File name: Pandora125s1_Cordoba_20210104_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142904.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210104_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210104T110736.0Z 7674.463612 15 1 50.08 2 68.75 104.24 53.51 314.54 0.00 1 0.00 1 0 25 6.010e-02 6.931e-03 3.831e-02 3.778e-03 3.156373e-01 1.917504e-03 3.316886e-03 -6.000000e+00 3.408219e-02 229.20 -2.00 3.11 -2.00 319.91 0.00e+00 -6.894306e-04 5.529233e-04 1.740011e-04 -6.000000e+00 1.528173e-03 287.83 -2.00 20.00 -2.00 319.06 0.00e+00 2.733 0.000 302.00 328.00 3 2.4658e+00 5.6167e-03 2.9997e-02 -6.0000e+00 8.4847e-02 3.4439e-02 6.6423e-03 1.4784e-02 -6.0000e+00 9.1973e-02 -1.5714e-02 4.8516e-03 7.2914e-03 -6.0000e+00 5.4913e-02 -2.5209e-03 2.4998e-03 2.1608e-03 -6.0000e+00 2.3422e-02 2.2373e-03 -8.9117e-04 1.1544e-04 2.3575e-05 -6.0000e+00 1.5557e-03 -3.4509e-04 0.0000e+00 11 8 0 10 0 0 99.95 22.12 0.31 -0.00035 -0.00704 301 60 1 5 0 166.357 27.67 20.00 22.12 -6494 -16558 13055 -23959 -3274 -39290 21720 -19670 9794 -15271 -7553 -6070 -8567 876 -10595 9558 -16537 12132 321 3569 1587 2306 1134 -460 -1018 1763 -2449 -1253 1190 -4329 4776 3770 4490 -2609 -820 -6823 54 -5186 -101 542 -400 -1513 -1426 1282 -3760 -812 -156 11 -3141 2560 1106 3077 1195 1220 403 2327 853 1114 297 -533 2042 1660 2459 527 2107 -1266 1605 -610 1359 150 559 683 -20 1630 456 1010 -239 39 -894 1490 -1902 -677 -3194 -680 -1178 -597 -370 -859 249 -23 239 -23 504 259 1392 -271 843 692 334 -168 12 -1298 -497 455 -929 -652 -754 -250 -970 378 -364 222 -262 520 -275 270 429 -352 720 -103 -267 -225 -44 -326 815 786 704 1165 667 233 472 278 -179 392 -469 -374 -645 601 -124 147 -195 -178 -348 -187 -606 376 -980 -97 -1536 474 -732 323 -709 -329 -260 -415 45 -710 595 -1433 823 26 289 136 203 102 -44 -107 190 -281 -136 117 -431 473 416 541 -362 -107 -892 7 -814 -18 117 -98 -398 -389 360 -1108 -233 -44 3 -882 680 313 927 393 444 155 900 344 451 118 -211 798 695 1119 266 1127 -660 748 -280 639 82 337 435 -13 1006 280 556 -119 18 -433 796 -1199 -471 -2466 -537 -996 -540 -355 -860 261 -24 227 -20 399 197 1157 -241 831 764 401 -213 14 -1436 -506 466 -1050 -784 -947 -328 -1351 558 -580 362 -441 816 -400 365 571 -491 1064 -164 -438 -364 -74 -525 1235 1137 964 1582 979 373 801 489 -323 732 -938 -792 -1406 1407 -296 341 -437 -381 -726 SS 20210104T113719.4Z 7674.484252 29 1 18.78 2 62.59 100.95 58.07 307.85 0.00 1 0.00 1 0 17 3.287e-02 6.787e-03 1.294e-02 2.882e-03 2.513717e-01 1.442089e-03 2.696089e-03 -6.000000e+00 1.864865e-02 229.20 -2.00 3.11 -2.00 318.56 0.00e+00 3.020080e-04 2.785181e-04 1.127288e-04 -6.000000e+00 8.359726e-04 287.83 -2.00 20.00 -2.00 317.67 0.00e+00 2.160 0.000 302.00 328.00 3 2.7258e+00 3.9355e-03 2.3754e-02 -6.0000e+00 4.6425e-02 4.8190e-02 4.4806e-03 1.1734e-02 -6.0000e+00 5.0319e-02 -1.9395e-02 2.8179e-03 5.7125e-03 -6.0000e+00 3.0044e-02 4.2159e-04 1.4359e-03 1.5875e-03 -6.0000e+00 1.2819e-02 3.2244e-03 -8.2735e-04 8.4694e-05 1.7405e-05 -6.0000e+00 8.5093e-04 -2.4734e-03 0.0000e+00 12 9 1 12 9 1 99.77 22.22 0.18 -0.00247 -0.00869 51 28 1 5 0 357.818 27.78 19.99 22.22 800 -6211 3300 -4603 -11048 -9618 -6483 1367 -192 -1038 -6363 -4290 -3582 3171 -164 2167 -2541 1546 -526 965 -737 -2926 430 -894 -318 -3809 1663 -2524 1194 -1891 30277 1328 3189 -1521 -2061 -1269 -2436 542 -352 292 -1025 -468 -1310 -252 -1307 1243 -1774 -127 -1085 -1619 687 1615 1684 713 590 -348 1849 434 1560 119 939 1386 1667 1552 1460 -729 -485 -990 -96 1984 182 960 -340 804 -168 442 -427 -125 141 -465 -770 -709 -1471 -1470 -941 -847 149 -485 119 -441 424 -23 114 -114 76 359 228 290 253 -205 -382 -386 -726 242 -385 -536 -1056 -335 -311 347 -176 307 575 247 -2 151 517 20 463 -257 -209 -474 -4 141 554 867 427 886 548 411 280 164 -24 73 -357 -376 -331 318 -319 -74 334 -374 -328 55 -519 263 -386 -876 -722 -478 104 -17 -99 -640 -415 -373 353 -22 314 -408 245 -89 166 -133 -536 76 -168 -63 -818 343 -519 218 -339 4303 273 699 -349 -482 -275 -560 139 -110 101 -402 -192 -561 -108 -566 558 -809 -55 -465 -690 297 743 823 371 319 -193 1028 245 855 65 518 810 1058 1061 1022 -488 -294 -613 -61 1311 136 754 -273 621 -132 310 -270 -73 83 -310 -583 -595 -1340 -1399 -948 -919 160 -543 134 -517 459 -23 110 -104 72 372 246 347 326 -266 -468 -464 -815 274 -478 -711 -1370 -451 -438 518 -280 497 901 362 -3 202 678 28 676 -406 -342 -772 -6 214 794 1271 593 1212 801 648 466 281 -42 122 -637 -710 -643 627 -641 -145 630 -734 -628 SS 20210104T120632.0Z 7674.504537 44 1 18.00 2 56.46 97.71 62.96 302.03 0.00 1 0.00 1 0 17 2.470e-02 8.151e-03 1.685e-02 5.252e-03 2.096209e-01 2.619980e-03 2.256324e-03 -6.000000e+00 1.400855e-02 229.20 -2.00 3.11 -2.00 317.93 0.00e+00 5.265834e-04 4.216462e-04 1.858369e-04 -6.000000e+00 6.279968e-04 287.83 -2.00 20.00 -2.00 317.01 0.00e+00 1.804 0.000 302.00 328.00 3 4.1627e+00 7.0395e-03 1.9808e-02 -6.0000e+00 3.4874e-02 5.4576e-02 7.9614e-03 9.7308e-03 -6.0000e+00 3.7799e-02 -2.3914e-02 4.7480e-03 4.7356e-03 -6.0000e+00 2.2569e-02 4.3767e-03 2.3364e-03 1.3228e-03 -6.0000e+00 9.6291e-03 1.1506e-03 -8.6565e-04 1.5280e-04 1.4594e-05 -6.0000e+00 6.3924e-04 -2.1190e-03 0.0000e+00 12 9 1 12 9 1 93.98 22.28 -0.31 -0.00212 -0.00862 12 7 1 5 0 1371.466 27.88 20.00 22.28 -3389 1858 -10409 -3980 -10049 715 -3098 -3037 -1320 3440 -9734 1339 1785 -4073 8445 -2834 540 -1847 5322 152 3033 -1928 -751 -207 -213 -3421 -852 2259 -955 1889 11692 6414 816 2249 -4080 -731 -3462 850 -1375 36 -747 637 -744 -646 1141 -1961 1286 -772 36 -1247 1011 248 937 613 1942 -623 896 1612 -534 -130 2327 1328 1397 945 707 -107 -457 -1025 673 2357 182 -383 502 595 803 -876 -254 -1593 492 -1161 -44 -1066 -2069 -1516 -927 192 -723 -14 -207 759 -1210 1354 -1863 -345 -273 -303 -524 1029 692 -556 -856 -442 -676 605 609 -810 -996 -718 33 -150 173 462 395 159 676 1140 361 -125 -509 932 -727 376 324 582 -75 782 51 1409 50 268 237 -309 211 -177 -77 -866 -506 144 413 104 29 -728 -84 -396 231 -1524 -528 -1249 72 -326 -352 -170 453 -1454 174 247 -676 1405 -585 113 -403 1118 35 691 -457 -175 -50 -54 -933 -229 591 -237 431 2459 1520 220 630 -1156 -187 -949 256 -506 16 -359 318 -387 -340 587 -1038 647 -384 17 -590 481 127 505 347 1121 -375 541 1025 -340 -81 1443 883 1007 733 558 -79 -306 -652 433 1687 148 -330 434 500 635 -677 -173 -1018 310 -826 -35 -944 -1986 -1509 -918 203 -818 -16 -244 865 -1392 1379 -1766 -323 -264 -301 -577 1234 896 -728 -1058 -499 -763 688 755 -1018 -1309 -982 47 -225 273 740 612 244 943 1469 461 -166 -729 1421 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