File name: Pandora125s1_Cordoba_20210112_L2Fit_fout2c3d20170323p1-8.txt File generation date: 20250228T141421.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210112_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 214 355 Nominal wavelengths inside fitting window [nm]: 305.0972 305.2384 305.3797 305.5210 305.6622 305.8035 305.9447 306.0859 306.2272 306.3684 306.5095 306.6507 306.7919 306.9330 307.0742 307.2153 307.3564 307.4975 307.6386 307.7797 307.9208 308.0619 308.2029 308.3439 308.4850 308.6260 308.7670 308.9080 309.0490 309.1899 309.3309 309.4719 309.6128 309.7537 309.8946 310.0355 310.1764 310.3173 310.4582 310.5990 310.7399 310.8807 311.0215 311.1624 311.3032 311.4439 311.5847 311.7255 311.8662 312.0070 312.1477 312.2884 312.4291 312.5698 312.7105 312.8512 312.9919 313.1325 313.2732 313.4138 313.5544 313.6950 313.8356 313.9762 314.1168 314.2573 314.3979 314.5384 314.6789 314.8194 314.9599 315.1004 315.2409 315.3814 315.5218 315.6623 315.8027 315.9431 316.0835 316.2239 316.3643 316.5047 316.6451 316.7854 316.9257 317.0661 317.2064 317.3467 317.4870 317.6273 317.7675 317.9078 318.0481 318.1883 318.3285 318.4687 318.6089 318.7491 318.8893 319.0295 319.1696 319.3098 319.4499 319.5900 319.7301 319.8702 320.0103 320.1504 320.2904 320.4305 320.5705 320.7105 320.8505 320.9905 321.1305 321.2705 321.4105 321.5504 321.6904 321.8303 321.9702 322.1101 322.2500 322.3899 322.5298 322.6697 322.8095 322.9494 323.0892 323.2290 323.3688 323.5086 323.6484 323.7881 323.9279 324.0676 324.2074 324.3471 324.4868 324.6265 324.7662 324.9058 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210112T140558.9Z 7682.587487 120 1 49.81 2 32.30 80.30 24.38 79.97 0.00 1 0.00 1 0 17 1.169e-02 6.449e-03 6.067e-03 2.801e-03 1.351580e-01 1.399488e-03 1.469010e-03 -6.000000e+00 6.648734e-03 229.21 -2.00 3.11 -2.00 316.96 0.00e+00 1.525022e-04 1.775223e-04 1.847964e-05 -6.000000e+00 2.986818e-04 288.23 -2.00 20.00 -2.00 316.05 0.00e+00 1.182 0.000 302.00 328.00 3 3.2044e+00 3.6907e-03 1.2939e-02 -6.0000e+00 1.6551e-02 4.0066e-02 4.1383e-03 6.2828e-03 -6.0000e+00 1.7939e-02 -4.9115e-03 2.3882e-03 3.0561e-03 -6.0000e+00 1.0705e-02 -5.1206e-03 1.1223e-03 8.7239e-04 -6.0000e+00 4.5991e-03 6.3246e-03 1.0071e-03 8.1849e-05 9.9928e-06 -6.0000e+00 3.0533e-04 2.3586e-02 0.0000e+00 11 9 0 11 8 0 99.96 22.27 0.20 0.02359 0.03115 117 23 1 5 0 425.714 27.88 20.01 22.27 -2996 -871 474 -2529 -262 -4488 3522 -2892 3290 -1497 2835 136 235 -632 986 -1678 987 374 1147 990 -1277 1513 -1872 526 -704 2122 -350 720 -205 3039 1364 2083 1753 -1468 -920 -3089 317 -1834 -889 -1385 -349 -1011 -68 -1030 -606 -914 -235 -72 -909 1512 -299 