File name: Pandora125s1_Cordoba_20210107_L2Fit_fout2c3d20170323p1-8.txt File generation date: 20250228T141446.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210107_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 214 355 Nominal wavelengths inside fitting window [nm]: 305.0972 305.2384 305.3797 305.5210 305.6622 305.8035 305.9447 306.0859 306.2272 306.3684 306.5095 306.6507 306.7919 306.9330 307.0742 307.2153 307.3564 307.4975 307.6386 307.7797 307.9208 308.0619 308.2029 308.3439 308.4850 308.6260 308.7670 308.9080 309.0490 309.1899 309.3309 309.4719 309.6128 309.7537 309.8946 310.0355 310.1764 310.3173 310.4582 310.5990 310.7399 310.8807 311.0215 311.1624 311.3032 311.4439 311.5847 311.7255 311.8662 312.0070 312.1477 312.2884 312.4291 312.5698 312.7105 312.8512 312.9919 313.1325 313.2732 313.4138 313.5544 313.6950 313.8356 313.9762 314.1168 314.2573 314.3979 314.5384 314.6789 314.8194 314.9599 315.1004 315.2409 315.3814 315.5218 315.6623 315.8027 315.9431 316.0835 316.2239 316.3643 316.5047 316.6451 316.7854 316.9257 317.0661 317.2064 317.3467 317.4870 317.6273 317.7675 317.9078 318.0481 318.1883 318.3285 318.4687 318.6089 318.7491 318.8893 319.0295 319.1696 319.3098 319.4499 319.5900 319.7301 319.8702 320.0103 320.1504 320.2904 320.4305 320.5705 320.7105 320.8505 320.9905 321.1305 321.2705 321.4105 321.5504 321.6904 321.8303 321.9702 322.1101 322.2500 322.3899 322.5298 322.6697 322.8095 322.9494 323.0892 323.2290 323.3688 323.5086 323.6484 323.7881 323.9279 324.0676 324.2074 324.3471 324.4868 324.6265 324.7662 324.9058 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210107T102057.0Z 7677.431216 199 1 50.05 2 78.69 109.36 26.35 26.91 0.00 1 0.00 1 0 17 3.203e-01 8.429e-03 1.924e-01 3.969e-03 5.463021e-01 2.149419e-03 5.513632e-03 -6.000000e+00 1.830880e-01 229.21 -2.00 3.11 -2.00 321.48 0.00e+00 1.359565e-03 1.108031e-03 9.972687e-04 -6.000000e+00 8.201389e-03 287.98 -2.00 20.00 -2.00 320.85 0.00e+00 4.923 0.001 302.00 328.00 3 -6.4903e-01 7.8965e-03 5.3825e-02 -6.0000e+00 4.5680e-01 1.2958e-01 1.0740e-02 2.6824e-02 -6.0000e+00 4.9553e-01 -1.2285e-01 1.0166e-02 1.4018e-02 -6.0000e+00 2.9426e-01 3.4629e-02 4.7954e-03 4.4645e-03 -6.0000e+00 1.2597e-01 4.9990e-03 8.7601e-04 1.2124e-04 5.5174e-05 -6.0000e+00 8.4707e-03 2.2361e-02 0.0000e+00 11 8 0 10 0 0 32.08 22.20 0.35 0.02236 0.02894 442 88 1 5 0 113.233 27.78 19.98 22.20 -75826 95409 -151124 4005 -170565 63530 -158316 900000 -67589 -59784 -102296 -86381 -27078 -33924 390 -44400 -19624 -31984 4212 4666 -8687 -29605 53395 -38328 -4338 -8860 -15405 1541 -35948 18134 -27445 20363 -17560 16771 -7559 -827 -19932 -814 -1799 3544 