File name: Pandora125s1_Cordoba_20201118_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142918.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20201118_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20201118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201118T110217.5Z 7627.459924 90 1 50.92 2 67.22 99.44 102.11 128.63 0.00 1 0.00 1 0 25 4.136e-01 4.779e-02 2.139e-01 1.357e-02 3.352999e-01 6.858310e-03 3.684753e-03 -6.000000e+00 2.344016e-01 228.97 -2.00 3.11 -2.00 320.06 0.00e+00 7.981478e-03 2.126002e-03 4.715478e-04 -6.000000e+00 1.041666e-02 285.54 -2.00 20.00 -2.00 319.28 0.00e+00 2.562 0.000 302.00 328.00 3 5.0152e+00 2.0498e-02 2.9391e-02 -6.0000e+00 5.8367e-01 1.7303e-01 2.4040e-02 1.7578e-02 -6.0000e+00 6.3300e-01 -3.0051e-01 1.7512e-02 9.7004e-03 -6.0000e+00 3.7749e-01 1.4832e-01 9.1513e-03 7.9024e-03 -6.0000e+00 1.6077e-01 1.8969e-04 4.2870e-05 4.1411e-04 7.7838e-05 -6.0000e+00 1.0706e-02 -1.9947e-03 0.0000e+00 12 8 8 10 0 0 44.97 22.28 0.40 -0.00199 -0.00167 13 3 1 5 0 3916.389 27.88 20.01 22.28 148356 63882 49405 118011 108654 35478 205445 49170 66563 40657 89265 117856 45363 150560 87764 63810 53182 106512 15098 42389 45486 23800 41630 126773 21331 25469 20181 51756 21399 20471 -118627 10070 39534 42892 33665 37035 47205 9053 9280 18865 19975 11509 9981 18047 8193 19684 9590 14045 11559 5159 17007 3447 11463 11845 3812 6616 3443 -447 5408 -3469 16401 5895 12107 1386 3172 9338 6854 8644 2824 -1303 9059 172 -52 -1972 1422 -2066 1000 -4733 195 1694 3121 1649 1281 -2467 -2748 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-577 1072 -5179 -4077 SS 20201118T112837.0Z 7627.478206 101 1 49.95 2 61.67 96.35 97.82 124.80 0.00 1 0.00 1 0 17 7.377e-02 1.190e-02 4.274e-02 5.727e-03 2.959857e-01 2.891768e-03 3.147021e-03 -6.000000e+00 4.180749e-02 228.97 -2.00 3.11 -2.00 319.47 0.00e+00 1.580393e-03 7.186427e-04 1.620487e-04 -6.000000e+00 1.857805e-03 285.54 -2.00 20.00 -2.00 318.64 0.00e+00 2.097 0.000 302.00 328.00 3 4.1950e+00 8.1976e-03 2.4414e-02 -6.0000e+00 1.0410e-01 6.3924e-02 9.4864e-03 1.3797e-02 -6.0000e+00 1.1290e-01 -4.6896e-02 6.5404e-03 6.8668e-03 -6.0000e+00 6.7328e-02 1.0737e-02 3.3960e-03 2.3028e-03 -6.0000e+00 2.8676e-02 7.1824e-04 -8.8019e-04 1.7361e-04 2.4841e-05 -6.0000e+00 1.9093e-03 -2.4601e-03 0.0000e+00 12 9 8 11 8 0 62.22 22.28 0.19 -0.00246 -0.00907 37 7 1 5 0 1349.844 27.88 20.02 22.28 3174 17356 -10488 40146 -7365 10715 -18332 -21746 19160 -8279 -12266 -9059 -925 -14259 22075 -3852 9298 -3209 6068 -3599 -84 -5217 7063 9451 3216 -1369 -7086 1468 8535 3782 -45850 13238 2614 8814 -1485 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-364 -1191 549 -1374 389 -408 -456 1372 356 195 685 498 -20 842 -1308 -540 279 986 1264 743 435 962 2710 -62 1918 -66 1488 -583 -690 -992 -318 -349 300 -811 567 -1129 -774 SS 20201118T114125.4Z 7627.487099 107 1 50.76 2 58.96 94.82 95.65 123.04 0.00 1 0.00 1 0 41 5.132e-01 9.741e-02 1.276e-01 1.721e-02 2.345733e-01 8.489512e-03 3.476697e-03 -6.000000e+00 2.907485e-01 228.97 -2.00 3.11 -2.00 319.01 0.00e+00 2.176300e-02 1.937699e-03 1.742621e-03 -6.000000e+00 1.292234e-02 285.54 -2.00 20.00 -2.00 318.15 0.00e+00 1.932 0.000 302.00 328.00 3 5.7526e+00 2.3807e-02 2.1886e-02 -6.0000e+00 7.2398e-01 3.2394e-01 2.7251e-02 1.7923e-02 -6.0000e+00 7.8522e-01 -4.0808e-01 1.7361e-02 1.2816e-02 -6.0000e+00 4.6826e-01 1.7833e-01 9.0588e-03 1.5638e-02 -6.0000e+00 1.9939e-01 1.7568e-04 2.1066e-03 5.0784e-04 1.6509e-04 -6.0000e+00 1.3281e-02 -8.8928e-04 0.0000e+00 12 8 8 10 0 0 99.90 22.28 0.24 -0.00089 0.01494 15 3 1 5 0 3384.002 27.88 19.98 22.28 105098 201132 187607 148407 95821 126672 120028 167623 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