866 12903 -9626 4160 -12778 5217 -8406 2188 -739 -111 -3398 -2062 -5277 -9332 -2971 -8407 -505 -4804 3797 -6325 3106 -1974 1906 -180 -127 598 -882 -891 -3147 1405 -1506 3158 353 4346 1116 4885 1435 1973 -1607 2486 681 909 1546 -613 -190 -1664 1874 -1225 1594 -820 1469 -1304 -129 -2590 900000 -4897 94 -1158 2194 -1155 5185 -5768 -492 -4469 900000 -3289 2002 1085 -4915 1750 396 900000 1215 900000 560 900000 134 2126 -1376 1880 500 -2442 458 -2720 900000 -1595 3369 369 900000 1032 1858 1993 1537 1534 2868 3361 2923 1840 2949 3118 2255 2839 1580 3483 3770 2274 1762 3988 528 4845 2809 388 2531 1757 2135 -944 5416 1052 5497 1951 2953 -252 4357 2770 4791 3741 1957 4550 -375 2337 -4265 3174 -2904 3794 -1434 4668 -2213 1109 727 1760 1001 -513 108 -4560 4977 -4337 1569 -5866 2251 -4876 1336 -569 -94 -3061 -1731 -4095 -6746 -1980 -6364 -377 -3941 3073 -6625 3379 -2561 2582 -255 -176 787 -1128 -1143 -4328 1962 -2264 4769 524 5952 1536 6260 1842 2428 -2131 3627 1167 1733 3157 -1353 -446 -4258 5219 -3592 4602 -2419 4063 -3448 -312 -6152 SS 20200523T115617.1Z 7448.497420 252 1 50.13 2 80.62 58.44 88.50 63.91 0.00 1 0.00 1 0 25 4.246e-01 1.421e-02 2.569e-01 7.411e-03 6.560120e-01 4.015677e-03 6.513866e-03 -6.000000e+00 2.376868e-01 224.82 -2.00 3.11 -2.00 321.93 0.00e+00 4.770046e-03 2.291549e-03 1.311095e-03 -6.000000e+00 1.079500e-02 284.03 -2.00 20.00 -2.00 321.39 0.00e+00 5.837 0.002 302.00 328.00 3 8.6966e-02 1.5610e-02 6.4852e-02 -6.0000e+00 5.8584e-01 4.2077e-01 2.1654e-02 3.6291e-02 -6.0000e+00 6.3768e-01 -4.9408e-01 2.0382e-02 1.6839e-02 -6.0000e+00 3.8054e-01 1.8783e-01 9.3755e-03 7.1863e-03 -6.0000e+00 1.6288e-01 8.6329e-04 -1.5975e-03 2.1895e-04 7.7502e-05 -6.0000e+00 1.0990e-02 3.2183e-03 0.0000e+00 12 8 8 10 0 0 28.94 20.97 0.39 0.00322 -0.00879 258 51 1 5 0 194.276 26.62 19.99 20.97 18008 -195944 -8574 -148218 -87598 900000 -187082 -108301 -131963 -36384 -165444 -125914 -157018 -36322 -91049 52330 -62744 2095 -31892 5454 -27456 -42605 -50371 -59330 -2016 -43107 24547 -23889 -47669 -20778 1717 24751 15157 -9913 -6268 7528 -20350 24361 -2068 30675 6514 514 13594 19325 17543 25866 4999 11723 27691 16918 23499 16517 13773 19633 23873 15837 22486 7952 17151 12593 3366 11716 7141 12937 12711 2658 2896 6509 3587 6863 2462 4577 4476 4387 -419 1349 2806 916 -3422 -2651 2211 -1745 1662 -3744 -1373 -1349 -327 -884 519 14 651 -1391 -3626 -1530 -3217 -637 -540 -548 -1658 296 -1183 -1812 -1517 -978 -1609 -1645 790 -1642 -943 -1133 764 -527 264 -688 -88 576 904 527 -914 180 53 247 417 819 1079 1228 1452 652 661 930 710 462 -68 74 -408 -289 -73 219 -8 325 -20 -516 -1047 130 -5554 -62 -2801 -803 900000 -4211 -1204 -2054 -263 -4065 -2184 -4493 -399 -2184 378 -1560 30 -682 84 -595 -1047 -1325 -1876 -38 -1285 377 -575 -1392 -475 36 499 410 -380 -224 220 -818 719 -96 1234 379 34 829 1193 1106 1521 368 824 1719 1228 1744 1470 1380 2101 2596 1929 2631 1073 2036 1512 447 1548 1120 2286 2429 553 581 1272 779 1664 697 1336 1304 1211 -117 329 616 203 -867 -792 743 -701 715 -1802 -685 -719 -192 -541 314 8 356 -721 -1827 -763 -1812 -406 -400 -468 -1681 300 -1148 -1589 -1194 -756 -1347 -1468 723 -1647 -1025 -1389 1028 -769 410 -1046 -125 778 1216 744 -1392 284 83 375 647 1228 1552 1700 1925 897 1026 1640 1384 963 -149 171 -1025 -764 -196 600 -22 859 -54 -1292 -2533 SS 20200523T120621.0Z 7448.504410 257 1 50.03 2 78.81 56.91 86.66 62.56 0.00 1 0.00 1 0 25 3.179e-01 9.490e-03 1.594e-01 3.972e-03 5.683904e-01 2.126419e-03 5.713822e-03 -6.000000e+00 1.772339e-01 224.82 -2.00 3.11 -2.00 321.52 0.00e+00 8.775985e-04 1.089284e-03 6.085710e-04 -6.000000e+00 8.065684e-03 284.03 -2.00 20.00 -2.00 320.94 0.00e+00 4.974 0.001 302.00 328.00 3 1.1008e-01 7.6734e-03 5.4588e-02 -6.0000e+00 4.3733e-01 1.8216e-01 1.0417e-02 2.7749e-02 -6.0000e+00 4.7597e-01 -1.9433e-01 1.0053e-02 1.4060e-02 -6.0000e+00 2.8470e-01 6.7868e-02 4.7591e-03 4.4110e-03 -6.0000e+00 1.2237e-01 2.1380e-03 -1.0256e-03 1.2072e-04 5.4618e-05 -6.0000e+00 8.3035e-03 3.1074e-03 0.0000e+00 12 8 8 10 0 0 57.49 20.96 0.31 0.00311 -0.00460 411 82 1 5 0 121.711 26.62 19.99 20.96 -80279 -147309 -133649 900000 -43730 -142822 -38514 -96989 -15410 -95091 -34630 -107015 -56248 -98123 -12155 -23449 -50791 12201 -20661 -11508 -36002 -36668 20033 1347 -33572 20857 -46661 2141 -39644 -31866 -84680 -22546 9869 -10694 -949 7506 6855 -986 8726 -2085 17519 4236 4203 7977 1443 5223 9794 1733 3892 8923 5751 6431 2588 4006 8433 6606 3443 3899 361 4264 2450 1746 4452 5145 5124 1350 2498 -116 1365 1508 2225 1970 1878 659 2465 -2191 -127 505 281 -1049 383 -249 -2201 -838 -1282 541 -199 62 -283 -34 872 482 -348 -1740 515 -542 -517 -164 -144 -663 638 -1768 -937 -54 -515 -1575 -1642 -1336 -264 -130 355 207 -369 736 -248 182 126 -140 373 -259 -450 129 704 85 1116 756 549 614 1127 384 692 -301 430 -154 -333 -412 -382 447 209 57 -100 -176 -708 -547 -2350 -2029 900000 -244 -1991 -205 -1049 -85 -1273 -263 -1761 -663 -2201 -143 -371 -1188 165 -420 -225 -970 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