File name: Pandora125s1_Cordoba_20200622_L2Fit_fout2c3d20170323p1-8.txt File generation date: 20250228T141414.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200622_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200622 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 214 355 Nominal wavelengths inside fitting window [nm]: 305.0972 305.2384 305.3797 305.5210 305.6622 305.8035 305.9447 306.0859 306.2272 306.3684 306.5095 306.6507 306.7919 306.9330 307.0742 307.2153 307.3564 307.4975 307.6386 307.7797 307.9208 308.0619 308.2029 308.3439 308.4850 308.6260 308.7670 308.9080 309.0490 309.1899 309.3309 309.4719 309.6128 309.7537 309.8946 310.0355 310.1764 310.3173 310.4582 310.5990 310.7399 310.8807 311.0215 311.1624 311.3032 311.4439 311.5847 311.7255 311.8662 312.0070 312.1477 312.2884 312.4291 312.5698 312.7105 312.8512 312.9919 313.1325 313.2732 313.4138 313.5544 313.6950 313.8356 313.9762 314.1168 314.2573 314.3979 314.5384 314.6789 314.8194 314.9599 315.1004 315.2409 315.3814 315.5218 315.6623 315.8027 315.9431 316.0835 316.2239 316.3643 316.5047 316.6451 316.7854 316.9257 317.0661 317.2064 317.3467 317.4870 317.6273 317.7675 317.9078 318.0481 318.1883 318.3285 318.4687 318.6089 318.7491 318.8893 319.0295 319.1696 319.3098 319.4499 319.5900 319.7301 319.8702 320.0103 320.1504 320.2904 320.4305 320.5705 320.7105 320.8505 320.9905 321.1305 321.2705 321.4105 321.5504 321.6904 321.8303 321.9702 322.1101 322.2500 322.3899 322.5298 322.6697 322.8095 322.9494 323.0892 323.2290 323.3688 323.5086 323.6484 323.7881 323.9279 324.0676 324.2074 324.3471 324.4868 324.6265 324.7662 324.9058 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200622T113004.0Z 7478.479213 40 1 50.00 2 88.06 60.76 101.58 68.22 0.00 1 0.00 1 0 41 2.586e-01 1.665e-01 9.906e-02 6.612e-02 9.945464e-02 3.493568e-02 2.990353e-04 -6.000000e+00 1.450036e-01 224.72 -2.00 3.11 -2.00 311.79 0.00e+00 2.807977e-03 1.767626e-03 1.526008e-04 -6.000000e+00 6.455183e-03 282.71 -2.00 20.00 -2.00 311.53 0.00e+00 16.238 0.035 302.00 328.00 3 -7.7332e+00 8.6436e-02 1.5836e-01 -6.0000e+00 3.5795e-01 2.1090e+00 9.4427e-02 1.6903e-02 -6.0000e+00 3.8911e-01 -2.6797e-01 5.6165e-02 1.2642e-03 -6.0000e+00 2.3225e-01 5.6920e-02 2.4447e-02 1.5164e-03 -6.0000e+00 1.0067e-01 2.2378e-04 -1.4202e-03 1.7256e-03 1.5359e-05 -6.0000e+00 6.7323e-03 -2.9925e-03 0.0000e+00 12 8 8 10 0 0 73.71 21.04 1.55 -0.00299 -0.01366 46 9 1 5 0 1086.758 26.73 20.01 21.04 46882 31290 44205 5381 -7738 -43511 18192 -21712 8150 -13662 -7600 -25663 47 1740 17309 12984 1540 29875 404 12172 3476 9653 1720 14300 -4165 1451 4597 1060 -21307 220806 -6327 -28931 -9691 -27660 -22855 -28913 -15271 -11568 32480 14013 37269 13992 30218 23667 14415 43849 -903 18517 -4727 4535 -10677 23368 -8971 8296 4328 7472 2272 6496 8090 -4746 14012 6249 17006 205 6517 -20122 -14738 -24295 -1322 -1320 17608 13330 20687 20048 -10082 -7745 -37586 -32594 -36340 -4788 -27058 126 -2945 9071 6463 15860 14872 20030 39143 10623 8498 -5903 -8497 -33127 -1381 -24140 6106 11925 17786 3224 -5539 -5639 -8948 11037 -6834 20805 2380 16275 6230 32106 17053 22498 7053 13168 -14224 -13382 -2548 -4821 15551 3233 13422 -9789 11976 -10715 2680 -20207 -11707 -21580 -8449 -6305 -6647 -2553 -1920 3441 -3425 17396 -4759 13111 12262 5502 -4221 466 30644 24393 29027 4558 -6322 -47163 11225 -21595 6317 -12855 -6206 -24697 38 1538 14097 11330 1477 21420 389 10488 3203 8167 1552 11500 -4055 1324 3860 855 -19476 17154 -4852 -28645 -8169 -27404 -19270 -25407 -12824 -10793 22591 13282 29026 13871 25535 21030 13788 31251 -950 15054 -4562 3906 -11051 18336 -9931 7839 4225 7033 2230 6121 7301 -4869 12354 6327 16251 234 6684 -23545 -14741 -26008 -1221 -1354 16247 12997 18295 16923 -10440 -7087 -41191 -32264 -39598 -4212 -32354 126 -3133 8908 6972 16495 16203 20918 34196 11524 8463 -5997 -7971 -39029 -1300 -30958 6298 12465 17649 3481 -6203 -5857 -9529 10330 -8191 19572 2885 17594 7707 31762 19787 23708 7975 13073 -16835 -15010 -2615 -5358 15238 3769 14782 -13226 12482 -13154 2706 -23936 -12138 -26371 -9520 -7193 -7695 -2819 -2131 3771 -4234 18759 -6512 15175 14121 6545 -5331 542 SS 20200622T113317.0Z 7478.481447 44 1 8.03 2 87.46 60.33 100.97 67.86 0.00 1 0.00 1 7 257 2.327e-01 2.174e-01 1.058e-01 9.834e-02 1.566964e-01 5.160391e-02 2.019123e-03 -6.000000e+00 1.304287e-01 224.72 -2.00 3.11 -2.00 311.80 0.00e+00 -9.105739e-04 2.660961e-03 3.427965e-04 -6.000000e+00 5.808547e-03 282.71 -2.00 20.00 -2.00 311.54 0.00e+00 14.677 0.026 302.00 328.00 3 -6.3179e+00 1.2764e-01 1.4209e-01 -6.0000e+00 3.2197e-01 2.0738e+00 1.4071e-01 1.4875e-02 -6.0000e+00 3.5004e-01 -3.2044e-01 8.2946e-02 3.1710e-03 -6.0000e+00 2.0893e-01 9.7396e-02 3.5579e-02 2.0422e-03 -6.0000e+00 9.0516e-02 2.0583e-04 -6.2716e-03 2.5057e-03 4.8989e-05 -6.0000e+00 6.0585e-03 0.0000e+00 0.0000e+00 12 11 11 12 9 1 33.27 21.05 0.35 0.00000 -0.04713 5 8 1 5 0 1291.239 26.73 20.00 21.05 32962 62979 10882 21601 -27011 -12394 -11242 6363 -17118 17288 -23647 -12644 -23465 -6080 23726 4654 13240 19064 39482 1414 53302 -6851 19061 3810 46092 12859 34876 -19538 -2484 -23781 -25075 1822 -25209 -4066 -52761 -2426 -23024 14538 -21942 27031 24581 29804 44728 28229 23319 26702 10916 -18777 13972 -16499 40965 -13870 14995 -5549 40444 -4996 2873 1060 6500 -5848 -3487 25299 3187 41782 3208 6331 -8802 14066 -20023 16003 