File name: Pandora125s1_Cordoba_20210112_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142824.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210112_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210112T140558.9Z 7682.587487 120 1 49.81 2 32.30 80.30 24.38 79.97 0.00 1 0.00 1 0 17 1.215e-02 6.501e-03 6.165e-03 2.809e-03 1.358077e-01 1.400287e-03 1.489166e-03 -6.000000e+00 6.895849e-03 229.21 -2.00 3.11 -2.00 316.96 0.00e+00 1.942431e-04 1.772283e-04 2.081598e-05 -6.000000e+00 3.095738e-04 288.23 -2.00 20.00 -2.00 316.05 0.00e+00 1.182 0.000 302.00 328.00 3 4.0716e+00 3.6936e-03 1.2964e-02 -6.0000e+00 1.7165e-02 4.1241e-02 4.1382e-03 6.3357e-03 -6.0000e+00 1.8601e-02 -5.5831e-03 2.3845e-03 3.0877e-03 -6.0000e+00 1.1109e-02 -4.8472e-03 1.1169e-03 8.7071e-04 -6.0000e+00 4.7433e-03 2.6385e-03 -5.8975e-04 8.1735e-05 1.0097e-05 -6.0000e+00 3.1457e-04 -4.1823e-03 0.0000e+00 11 9 0 11 8 0 99.96 22.27 0.20 -0.00418 -0.00861 117 23 1 5 0 425.714 27.88 20.01 22.27 1680 -2655 -1067 -498 -3986 -966 -4250 4244 -2294 3278 -2156 2438 560 833 -44 1305 -1777 958 434 1222 963 -1545 1430 -1735 631 -699 1801 -1069 -33 -618 3106 1557 2350 1698 -2073 -1140 -2668 1070 -982 -285 -1146 -307 -1033 -186 -1161 -722 -1158 -509 -325 -1022 1657 -111 1226 399 900 -209 850 -441 931 682 954 1339 1290 1586 -121 -136 -349 504 254 2192 289 641 -730 677 -344 635 371 308 726 -835 -123 -1009 -1101 -1996 -414 -725 -260 -611 -142 -254 212 100 -266 501 433 650 -56 1377 -455 3 -414 -426 212 833 -292 -868 -738 -1058 -525 -146 46 -81 245 -290 436 133 577 99 138 -90 -305 -187 17 355 671 1384 282 1609 157 588 365 320 -123 105 -144 -169 -444 72 -75 -355 221 -631 -138 319 -580 -244 -108 -785 -165 -751 756 -491 710 -485 519 127 209 -12 380 -549 300 140 399 324 -527 467 -604 225 -261 661 -382 -11 -194 935 497 787 597 -714 -361 -892 393 -439 -149 -667 -185 -642 -116 -722 -462 -728 -304 -185 -566 909 -66 750 256 615 -145 596 -314 641 464 659 975 1011 1313 -102 -106 -254 339 174 1660 248 577 -674 603 -293 506 263 199 464 -595 -98 -884 -1031 -1960 -425 -806 -306 -751 -176 -306 248 106 -252 461 407 660 -60 1597 -575 4 -515 -488 227 907 -351 -1121 -992 -1485 -759 -221 72 -129 372 -431 583 164 697 125 187 -133 -470 -287 27 537 958 1863 361 2105 207 817 530 472 -194 170 -233 -290 -833 138 -145 -681 408 -1138 -242 SS 20210112T141237.7Z 7682.592104 123 1 15.49 2 30.91 79.01 23.02 78.54 0.00 1 0.00 1 0 17 8.400e-03 5.847e-03 1.447e-03 8.172e-04 1.346019e-01 4.092559e-04 1.478637e-03 -6.000000e+00 4.765687e-03 229.21 -2.00 3.11 -2.00 315.99 0.00e+00 2.299055e-04 4.279635e-05 2.070029e-05 -6.000000e+00 2.139735e-04 288.23 -2.00 20.00 -2.00 315.19 0.00e+00 1.165 0.000 302.00 328.00 3 1.5126e+00 1.0651e-03 1.2784e-02 -6.0000e+00 1.1863e-02 3.5706e-02 1.1873e-03 6.2646e-03 -6.0000e+00 1.2856e-02 -7.5910e-03 6.7854e-04 3.0523e-03 -6.0000e+00 7.6778e-03 -4.6209e-03 3.0849e-04 8.5904e-04 -6.0000e+00 3.2776e-03 3.4847e-02 -7.8161e-04 2.3052e-05 1.0416e-05 -6.0000e+00 2.1743e-04 -3.0780e-03 0.0000e+00 12 1 1 12 9 1 97.60 22.30 0.21 -0.00308 -0.00895 228 145 1 5 0 66.902 27.88 20.02 22.30 28 -882 -324 -1728 -2721 -1418 198 1803 2957 1826 -330 -857 385 367 705 472 -1031 -361 -176 257 450 -465 262 426 54 386 -128 -245 -45 441 1758 1797 2774 1155 -1090 -1171 -933 -473 224 -129 -1217 -1306 -1001 -1324 -956 -764 -1267 -894 -1035 -476 385 940 671 1032 503 917 816 606 507 401 1025 1143 1341 1621 409 -466 147 -79 917 1153 356 135 -91 199 138 46 285 -43 396 238 -766 -762 -1673 -1491 -912 -845 -533 -299 -218 -130 77 315 -93 510 832 341 408 462 139 -213 -117 -529 -225 135 -258 -860 -576 -738 -486 124 30 66 44 260 46 403 428 265 96 -143 -509 -286 4 206 701 934 650 1181 706 420 462 88 127 72 -395 -481 -196 200 -188 -136 -75 -267 -435 7 -257 -96 -499 -694 -319 44 431 786 525 -96 -238 110 116 248 181 -413 -144 -72 107 191 -198 109 182 24 179 -60 -109 -18 166 692 740 1120 495 -480 -478 -396 -213 119 -81 -807 -904 -707 -948 -676 -536 -927 -623 -689 -304 248 639 480 765 385 705 638 476 391 305 789 930 1172 1497 385 -406 114 -61 712 943 326 131 -89 190 125 40 221 -33 296 196 -665 -727 -1718 -1488 -962 -961 -643 -374 -275 -161 88 347 -92 498 827 345 452 564 171 -279 -144 -602 -257 158 -308 -1103 -768 -1026 -698 174 43 98 66 363 62 503 524 338 132 -198 -742 -416 6 300 960 1213 857 1515 954 561 642 125 181 105 -615 -794 -332 346 -331 -235 -127 -437 -696 SS 20210112T141846.3Z 7682.596369 126 1 26.57 2 29.63 77.75 21.78 77.11 0.00 1 0.00 1 0 17 8.061e-03 5.521e-03 9.658e-04 5.054e-04 1.320816e-01 2.520899e-04 1.450841e-03 -6.000000e+00 4.574576e-03 229.21 -2.00 3.11 -2.00 316.37 0.00e+00 2.329114e-04 2.838704e-05 1.838410e-05 -6.000000e+00 2.053427e-04 288.23 -2.00 20.00 -2.00 315.51 0.00e+00 1.150 0.000 302.00 328.00 3 8.7537e-01 6.5927e-04 1.2607e-02 -6.0000e+00 1.1387e-02 2.9147e-02 7.3646e-04 6.1635e-03 -6.0000e+00 1.2339e-02 -6.0448e-03 4.2158e-04 3.0018e-03 -6.0000e+00 7.3693e-03 -4.9033e-03 1.9355e-04 8.4448e-04 -6.0000e+00 3.1470e-03 6.7332e-02 -5.4892e-04 1.4383e-05 9.9181e-06 -6.0000e+00 2.0865e-04 -5.0419e-03 0.0000e+00 12 1 1 12 1 1 99.97 22.33 0.25 -0.00504 -0.00917 901 323 1 5 0 29.135 27.88 20.01 22.33 27 -490 -575 -639 -3418 -659 -244 2048 1932 2172 -220 44 458 63 947 182 -671 -613 -138 8 546 -696 445 98 201 31 -52 -574 -151 457 1945 1797 1964 1156 -1697 -776 -1113 -406 128 -96 -1114 -1218 -985 -1198 -901 -809 -1038 -1067 -906 -820 736 690 1037 1070 610 659 909 523 472 630 846 1139 1228 1587 430 -255 -147 -207 636 1186 342 290 -26 344 241 -36 403 -210 552 6 -508 -853 -1518 -1505 -831 -863 -379 -409 -150 -40 79 295 -109 670 719 370 314 639 26 -160 -230 -443 -238 191 -163 -932 -565 -823 -409 43 28 -4 78 99 73 356 386 142 166 -33 -514 -230 -29 293 688 926 493 1240 628 403 451 56 22 -24 -296 -400 -146 137 -93 -154 51 -364 -380 6 -130 -156 -166 -800 -134 -49 445 472 567 -58 11 119 18 302 64 -244 -223 -51 3 211 -269 168 38 82 13 -22 -233 -59 164 686 664 764 473 -674 -283 -424 -175 66 -55 -710 -811 -669 -824 -612 -546 -686 -712 -576 -503 452 448 705 757 444 485 678 392 348 457 623 885 1026 1400 386 -211 -115 -151 469 979 299 267 -24 332 221 -30 314 -150 387 4 -442 -770 -1472 -1516 -884 -991 -461 -488 -180 -50 91 327 -108 614 671 376 351 782 32 -198 -285 -506 -255 209 -195 -1204 -757 -1151 -591 64 42 -6 118 139 99 446 473 182 227 -50 -753 -358 -44 428 944 1205 649 1585 845 577 672 86 34 -38 -461 -660 -248 237 -164 -267 87 -640 -652 SS 20210112T142446.5Z 7682.600538 129 1 20.92 2 28.39 76.45 20.57 75.59 0.00 1 0.00 1 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