File name: Pandora125s1_Cordoba_20200925_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142839.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200925_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200925T114104.8Z 7573.486862 140 1 43.68 2 69.52 78.14 124.82 175.57 0.00 1 0.00 1 0 17 3.225e-01 3.929e-02 2.019e-01 1.325e-02 3.297897e-01 6.805746e-03 3.684731e-03 -6.000000e+00 1.831487e-01 228.19 -2.00 3.11 -2.00 320.20 0.00e+00 9.278633e-03 2.170972e-03 7.679961e-04 -6.000000e+00 8.216782e-03 283.03 -2.00 20.00 -2.00 319.49 0.00e+00 2.829 0.000 302.00 328.00 3 4.5408e+00 2.0344e-02 3.1365e-02 -6.0000e+00 4.5650e-01 1.5381e-01 2.3779e-02 1.7617e-02 -6.0000e+00 4.9586e-01 -2.5429e-01 1.7560e-02 1.0236e-02 -6.0000e+00 2.9422e-01 1.0724e-01 9.1712e-03 9.1954e-03 -6.0000e+00 1.2503e-01 2.4224e-04 -9.0681e-04 4.1159e-04 9.1574e-05 -6.0000e+00 8.5789e-03 -4.5098e-03 0.0000e+00 12 9 9 12 9 1 98.07 22.97 0.23 -0.00451 -0.01132 17 4 1 5 0 2417.403 28.51 20.00 22.97 82560 -5910 103170 863 900000 11075 127775 11472 900000 8648 147823 45864 158264 12975 66650 74992 29442 42386 40386 30836 14130 51592 10908 51653 25903 33898 14582 100984 -1498 39469 -113901 6456 33231 7359 29824 16070 19594 -19009 41804 -2367 1978 7487 18135 17766 14671 8593 9250 19156 8365 20925 5925 17504 6797 16693 3543 6786 6831 9446 8826 4698 -2748 6206 6718 3246 8890 -606 6165 -2841 2977 3372 5260 -4875 5066 -5129 2196 1490 1527 3312 108 -3053 -1848 -168 -3112 -2290 -3125 1728 -3084 -1216 -505 -835 -1084 -2525 -2196 -4428 -1145 -2082 -3010 -1789 2334 -2990 -61 38 3235 -68 1944 -2009 -385 -1836 -641 726 161 225 -1432 -262 -268 0 107 2624 -605 19 825 1564 -166 292 1885 -1290 571 1750 3041 731 2761 -675 1432 546 -820 -653 -107 -417 -313 -47 -1320 573 -1185 1599 -322 1998 45 900000 424 1650 439 900000 376 1909 1316 2044 707 2550 3049 2042 2696 2848 2466 1361 3331 1024 3232 2123 2593 1354 3964 -156 2691 -37165 737 3210 984 3035 1735 2105 -3387 4971 -490 451 1700 3844 3890 3347 2113 2264 4195 2016 4629 1587 4501 2068 4836 1208 2255 2290 3065 2815 1543 -1044 2320 2760 1509 4054 -288 2515 -1216 1246 1593 2714 -2930 2903 -3141 1170 720 663 1332 46 -1541 -1056 -105 -2177 -1746 -2550 1445 -2874 -1157 -482 -781 -950 -2051 -1709 -3373 -890 -1826 -3007 -1986 2709 -3691 -69 39 2983 -66 2099 -2284 -476 -2426 -886 1068 256 370 -2340 -397 -376 0 147 3649 -931 31 1380 2564 -269 455 2751 -1858 765 2454 4540 1221 4814 -1263 2681 1073 -1735 -1460 -244 -976 -740 -108 -2954 1203 -2456 SS 20200925T114839.3Z 7573.492121 143 1 50.58 2 67.94 77.01 124.68 173.57 0.00 1 0.00 1 0 25 1.077e-01 1.230e-02 1.259e-01 1.007e-02 3.241612e-01 5.104813e-03 3.470601e-03 -6.000000e+00 6.087440e-02 228.19 -2.00 3.11 -2.00 320.07 0.00e+00 -1.626654e-04 1.521463e-03 7.422049e-04 -6.000000e+00 2.683780e-03 283.03 -2.00 20.00 -2.00 319.32 0.00e+00 2.640 0.000 302.00 328.00 3 4.3363e+00 1.5025e-02 2.9664e-02 -6.0000e+00 1.5144e-01 1.1908e-02 1.7737e-02 1.5751e-02 -6.0000e+00 1.6437e-01 -4.3811e-02 1.3423e-02 7.6677e-03 -6.0000e+00 9.7940e-02 1.4188e-02 6.9233e-03 2.1388e-03 -6.0000e+00 4.1699e-02 3.7360e-04 -1.0678e-03 3.0875e-04 2.5919e-05 -6.0000e+00 2.7867e-03 -4.9852e-03 0.0000e+00 12 8 8 10 0 0 99.94 22.98 0.34 -0.00499 -0.01301 36 7 1 5 0 1404.998 28.51 20.00 22.98 -13350 69020 -13288 -28370 1431 32000 -25443 -9962 -3830 27615 11628 -12267 33359 -1286 12785 -33584 31871 20368 2205 -7242 19858 -27845 -15366 4264 -1073 7472 -11210 12929 13734 13968 -5250 -1890 7587 8476 -14102 289 -10903 6512 314 -6406 115 -3085 -195 2014 2123 -1846 755 4028 4006 -2237 10282 -1355 -1195 4049 875 2588 -2138 -80 1631 127 1932 704 468 6354 352 4964 -1255 1554 -1370 -598 -2937 -30 1016 1988 1603 -1881 428 41 3242 -546 -2038 -770 -3412 -4242 -1528 1641 -57 275 -933 1643 162 2495 -2154 2221 1803 -1167 -297 -313 488 343 457 -1119 -1308 -566 80 -677 801 -2471 1386 -604 794 39 -72 -880 268 1255 151 357 44 -794 -1121 -556 -798 1719 194 268 -1024 2017 -253 508 2062 316 269 -37 332 -558 -519 213 506 -326 119 -768 -299 -384 1005 -468 -1184 40 595 -856 -321 -133 765 383 -512 971 -62 646 -3078 1634 1222 167 -627 1358 -3058 -1492 360 -103 693 -1329 1157 1131 1102 -525 -202 814 970 -1949 34 -1490 862 54 -1401 27 -784 -50 514 540 -490 194 1023 1005 -598 2541 -409 -386 1317 307 918 -817 -32 617 48 725 285 209 2905 177 2259 -559 677 -641 -316 -1777 -19 633 1190 904 -991 207 19 1466 -290 -1253 -523 -2585 -3401 -1268 1423 -54 267 -926 1550 152 2094 -1732 1634 1399 -1036 -293 -346 580 411 544 -1237 -1342 -582 89 -809 986 -3302 1880 -899 1249 64 -116 -1415 391 1696 203 499 66 -1287 -1876 -915 -1278 2745 299 395 -1446 2745 -379 821 3498 566 492 -71 670 -1204 -1152 480 1220 -776 272 -1686 -634 SS 20200925T115435.9Z 7573.496249 146 1 49.87 2 66.71 76.11 124.53 172.01 0.00 1 0.00 1 0 17 5.516e-02 6.613e-03 3.683e-02 3.725e-03 3.115731e-01 1.886509e-03 3.280755e-03 -6.000000e+00 3.117737e-02 228.19 -2.00 3.11 -2.00 319.82 0.00e+00 5.238788e-04 5.247286e-04 1.670012e-04 -6.000000e+00 1.374485e-03 283.03 -2.00 20.00 -2.00 319.06 0.00e+00 2.510 0.000 302.00 328.00 3 3.0244e+00 5.4440e-03 2.8119e-02 -6.0000e+00 7.7559e-02 3.0444e-03 6.3801e-03 1.4584e-02 -6.0000e+00 8.4185e-02 -2.0928e-02 4.7204e-03 7.1856e-03 -6.0000e+00 5.0160e-02 1.9343e-04 2.4502e-03 2.1020e-03 -6.0000e+00 2.1357e-02 1.5897e-03 -9.4239e-04 1.1367e-04 2.2802e-05 -6.0000e+00 1.4272e-03 -5.1898e-03 0.0000e+00 11 8 0 10 0 0 94.48 22.98 0.39 -0.00519 -0.01227 106 21 1 5 0 470.345 28.51 19.99 22.98 -9746 27149 -19708 7322 -35766 4995 -14033 12795 -12730 -5886 846 -16867 1174 -8401 6735 -8112 7047 -9179 785 -1101 -1135 4359 213 2604 -1195 6793 1866 -1424 -8733 -4190 -2565 5618 1460 201 -4887 -5376 -4879 -2252 2181 1187 1843 -2739 781 -1121 95 -2224 -681 -2065 305 -264 2962 1743 304 1080 447 1039 1105 1034 324 -383 -10 1668 721 1627 1153 -247 1079 -658 1310 1948 1799 577 1298 -460 1314 -2105 -77 -2244 649 -241 49 -517 -1864 -1503 -635 -745 47 600 -79 888 -615 691 -954 1087 -290 277 356 504 490 -208 -274 -1045 7 -899 304 -1362 -786 -861 -219 -661 38 -126 -47 386 64 284 191 723 -266 -43 -696 -162 -80 582 524 1169 644 1131 957 256 589 124 208 -125 -144 -639 -114 92 -252 -149 310 -249 -363 -307 682 -841 235 -1581 134 -463 360 -528 -249 35 -837 54 -494 398 -634 510 -815 66 -99 -106 383 20 245 -125 693 204 -162 -994 -439 -277 616 184 28 -679 -704 -666 -345 405 254 463 -766 219 -327 27 -658 -197 -595 84 -74 836 540 102 383 175 414 452 426 132 -154 -4 712 341 829 611 -126 523 -312 633 1064 1101 379 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