1115 285 889 -213 857 -347 1064 746 904 1162 1126 1503 18 207 -77 612 72 1900 128 586 -690 779 -169 886 612 436 658 -1008 -264 -1112 -1148 -2043 -496 -785 -290 -621 -127 -214 273 164 -212 514 424 629 -67 1364 -469 -42 -458 -479 201 888 -232 -826 -689 -1024 -480 -92 77 -116 138 -456 268 19 574 175 279 23 -269 -219 -44 238 553 1250 142 1660 314 716 434 315 -106 219 28 -55 -378 130 -88 -452 124 -748 -153 -653 -192 103 -497 -45 -791 626 -617 711 -336 603 31 59 -171 286 -518 308 120 374 332 -434 493 -650 187 -263 776 -125 240 -64 912 435 696 615 -504 -290 -1031 116 -818 -464 -804 -210 -626 -42 -640 -387 -573 -140 -41 -502 828 -176 680 183 606 -148 599 -246 730 506 623 844 881 1242 15 161 -56 411 49 1436 109 526 -635 691 -144 705 433 282 420 -718 -208 -973 -1072 -2000 -508 -870 -340 -760 -156 -257 319 173 -201 472 397 638 -71 1578 -591 -53 -568 -546 214 966 -278 -1064 -924 -1433 -692 -138 122 -184 209 -676 357 23 692 220 377 33 -412 -337 -65 359 787 1679 181 2166 412 992 628 463 -167 354 45 -94 -707 248 -171 -863 228 -1347 -268 SS 20210112T141237.7Z 7682.592104 123 1 15.49 2 30.91 79.01 23.02 78.54 0.00 1 0.00 1 0 17 7.606e-03 5.696e-03 1.428e-03 8.145e-04 1.342335e-01 4.086163e-04 1.461581e-03 -6.000000e+00 4.325241e-03 229.21 -2.00 3.11 -2.00 316.01 0.00e+00 1.524369e-04 4.289380e-05 1.461410e-05 -6.000000e+00 1.942795e-04 288.23 -2.00 20.00 -2.00 315.19 0.00e+00 1.165 0.000 302.00 328.00 3 6.4489e-01 1.0631e-03 1.2767e-02 -6.0000e+00 1.0767e-02 3.5002e-02 1.1856e-03 6.2242e-03 -6.0000e+00 1.1669e-02 -7.0320e-03 6.7842e-04 3.0271e-03 -6.0000e+00 6.9637e-03 -4.8957e-03 3.1001e-04 8.5489e-04 -6.0000e+00 2.9923e-03 8.3534e-02 1.1836e-03 2.3077e-05 1.0239e-05 -6.0000e+00 1.9858e-04 2.2314e-02 0.0000e+00 12 1 1 12 9 1 97.60 22.30 0.21 0.02231 0.03121 228 145 1 5 0 66.902 27.88 20.02 22.30 -1314 -255 -909 -1412 -801 -85 1023 2337 1813 290 -476 -39 -259 90 128 -991 -376 -280 139 416 -237 309 265 -56 397 186 443 666 816 1684 1585 2490 1175 -527 -984 -1355 -1216 -584 -687 -1418 -1325 -981 -1221 -833 -655 -1043 -659 -817 -386 239 753 552 928 499 924 839 712 648 472 983 987 1186 1539 525 -167 396 14 754 903 226 92 -51 292 297 263 486 72 348 108 -876 -849 -1718 -1524 -966 -882 -553 -303 -207 -109 108 340 -79 515 837 355 428 484 132 -258 -187 -608 -254 197 -173 -812 -525 -701 -435 186 62 23 -80 77 -151 278 434 363 259 -9 -473 -333 -74 69 555 779 494 1227 882 560 537 84 147 199 -197 -353 -123 270 -197 -245 -196 -399 -457 -382 -76 -262 -359 -180 -19 244 619 520 84 -132 -11 -82 31 49 -396 -150 -114 58 176 -100 128 113 -25 184 87 197 269 306 661 651 1002 501 -231 -401 -573 -547 -311 -432 -937 -915 -691 -871 -587 -458 -716 -458 -542 -246 154 510 393 686 381 709 654 557 498 358 755 801 1034 1416 492 -145 305 11 585 736 206 89 -50 278 269 230 376 54 260 89 -759 -806 -1759 -1517 -1016 -1000 -665 -378 -261 -134 123 373 -78 502 830 358 474 588 162 -337 -229 -690 -290 230 -206 -1038 -698 -971 -623 261 91 35 -121 107 -205 346 529 461 354 -12 -687 -483 -105 100 758 1008 649 1570 1188 746 744 118 209 291 -306 -581 -208 466 -346 -424 -329 -651 -729 SS 20210112T141846.3Z 7682.596369 126 1 26.57 2 29.63 77.75 21.78 77.11 0.00 1 0.00 1 0 17 7.339e-03 5.420e-03 9.525e-04 5.042e-04 1.316707e-01 2.520103e-04 1.434036e-03 -6.000000e+00 4.172521e-03 229.21 -2.00 3.11 -2.00 316.37 0.00e+00 1.623337e-04 2.843466e-05 1.505528e-05 -6.000000e+00 1.874357e-04 288.23 -2.00 20.00 -2.00 315.51 0.00e+00 1.150 0.000 302.00 328.00 3 7.6956e-03 6.5898e-04 1.2587e-02 -6.0000e+00 1.0387e-02 2.8460e-02 7.3662e-04 6.1197e-03 -6.0000e+00 1.1258e-02 -5.4217e-03 4.2199e-04 2.9765e-03 -6.0000e+00 6.7181e-03 -5.2523e-03 1.9451e-04 8.4124e-04 -6.0000e+00 2.8863e-03 1.6139e-01 1.0148e-03 1.4385e-05 9.7701e-06 -6.0000e+00 1.9160e-04 2.3203e-02 0.0000e+00 12 1 1 12 1 1 99.97 22.33 0.25 0.02320 0.03083 901 323 1 5 0 29.135 27.88 20.01 22.33 -931 -489 208 -2089 -43 -530 1252 1291 2146 397 421 20 -561 313 -168 -617 -625 -242 -117 516 -458 486 -57 87 47 259 121 573 850 1869 1595 1687 1180 -1105 -573 -1540 -1159 -699 -672 -1324 -1236 -962 -1088 -773 -697 -802 -819 -670 -716 597 502 921 968 610 670 930 628 614 700 801 980 1074 1507 553 65 117 -105 468 920 204 243 14 444 410 195 618 -86 499 -134 -629 -946 -1567 -1542 -891 -908 -407 -413 -136 -10 120 336 -82 680 720 372 317 646 17 -203 -296 -512 -267 242 -89 -889 -517 -788 -363 98 56 -49 -40 -76 -115 236 389 228 315 89 -482 -277 -104 162 549 778 338 1281 793 536 521 49 39 96 -109 -277 -77 204 -102 -259 -60 -489 -397 -246 -133 54 -488 -9 -107 271 315 559 104 105 5 -162 100 -59 -224 -227 -89 -44 199 -177 183 -22 35 20 110 49 222 305 659 588 655 482 -438 -208 -585 -499 -357 -383 -842 -821 -652 -747 -525 -470 -529 -545 -425 -439 366 326 625 683 444 492 692 470 451 507 589 760 895 1326 495 54 92 -77 344 757 178 223 13 427 374 161 480 -62 350 -104 -546 -852 -1516 -1551 -946 -1041 -493 -492 -163 -12 138 371 -81 622 671 377 353 788 21 -250 -365 -583 -286 265 -106 -1146 -692 -1100 -523 147 83 -73 -60 -107 -156 295 476 290 431 132 -705 -404 -157 236 752 1009 443 1633 1065 766 775 75 60 151 -170 -456 -130 352 -180 -450 -101 -857 -679 SS 20210112T142446.5Z 7682.600538 129 1 20.92 2 28.39 76.45 20.57 75.59 0.00 1 0.00 1 0 17 7.478e-03 5.558e-03 1.180e-03 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