2733 1954 -949 -1868 10159 -6589 11915 -1813 6905 -5024 9352 -865 6268 226 3407 3350 4005 382 871 3733 -369 5580 2884 3899 -363 5706 -2143 2521 3192 1121 2576 1724 1431 1229 2678 -3051 744 -2613 -632 -2219 650 -2076 -273 -448 -1164 254 -249 652 -908 1092 -72 1380 -1178 1319 -668 392 210 350 -990 -397 -461 -209 -99 -1473 -685 -1586 -840 -1676 542 -423 501 -152 568 -302 116 543 40 284 -18 -110 -550 376 -81 903 332 935 822 780 723 716 416 -61 73 -569 -429 -327 480 -311 6 28 10 -327 -528 369 -2526 15 -2931 246 -2794 900000 -643 -549 -1501 -1267 -275 -459 5 -916 -345 -691 67 77 -165 -702 620 -1219 -105 -233 -422 34 -1155 378 -1067 569 -834 558 -303 -33 -1104 -46 -124 267 225 171 -88 -185 906 -704 1071 -192 696 -618 1113 -125 915 37 597 609 730 70 156 657 -73 1165 695 997 -95 1404 -569 683 991 400 961 653 522 416 801 -878 211 -820 -227 -949 308 -1117 -153 -268 -752 172 -175 459 -631 696 -45 805 -700 832 -492 328 201 368 -1072 -403 -424 -174 -87 -1425 -701 -1720 -960 -2084 729 -633 786 -240 856 -429 155 720 55 420 -28 -186 -907 593 -124 1314 466 1248 1118 1180 1226 1325 815 -126 157 -1323 -1055 -824 1224 -860 16 70 24 -759 SS 20210107T102800.1Z 7677.436112 202 1 50.12 2 77.27 108.54 25.70 23.30 0.00 1 0.00 1 0 25 2.180e-01 6.656e-03 9.007e-02 2.753e-03 4.949349e-01 1.468997e-03 4.989348e-03 -6.000000e+00 1.239726e-01 229.21 -2.00 3.11 -2.00 321.20 0.00e+00 1.881658e-03 6.809747e-04 4.746438e-04 -6.000000e+00 5.562601e-03 287.98 -2.00 20.00 -2.00 320.52 0.00e+00 4.414 0.001 302.00 328.00 3 -6.8952e-01 5.0845e-03 4.8169e-02 -6.0000e+00 3.0863e-01 1.0635e-01 6.6538e-03 2.3662e-02 -6.0000e+00 3.3451e-01 -8.7437e-02 6.0375e-03 1.2267e-02 -6.0000e+00 1.9959e-01 2.0674e-02 2.9204e-03 4.4553e-03 -6.0000e+00 8.5745e-02 8.7550e-03 8.6247e-04 8.4397e-05 4.9633e-05 -6.0000e+00 5.6917e-03 2.2180e-02 0.0000e+00 11 8 0 10 0 0 28.22 22.20 0.27 0.02218 0.02866 594 118 1 5 0 84.218 27.78 20.01 22.20 -8560 -112397 -19455 -92919 -30435 -93243 -78389 -56227 -78018 -28031 -84780 -31029 -46119 -20006 -34300 -3574 -31866 -2290 -30480 -3555 -10216 -5707 -14257 -13450 2236 -11804 -6157 -28602 -3488 -27148 8633 -7591 6519 -323 -6861 -7888 1739 -635 1702 768 -2909 663 -3539 7977 -153 1950 533 1938 -652 2938 973 3930 501 2441 3195 501 2904 475 3329 -732 4578 470 5816 1516 2137 -239 479 -489 762 1884 1152 1783 410 841 -937 1890 -1953 468 -1591 -377 -1073 -1068 -664 -1099 -258 -991 485 170 536 53 1483 -585 834 0 -50 -386 257 -50 -203 48 -879 -483 -691 -71 -1777 -406 -1193 -294 -107 31 -334 322 126 22 426 -27 281 -28 232 -807 -24 -7 290 188 1143 226 1380 768 268 607 114 363 -284 -74 -536 -1 111 59 -116 -9 -204 -335 -48 -2036 -141 -1289 -208 -1220 -991 -654 -1248 -282 -1555 -402 -861 -355 -841 -73 -930 -54 -1003 -93 -287 -155 -449 -457 69 -434 -219 -1207 -114 -1239 321 -382 315 -16 -352 -428 99 -47 151 79 -335 77 -444 899 -19 239 67 244 -91 425 159 682 97 492 663 110 631 103 688 -159 1070 128 1678 486 661 -71 141 -154 273 749 489 758 170 341 -347 617 -637 158 -636 -173 -564 -617 -404 -716 -179 -734 368 130 422 39 997 -374 517 0 -38 -339 256 -55 -225 50 -892 -447 -640 -70 -1920 -454 -1423 -372 -150 47 -536 511 191 32 568 -38 415 -44 387 -1377 -40 -11 446 277 1598 304 1991 1148 448 1097 218 717 -594 -166 -1270 -2 292 156 -301 -22 -474 -758 SS 20210107T103351.0Z 7677.440174 205 1 50.07 2 76.09 107.86 25.23 20.18 0.00 1 0.00 1 0 25 1.364e-01 5.331e-03 5.685e-02 2.153e-03 4.597297e-01 1.134430e-03 4.630129e-03 -6.000000e+00 7.754095e-02 229.21 -2.00 3.11 -2.00 320.96 0.00e+00 1.485507e-03 4.848091e-04 5.658505e-04 -6.000000e+00 3.479179e-03 287.98 -2.00 20.00 -2.00 320.26 0.00e+00 4.064 0.001 302.00 328.00 3 -6.9974e-01 3.7760e-03 4.4369e-02 -6.0000e+00 1.9304e-01 8.8773e-02 4.8393e-03 2.1737e-02 -6.0000e+00 2.0923e-01 -6.7437e-02 4.2622e-03 1.1265e-02 -6.0000e+00 1.2484e-01 1.4308e-02 2.0946e-03 3.8358e-03 -6.0000e+00 5.3632e-02 1.2730e-02 1.0053e-03 6.5821e-05 4.2621e-05 -6.0000e+00 3.5598e-03 2.2011e-02 0.0000e+00 10 0 0 10 0 0 26.83 22.22 0.28 0.02201 0.02957 717 143 1 5 0 69.721 27.78 20.01 22.22 -78537 -8279 -38340 -23942 -45455 -49470 -40343 -23461 -35988 -49970 -31294 -31119 -9743 -37525 -12502 -22559 8398 -19486 3029 -3708 4754 -14030 -5868 -14893 -9728 -10510 -15038 -3545 -19761 1874 -10453 -301 -7466 -2818 -5957 63 -8826 -3010 138 -1376 822 -1559 681 -597 4040 -1486 1737 -2103 4406 -1240 3873 1633 2466 1935 1243 692 847 1385 1338 1371 1544 2817 1338 2983 42 2148 -106 1711 779 789 1368 627 1071 189 535 -311 537 -760 75 -917 -522 -1328 -1124 -1401 -861 -399 -157 286 -148 711 477 785 153 780 4 415 -24 122 -323 -168 -653 -927 -127 -473 -1013 -958 -630 -655 135 -322 -6 119 323 11 354 397 141 166 -305 -195 -363 222 97 529 453 517 932 1019 314 384 -13 -76 25 -260 -275 -238 275 -23 9 -13 -295 -245 -1278 -73 -463 -228 -493 -596 -497 -281 -539 -889 -474 -540 -167 -1038 -320 -712 209 -690 90 -124 152 -546 -225 -676 -446 -501 -732 -145 -943 79 -572 -17 -521 -184 -378 4 -700 -274 15 -171 108 -219 96 -86 591 -231 262 -334 672 -214 702 329 530 442 296 171 211 353 334 347 418 840 450 1043 15 688 -34 573 302 343 628 309 505 84 212 -113 184 -279 31 -450 -289 -813 -726 -965 -634 -310 -134 245 -124 551 341 520 100 543 3 372 -24 136 -367 -190 -676 -882 -120 -486 -1117 -1106 -766 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