23213 24162 770 2030 6832 -27173 -16205 -56613 -29109 -32744 11678 -12551 18838 -10287 34184 9480 26316 32257 25418 29037 5695 4661 -25974 9441 -28316 20182 -18008 44435 4114 18189 -11131 -6611 -7389 2111 25079 13956 9977 15210 47591 -3891 54635 14909 31633 -15612 16303 -17826 -11923 -4688 2067 195 14892 21710 -20128 14080 -28730 6144 -31327 268 -24178 -8299 5472 -25293 -600 871 27537 4378 35197 11496 29537 13672 19767 -14421 23705 35293 9947 15742 -26705 -9639 -8863 4715 -17346 12545 -24117 -11077 -24187 -5684 17735 4371 11455 15304 25708 1347 30544 -6676 14534 3479 28201 11009 23572 -19983 -1952 -21690 -23398 1334 -25115 -3305 -60338 -1634 -20531 10246 -26194 22928 22482 26086 33650 24500 20640 22841 10357 -22553 11388 -17694 26115 -15539 13251 -6169 28404 -5515 2918 1096 6111 -6106 -3631 20956 3489 32966 3542 5967 -8657 10790 -22326 14352 20621 21669 853 2113 6392 -31424 -14879 -72543 -29434 -38056 9833 -14479 16426 -12361 28066 10567 26617 31129 25865 26854 6025 4588 -31048 7634 -35115 16707 -23771 35261 5006 18223 -13654 -7060 -7671 2190 22330 14386 11069 16460 40056 -5517 45790 18107 30220 -21567 14706 -21208 -13938 -5326 2355 239 15872 21057 -28578 13879 -40771 5750 -40131 254 -30879 -9814 5750 -35974 -669 988 25193 5195 32428 13563 28691 14933 19448 -19118 SS 20200622T124155.2Z 7478.529111 72 1 2.33 2 75.47 50.01 88.38 59.57 0.00 1 0.00 1 0 25 3.122e-01 1.061e-02 1.811e-01 7.915e-03 4.585841e-01 4.044923e-03 4.697385e-03 -6.000000e+00 1.744863e-01 224.73 -2.00 3.11 -2.00 320.33 0.00e+00 1.212893e-03 1.424182e-03 6.861124e-04 -6.000000e+00 7.787260e-03 282.71 -2.00 20.00 -2.00 319.67 0.00e+00 3.903 0.000 302.00 328.00 3 -5.7929e-02 1.2222e-02 4.2812e-02 -6.0000e+00 4.3067e-01 8.8197e-02 1.4970e-02 2.1124e-02 -6.0000e+00 4.6877e-01 -8.0693e-02 1.2857e-02 1.0945e-02 -6.0000e+00 2.7981e-01 2.5669e-02 6.5763e-03 3.5238e-03 -6.0000e+00 1.2075e-01 7.7251e-03 7.1539e-04 2.3044e-04 3.9661e-05 -6.0000e+00 8.1396e-03 2.3194e-02 0.0000e+00 12 9 9 12 1 1 75.29 21.06 0.24 0.02319 0.02857 13 64 1 5 0 154.438 26.73 19.99 21.06 -41418 44218 -69759 -81628 -156 -119217 296246 -53763 -16862 -52983 16411 -10758 -32232 -12481 -27712 -9228 -28189 11264 -23047 30879 -29786 14265 -21997 12876 -9710 6082 -8385 9661 -20523 -2075 7892 -5071 11866 -9396 7135 -7518 14348 -7064 4624 -1193 3477 2879 4162 -682 1707 5147 -2018 714 4794 7728 -1335 7018 -3807 3442 -2276 1292 -1106 999 2082 2129 573 1332 3762 2278 4844 -667 3685 -1464 1359 -875 218 158 2352 605 -584 2463 -1203 2230 112 2571 -2012 -1745 -1608 -252 -1283 -996 -1251 -572 791 -324 997 -399 1025 -2478 340 -821 193 -1212 410 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