File name: Pandora125s1_Cordoba_20200929_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142929.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20200929_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20200929 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200929T103703.8Z 7577.442406 211 1 49.70 2 81.92 88.16 109.14 241.94 0.00 1 0.00 1 0 25 6.729e-01 4.655e-02 4.199e-01 3.239e-02 7.182807e-01 1.875974e-02 7.768447e-03 -6.000000e+00 3.896744e-01 228.28 -2.00 3.11 -2.00 322.11 0.00e+00 -4.389192e-04 8.999304e-03 1.056652e-02 -6.000000e+00 1.893916e-02 283.20 -2.00 20.00 -2.00 321.57 0.00e+00 6.661 0.002 302.00 328.00 3 1.4147e+00 6.9403e-02 9.5632e-02 -6.0000e+00 9.7174e-01 1.1174e+00 8.5810e-02 9.1237e-02 -6.0000e+00 1.0617e+00 -1.4480e+00 5.9536e-02 3.2555e-02 -6.0000e+00 6.2655e-01 5.6380e-01 2.9337e-02 5.7200e-03 -6.0000e+00 2.6396e-01 9.2307e-05 -3.7283e-04 1.0073e-03 1.2078e-04 -6.0000e+00 1.8969e-02 1.6791e-03 0.0000e+00 12 8 8 10 0 0 38.95 22.17 1.01 0.00168 -0.00112 51 10 1 5 0 974.341 27.78 20.00 22.17 52608 18944 241412 17860 900000 -51870 900000 -61212 219095 -88101 900000 -32242 294899 9029 900000 900000 78939 33376 65063 900000 46677 900000 -73841 900000 -61175 900000 7407 61014 -17411 164656 3868 15490 227744 -39100 900000 11130 900000 -40223 900000 27278 191414 58386 342338 4808 124283 14339 101119 32675 24088 57343 90544 143036 -6671 35610 62096 23610 16833 11724 -29435 44803 -12098 -2060 38551 26576 23493 -15926 38596 -4830 44004 12273 42639 19007 37032 5622 -4187 14777 18295 3669 -1083 9188 -11821 11839 -6569 10963 -15430 15564 -4162 8622 -487 11612 -6832 -805 8263 8623 6146 -9750 10628 -13114 6122 -6917 7923 -2340 -4369 -1111 9120 -3933 -2218 632 -5954 449 -8035 -1346 -1574 3479 -1292 -228 2429 -1911 -5784 5071 -2383 -3462 3974 5253 3917 -3321 5686 4944 6206 -1417 3971 -1409 989 791 -1065 -866 1259 633 1000 437 -2586 1507 -3986 1713 935 7609 788 900000 -3161 900000 -4191 6905 -8330 900000 -1647 9295 402 900000 900000 2488 1632 2417 900000 1944 900000 -8977 900000 -6955 900000 409 1923 -1037 5190 199 814 7178 -4153 900000 598 900000 -4242 900000 2017 6033 3610 10790 501 3917 1320 3824 2430 1974 3470 4224 4508 -967 3741 5219 2977 2299 1647 -5876 4001 -1875 -306 4438 3860 3734 -3645 4919 -960 5789 2539 7187 4411 7056 1369 -1014 2604 2831 652 -222 2110 -3939 3572 -2632 3900 -7573 5957 -2037 3817 -235 5032 -3316 -342 3073 3275 2683 -5823 6029 -10891 4650 -6402 5954 -1747 -3001 -733 5870 -3073 -1795 533 -5916 502 -11002 -1857 -2213 4538 -1681 -281 2934 -2533 -8488 7399 -3720 -5243 5379 6827 4981 -4389 6620 6040 8548 -2414 7548 -3031 2192 1874 -2763 -2367 3442 1768 2776 1170 -6657 3468 -9313 SS 20200929T105231.0Z 7577.453137 216 1 49.99 2 78.63 86.11 111.94 239.45 0.00 1 0.00 1 0 25 4.008e-01 1.592e-02 2.569e-01 6.677e-03 5.692931e-01 3.627417e-03 5.731692e-03 -6.000000e+00 2.293795e-01 228.28 -2.00 3.11 -2.00 321.64 0.00e+00 6.664514e-03 1.862885e-03 7.265596e-04 -6.000000e+00 1.030576e-02 283.20 -2.00 20.00 -2.00 321.06 0.00e+00 4.903 0.001 302.00 328.00 3 1.0337e+00 1.3157e-02 5.5000e-02 -6.0000e+00 5.7140e-01 2.6551e-01 1.7458e-02 3.1017e-02 -6.0000e+00 6.2079e-01 -3.4129e-01 1.6403e-02 1.4425e-02 -6.0000e+00 3.6723e-01 1.3081e-01 7.7814e-03 8.1499e-03 -6.0000e+00 1.5575e-01 8.7576e-04 -1.3850e-03 