File name: Pandora125s1_Cordoba_20200918_L2Fit_fout2c3d20170323p1-8.txt File generation date: 20250228T141429.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200918_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200918 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 214 355 Nominal wavelengths inside fitting window [nm]: 305.0972 305.2384 305.3797 305.5210 305.6622 305.8035 305.9447 306.0859 306.2272 306.3684 306.5095 306.6507 306.7919 306.9330 307.0742 307.2153 307.3564 307.4975 307.6386 307.7797 307.9208 308.0619 308.2029 308.3439 308.4850 308.6260 308.7670 308.9080 309.0490 309.1899 309.3309 309.4719 309.6128 309.7537 309.8946 310.0355 310.1764 310.3173 310.4582 310.5990 310.7399 310.8807 311.0215 311.1624 311.3032 311.4439 311.5847 311.7255 311.8662 312.0070 312.1477 312.2884 312.4291 312.5698 312.7105 312.8512 312.9919 313.1325 313.2732 313.4138 313.5544 313.6950 313.8356 313.9762 314.1168 314.2573 314.3979 314.5384 314.6789 314.8194 314.9599 315.1004 315.2409 315.3814 315.5218 315.6623 315.8027 315.9431 316.0835 316.2239 316.3643 316.5047 316.6451 316.7854 316.9257 317.0661 317.2064 317.3467 317.4870 317.6273 317.7675 317.9078 318.0481 318.1883 318.3285 318.4687 318.6089 318.7491 318.8893 319.0295 319.1696 319.3098 319.4499 319.5900 319.7301 319.8702 320.0103 320.1504 320.2904 320.4305 320.5705 320.7105 320.8505 320.9905 321.1305 321.2705 321.4105 321.5504 321.6904 321.8303 321.9702 322.1101 322.2500 322.3899 322.5298 322.6697 322.8095 322.9494 323.0892 323.2290 323.3688 323.5086 323.6484 323.7881 323.9279 324.0676 324.2074 324.3471 324.4868 324.6265 324.7662 324.9058 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200918T105111.7Z 7566.452219 44 1 49.46 2 81.99 83.12 94.96 91.88 0.00 1 0.00 1 0 25 7.350e-01 4.220e-02 4.553e-01 3.382e-02 6.940387e-01 1.941062e-02 9.472312e-03 -6.000000e+00 4.183027e-01 228.05 -2.00 3.11 -2.00 322.09 0.00e+00 2.246251e-02 1.018552e-02 9.683367e-03 -6.000000e+00 2.071409e-02 282.73 -2.00 20.00 -2.00 321.59 0.00e+00 6.714 0.002 302.00 328.00 3 4.9167e-01 7.3336e-02 8.0038e-02 -6.0000e+00 1.0453e+00 1.0854e+00 9.0037e-02 4.5877e-02 -6.0000e+00 1.1389e+00 -1.2572e+00 6.5469e-02 2.8614e-02 -6.0000e+00 6.7487e-01 4.7896e-01 3.2147e-02 1.4642e-02 -6.0000e+00 2.9676e-01 2.0344e-04 -5.5448e-04 1.0351e-03 3.4359e-04 -6.0000e+00 1.9627e-02 2.2083e-02 0.0000e+00 12 8 8 10 0 0 46.27 21.96 0.62 0.02208 0.01792 42 8 1 5 0 1177.444 27.56 20.00 21.96 900000 900000 900000 -90873 -96286 -78472 -53805 142092 900000 -51960 -98000 900000 -107042 -8923 -59058 12628 16770 382659 163413 900000 900000 57412 900000 -41548 341168 -29715 171226 900000 -15671 900000 900000 