File name: Pandora125s1_Cordoba_20201231_L2Fit_fwvt1c3d20170323p1-8.txt File generation date: 20250228T141623.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20201231_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20201231 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1630 1778 Nominal wavelengths inside fitting window [nm]: 492.0835 492.2050 492.3266 492.4481 492.5696 492.6911 492.8125 492.9340 493.0554 493.1768 493.2982 493.4196 493.5409 493.6623 493.7836 493.9049 494.0262 494.1475 494.2687 494.3900 494.5112 494.6324 494.7536 494.8748 494.9959 495.1171 495.2382 495.3593 495.4804 495.6015 495.7225 495.8436 495.9646 496.0856 496.2066 496.3276 496.4486 496.5695 496.6904 496.8113 496.9322 497.0531 497.1740 497.2948 497.4156 497.5364 497.6572 497.7780 497.8988 498.0195 498.1402 498.2609 498.3816 498.5023 498.6229 498.7436 498.8642 498.9848 499.1054 499.2260 499.3465 499.4671 499.5876 499.7081 499.8286 499.9491 500.0695 500.1900 500.3104 500.4308 500.5512 500.6715 500.7919 500.9122 501.0326 501.1529 501.2731 501.3934 501.5137 501.6339 501.7541 501.8743 501.9945 502.1147 502.2348 502.3550 502.4751 502.5952 502.7153 502.8353 502.9554 503.0754 503.1954 503.3154 503.4354 503.5554 503.6753 503.7952 503.9152 504.0351 504.1549 504.2748 504.3946 504.5145 504.6343 504.7541 504.8739 504.9936 505.1134 505.2331 505.3528 505.4725 505.5922 505.7118 505.8315 505.9511 506.0707 506.1903 506.3099 506.4294 506.5490 506.6685 506.7880 506.9075 507.0269 507.1464 507.2658 507.3853 507.5047 507.6240 507.7434 507.8628 507.9821 508.1014 508.2207 508.3400 508.4593 508.5785 508.6977 508.8170 508.9362 509.0553 509.1745 509.2936 509.4128 509.5319 509.6510 509.7701 509.8891 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-395: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20201231T092052.2Z 7670.389492 180 1 8.30 2 89.42 116.99 80.43 307.08 0.00 1 0.00 1 0 22 5.021e-03 4.999e-03 1.556e-03 1.552e-03 1.891500e+04 1.187500e+02 1.214592e+03 -6.000000e+00 2.969615e+02 287.68 -2.00 20.00 -2.00 505.42 0.00e+00 2.434105e-03 4.459573e-05 1.500793e-04 -6.000000e+00 1.454412e-04 287.68 -2.00 20.00 -2.00 500.96 0.00e+00 1.116748e+00 3.065498e-02 1.175654e-01 -6.000000e+00 1.019374e-01 229.20 -2.00 3.11 -2.00 502.47 0.00e+00 19.467 0.061 489.00 513.00 1 3.2640e+00 2.3543e-03 3.0036e-02 -6.0000e+00 7.8450e-03 -1.5700e-02 5.8257e-04 3.2738e-03 -6.0000e+00 2.0137e-03 4.4883e-03 3.2040e-03 1.5605e-04 1.2028e-04 -6.0000e+00 5.8582e-04 -5.3552e-02 5.0439e-04 12 9 9 12 1 1 57.06 22.33 1.66 -0.05355 -0.03133 5 7 1 4 0 1355.324 27.88 20.01 22.33 -728 -442 -225 4 574 868 712 777 679 237 411 -43 -484 -387 -304 -440 83 248 336 376 538 267 188 380 533 213 449 -150 -544 -811 -949 -614 -141 168 261 -84 40 19 -161 -291 135 161 198 392 587 363 465 3 74 -739 -501 -816 -826 -33 -234 -112 236 696 443 559 426 476 439 480 -144 -269 -261 -296 -533 -545 -622 -856 -511 -135 -213 -902 -937 -622 -507 -498 -236 -458 -194 -122 -31 -258 -244 7 -327 106 463 590 629 482 374 -73 -478 -602 -672 -1050 -1120 -851 -37 147 -496 -374 -160 -706 -237 -161 248 237 543 747 1030 1289 902 757 353 175 -238 271 645 722 501 482 334 -7 754 124 -150 -417 -622 -729 206 62 89 -74 678 207 310 237 361 48 97 -212 -530 -926 -528 -665 -395 -207 4 556 821 684 750 653 227 388 -40 -450 -374 -293 -413 79 242 333 376 540 259 183 373 524 210 438 -144 -536 -789 -923 -604 -137 167 263 -85 40 19 -160 -290 135 163 203 406 587 363 480 3 74 -728 -482 -781 -795 -32 -235 -115 236 698 447 564 433 486 448 488 -146 -268 -257 -300 -537 -546 -624 -869 -503 -133 -210 -882 -939 -615 -497 -489 -232 -455 -195 -119 -30 -255 -240 7 -321 104 458 584 616 480 360 -69 -454 -562 -621 -981 -1031 -815 -36 147 -507 -384 -163 -726 -244 -162 251 241 553 763 1060 1341 952 802 372 182 -244 274 652 734 513 495 345 -7 773 127 -153 -421 -630 -748 213 66 93 -78 724 225 340 253 385 51 106 -230 -569 -993 -566 SQ 20201231T092435.0Z 7670.392072 184 1 50.08 2 88.72 116.50 81.04 306.53 0.00 1 0.00 1 0 22 4.068e-03 4.031e-03 1.584e-04 1.580e-04 1.657149e+04 1.196546e+01 1.064134e+03 -6.000000e+00 2.406253e+02 287.68 -2.00 20.00 -2.00 505.41 0.00e+00 2.099930e-03 4.525921e-06 1.326426e-04 -6.000000e+00 1.178296e-04 287.68 -2.00 20.00 -2.00 500.90 0.00e+00 1.061183e+00 3.128120e-03 1.067502e-01 -6.000000e+00 8.257290e-02 229.20 -2.00 3.11 -2.00 502.43 0.00e+00 17.877 0.047 489.00 513.00 1 8.1541e-01 2.3996e-04 2.7207e-02 -6.0000e+00 6.3549e-03 -1.3215e-02 5.9639e-05 2.9412e-03 -6.0000e+00 1.6308e-03 6.5394e-02 2.2937e-03 1.6268e-05 1.0396e-04 -6.0000e+00 4.7459e-04 2.0145e-03 1.8354e-04 11 8 0 10 0 0 22.32 22.35 1.47 0.00201 0.01792 505 101 1 4 0 98.968 27.88 20.01 22.35 -643 -358 16 151 447 715 814 748 573 345 185 -46 -259 -276 -317 -324 -74 230 174 119 216 297 302 439 342 204 251 -1 -443 -552 -528 -507 -65 207 23 -67 33 -63 -139 -50 34 136 226 314 409 351 187 37 -204 -488 -701 -816 -736 -365 -107 63 151 188 310 385 504 449 412 322 160 -93 -152 -215 -434 -513 -452 -452 -274 -129 -328 -577 -639 -537 -642 -558 -527 -532 -410 -292 -261 -303 -250 -122 -61 2 283 529 501 333 210 -30 -179 -416 -739 -920 -937 -589 -167 -148 -298 -303 -393 -348 -96 47 157 335 571 700 809 949 887 572 383 240 88 243 543 469 397 354 170 131 313 32 -246 -217 -334 -301 40 155 47 214 298 288 233 259 240 178 46 -225 -539 -680 -584 -591 -319 14 143 432 705 774 715 546 342 181 -44 -250 -265 -305 -315 -70 222 171 118 215 297 304 443 347 206 252 -1 -430 -527 -504 -491 -65 210 23 -66 34 -65 -141 -51 35 134 226 318 415 356 188 37 -199 -489 -689 -795 -721 -364 -104 63 153 191 316 393 516 463 425 330 163 -94 -151 -211 -423 -498 -439 -443 -271 -128 -325 -567 -619 -514 -612 -531 -505 -514 -401 -288 -260 -302 -249 -121 -61 2 284 531 499 325 199 -29 -167 -383 -675 -847 -884 -551 -162 -149 -307 -314 -406 -359 -95 47 158 340 583 717 835 991 935 605 403 248 90 246 549 476 406 363 175 135 321 33 -249 -218 -336 -306 41 163 48 223 314 308 252 281 261 193 50 -240 -569 -714 -614 SQ 20201231T092744.6Z 7670.394267 188 1 27.27 2 88.11 116.10 81.56 306.06 0.00 1 0.00 1 0 29 3.462e-03 3.433e-03 1.473e-04 1.470e-04 1.424412e+04 1.090094e+01 9.218321e+02 -6.000000e+00 2.047685e+02 287.68 -2.00 20.00 -2.00 505.38 0.00e+00 1.792594e-03 4.201343e-06 1.142033e-04 -6.000000e+00 1.002698e-04 287.68 -2.00 20.00 -2.00 500.83 0.00e+00 1.005576e+00 2.915500e-03 9.278088e-02 -6.000000e+00 7.026611e-02 229.20 -2.00 3.11 -2.00 502.37 0.00e+00 16.301 0.036 489.00 513.00 1 3.0000e-01 2.2363e-04 2.4444e-02 -6.0000e+00 5.4078e-03 -6.4298e-03 5.5927e-05 2.5690e-03 -6.0000e+00 1.3878e-03 1.3752e-01 2.1000e-03 1.5394e-05 9.0054e-05 -6.0000e+00 4.0387e-04 8.2226e-03 1.4755e-04 10 0 0 10 0 0 25.15 22.36 1.21 0.00822 0.02279 572 114 1 4 0 47.667 27.88 20.01 22.36 -537 -270 -15 136 310 620 652 619 475 289 191 -41 -170 -247 -202 -271 -78 166 149 79 213 203 251 398 333 185 213 28 -381 -436 -402 -407 -28 195 -71 -99 12 -31 -109 -57 34 76 211 282 346 267 173 26 -177 -451 -562 -716 -672 -327 -86 43 85 166 218 309 429 388 328 290 143 -51 -135 -144 -364 -432 -375 -398 -198 -81 -239 -530 -523 -469 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