2.0442e-04 8.4343e-05 -6.0000e+00 1.0699e-02 1.1188e-03 0.0000e+00 12 8 8 10 0 0 25.99 22.18 0.46 0.00112 -0.00929 204 41 1 5 0 245.015 27.78 20.00 22.18 11240 -140654 67282 -147036 900000 -127301 900000 -166892 900000 -140399 35799 -84897 -63332 -40595 55235 -33342 -45917 109978 -77238 113892 -59402 32629 -61081 39257 -20442 71705 -22311 75004 -6050 33608 900000 -9838 93789 -30121 56731 -23019 57007 -31140 63965 116 44203 1218 9631 13549 7658 13972 6553 17570 -6275 28314 2509 20650 6733 22286 12573 12271 2483 11860 -757 2421 9452 -1441 14580 -880 10062 -963 11753 -5447 6224 2558 5615 2042 2850 4363 -918 3085 -6198 7286 -7956 7139 -3027 4463 -4652 1282 -2976 -606 -835 766 -291 641 -157 -1490 677 -5851 279 -3883 368 -793 -58 -918 376 -1578 -75 -979 -905 -710 -2118 -1338 -1804 1459 -1075 1109 -366 1215 -1340 222 316 553 -329 -447 500 -1107 1430 19 1704 1058 1320 -373 2385 -105 1059 635 -60 72 -367 120 -729 531 -658 549 -506 372 -1065 73 -3098 438 -3753 900000 -2166 900000 -4735 900000 -3581 233 -1304 -940 -613 403 -712 -1255 716 -3377 771 -2432 522 -2467 607 -604 875 -708 874 -153 583 900000 -373 1459 -1781 1364 -1153 1339 -2026 1936 8 2301 104 798 1114 675 1178 605 1476 -687 2278 283 2259 922 2810 1843 1855 424 1841 -129 392 1450 -267 2727 -217 2373 -248 2539 -1395 1517 744 1772 704 975 1476 -302 872 -1749 1757 -2414 2190 -1206 1883 -2369 651 -1676 -377 -550 515 -199 423 -98 -868 362 -3331 163 -2731 286 -715 -61 -985 377 -1452 -61 -807 -805 -673 -2137 -1425 -2091 1821 -1520 1629 -581 1825 -1937 299 425 775 -497 -712 795 -1733 2105 30 2478 1489 1771 -520 3602 -182 1994 1272 -125 160 -874 301 -1888 1384 -1743 1392 -1311 900 -2520 SS 20200929T110010.0Z 7577.458449 219 1 49.95 2 77.01 85.08 113.29 238.17 0.00 1 0.00 1 0 25 2.892e-01 9.823e-03 1.889e-01 4.183e-03 5.177782e-01 2.219792e-03 5.222373e-03 -6.000000e+00 1.633484e-01 228.28 -2.00 3.11 -2.00 321.31 0.00e+00 -7.057871e-04 1.045605e-03 4.602276e-04 -6.000000e+00 7.209518e-03 283.20 -2.00 20.00 -2.00 320.69 0.00e+00 4.333 0.001 302.00 328.00 3 9.3091e-01 7.6371e-03 4.8251e-02 -6.0000e+00 4.0641e-01 8.9961e-02 1.0154e-02 2.5002e-02 -6.0000e+00 4.4124e-01 -1.0718e-01 9.6503e-03 1.2817e-02 -6.0000e+00 2.6290e-01 3.1692e-02 4.6271e-03 3.8373e-03 -6.0000e+00 1.1182e-01 1.8175e-03 -9.5944e-04 1.2732e-04 4.4399e-05 -6.0000e+00 7.4823e-03 1.0730e-03 0.0000e+00 12 8 8 10 0 0 30.76 22.18 0.27 0.00107 -0.00614 311 62 1 5 0 160.600 27.78 20.00 22.18 -121790 56646 -115043 -74962 -93533 -71304 -6231 -108175 33135 -92111 9560 -129872 -12842 -98492 70256 -19817 -13168 -31740 17979 -18204 -9396 -8665 -24216 37645 -29841 146 -18919 8536 -41241 3669 -23502 17597 -15753 6482 7642 -9095 -1542 -8119 13264 -11534 5246 -1308 6819 -6117 5975 -1722 4840 4327 1919 3230 -1238 7640 -1599 10843 -941 7309 -853 10747 -2945 5464 202 3366 3893 4981 5917 1487 1290 -3282 4467 2254 2795 -743 3166 -176 1130 791 1007 -3049 -1229 63 -1562 1292 -2210 -1074 -2705 1073 -973 910 -1456 1258 -664 502 -802 5 1375 -415 730 -70 493 -935 227 -2446 -204 -703 84 -1860 -515 -1089 -736 252 -568 390 -68 518 -452 1244 -47 274 -436 507 -853 -48 334 145 1359 413 924 906 1293 -380 1077 -408 168 -236 -184 -236 -323 317 32 107 5 32 -789 -1590 231 -1821 -795 -1084 -617 -31 -1691 146 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