900000 47776 63726 -6996 -46424 187972 5202 337028 17294 42155 12294 51288 37194 4928 93816 45585 98818 49332 45742 28661 79804 35154 -12143 93549 166111 49713 -11774 95580 -8064 14570 30790 65934 18258 3450 58083 21678 59897 4996 24169 12675 32775 -13776 7077 22878 36269 -12286 22871 -10843 12609 -7302 -3675 -11134 -1217 7648 -9761 3001 2277 268 -9535 1159 2336 3555 -7162 -2844 -3621 -765 -7626 -1801 5403 -6976 764 -10665 2905 -8756 647 -2896 -1793 -2369 3083 2979 1293 2208 -1222 -1826 -3307 2475 1524 2444 -1609 5425 3179 1416 -4776 4007 -3528 345 4645 -696 2946 470 1405 -405 -1114 -2143 572 -483 1659 -1445 1981 -249 -2213 900000 900000 900000 -6676 -6124 -3614 -1770 4674 900000 -1709 -4113 900000 -7893 -324 -4355 516 704 12588 5376 900000 900000 1889 900000 -2392 11223 -1362 5633 900000 -630 900000 900000 900000 1863 2096 -401 -3846 6184 322 11087 1160 2294 933 2726 2306 430 3580 2879 3771 3181 3250 2640 4726 3423 -1949 5386 5465 4225 -1759 4716 -1139 1777 3630 6507 3160 686 6397 3411 6768 1108 4909 3009 6567 -4120 1556 3797 4773 -2590 3728 -2967 3243 -2757 -1480 -5093 -530 3235 -5168 1448 1113 130 -4780 507 953 1439 -3581 -1600 -2418 -579 -6949 -1597 4453 -5834 526 -7996 2032 -7353 521 -2593 -1741 -2620 3641 4018 1805 2979 -1620 -2326 -4279 3175 2106 3525 -2414 7726 4441 1954 -6755 5016 -4581 443 6490 -1179 5354 940 2931 -915 -2712 -5922 1573 -1365 4597 -3989 4948 -592 -5132 SS 20200918T110658.0Z 7566.463171 49 1 50.00 2 78.67 80.97 91.69 89.94 0.00 1 0.00 1 0 17 2.532e-01 2.151e-02 2.305e-01 6.995e-03 5.577740e-01 3.738324e-03 5.860845e-03 -6.000000e+00 1.433067e-01 228.05 -2.00 3.11 -2.00 321.54 0.00e+00 7.991291e-03 1.894141e-03 2.037844e-03 -6.000000e+00 6.317209e-03 282.73 -2.00 20.00 -2.00 320.97 0.00e+00 4.917 0.001 302.00 328.00 3 2.3693e-01 1.3380e-02 5.4123e-02 -6.0000e+00 3.5643e-01 3.2924e-01 1.7671e-02 2.7139e-02 -6.0000e+00 3.8701e-01 -4.0324e-01 1.6440e-02 1.7448e-02 -6.0000e+00 2.3040e-01 1.5745e-01 7.8519e-03 9.6912e-03 -6.0000e+00 9.8737e-02 1.9128e-03 6.1966e-04 2.1161e-04 1.2543e-04 -6.0000e+00 6.6063e-03 2.2086e-02 0.0000e+00 12 8 8 10 0 0 31.37 21.96 0.37 0.02209 0.02674 167 33 1 5 0 299.372 27.56 20.00 21.96 -82818 70920 -4111 -78208 -35020 -26022 -59968 73667 -20735 -35069 -79492 -37306 -28468 -3765 -26294 8632 -3915 -20014 57097 -9840 15538 16805 8006 -2178 639 898 2040 12550 -16766 -144285 -1518 70674 22001 23846 1964 63723 -10537 63264 -354 29639 15224 17440 3666 19364 19360 20946 23287 10721 19818 6645 22908 11585 24851 12721 12315 6885 13260 4956 14218 15327 8835 17326 6306 10958 3401 8181 -959 4223 1972 4528 4008 1830 3723 3746 346 326 -1210 -3639 597 -2440 1739 -261 -1368 -1519 -119 -915 -1301 30 -1340 329 -211 -1352 -181 -816 -2160 -748 -889 -1009 -1152 -176 -1346 -1742 16 -786 -1246 -2689 -503 -2025 168 -720 285 -527 164 -42 -518 99 -512 741 -255 599 -190 1364 809 1825 -217 1326 1034 824 1295 1210 555 457 313 -591 -96 -515 545 -419 114 -365 -111 -1199 -1477 484 -37 -1313 -340 -234 -802 502 -215 -421 -1518 -550 -489 -64 -674 177 -98 -633 872 -301 375 392 209 -66 19 27 60 317 -576 -20008 -63 1635 913 948 90 1625 -641 2195 -28 1933 1284 1508 376 1717 1746 1890 2079 1110 1935 795 2701 1663 3349 2037 2028 1221 2200 867 2212 2394 1590 3385 1548 2754 901 1964 -250 1110 608 1524 1431 669 1275 1245 106 91 -333 -1104 203 -1005 784 -133 -741 -875 -73 -626 -928 21 -937 212 -126 -766 -101 -497 -1533 -604 -822 -1035 -1275 -182 -1273 -1499 13 -717 -1218 -2801 -545 -2411 217 -1038 431 -805 254 -61 -717 135 -737 1124 -414 969 -300 2049 1262 2701 -316 1812 1444 1285 2259 2305 1127 967 699 -1424 -244 -1342 1431 -1114 293 -888 -272 -2862 SS 20200918T111427.1Z 7566.468369 52 1 50.11 2 77.10 79.93 90.14 89.02 0.00 1 0.00 1 0 25 3.449e-01 1.063e-02 1.848e-01 4.400e-03 5.099907e-01 2.342787e-03 5.089560e-03 -6.000000e+00 1.954100e-01 228.05 -2.00 3.11 -2.00 321.24 0.00e+00 -7.573185e-04 1.083459e-03 3.819079e-04 -6.000000e+00 8.612652e-03 282.73 -2.00 20.00 -2.00 320.63 0.00e+00 4.360 0.001 302.00 328.00 3 1.8876e-01 7.9861e-03 4.8233e-02 -6.0000e+00 4.8588e-01 9.2804e-02 1.0522e-02 2.4502e-02 -6.0000e+00 5.2732e-01 -1.0280e-01 9.9259e-03 1.2516e-02 -6.0000e+00 3.1414e-01 3.3582e-02 4.7811e-03 3.7180e-03 -6.0000e+00 1.3504e-01 3.7635e-03 1.0935e-03 1.3507e-04 4.1611e-05 -6.0000e+00 9.0000e-03 2.1754e-02 0.0000e+00 12 8 8 10 0 0 15.40 21.96 0.30 0.02175 0.02997 249 50 1 5 0 201.204 27.56 20.00 21.96 -71649 -8993 -118684 -66888 -108154 221071 -147492 102409 -119085 15991 -93102 15892 -72818 -637 -32166 -34912 -7171 -27761 9336 -18016 1402 -39405 26618 -48695 6393 -27269 27376 -45986 21703 900000 -9032 4250 -6767 -68 -13010 8067 -23015 12578 -3640 6489 -6023 8445 -1218 3151 4569 1088 6819 -1653 3081 -2020 8165 -926 11425 -41 10832 -2436 6336 3144 3933 1231 1813 4836 2897 6277 -637 4205 -40 4600 -47 2271 1291 2077 394 780 1512 492 1492 1022 1159 -3098 1652 -3233 -641 -3050 -63 -914 583 -523 1612 541 68 382 -1220 1846 -1867 83 -704 599 -1442 784 -1433 -482 -812 -850 -728 -1148 -959 -742 346 -563 792 -774 1023 -546 594 -270 284 -201 84 -605 -551 659 244 1273 142 1192 734 1507 91 1096 -182 640 -268 -452 -30 -79 688 -459 88 -489 7 -650 -713 -52 -2098 -643 -1447 948 -3585 439 -2831 103 -1847 122 -1666 -9 -713 -892 -150 -769 189 -499 33 -1433 541 -2316 188 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