File name: Pandora125s1_Cordoba_20210116_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142746.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210116_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210116T200424.2Z 7686.836391 5 1 44.38 2 49.79 268.63 21.63 336.38 0.00 1 0.00 1 0 17 8.706e-03 5.178e-03 1.149e-03 4.064e-04 1.775167e-01 2.028930e-04 1.932717e-03 -6.000000e+00 4.937738e-03 229.21 -2.00 3.11 -2.00 317.64 0.00e+00 2.077513e-04 3.030180e-05 3.168520e-05 -6.000000e+00 2.219186e-04 288.41 -2.00 20.00 -2.00 316.71 0.00e+00 1.546 0.000 302.00 328.00 3 1.7038e-01 5.4104e-04 1.6949e-02 -6.0000e+00 1.2290e-02 2.3266e-02 6.0938e-04 8.2923e-03 -6.0000e+00 1.3320e-02 -5.2803e-03 3.5949e-04 4.0378e-03 -6.0000e+00 7.9559e-03 -5.1469e-03 1.7487e-04 1.1304e-03 -6.0000e+00 3.3957e-03 8.5265e-02 -8.2960e-04 1.1879e-05 1.3040e-05 -6.0000e+00 2.2535e-04 -9.4179e-04 0.0000e+00 10 0 0 10 0 0 14.88 21.94 0.25 -0.00094 -0.00718 2377 473 1 5 0 18.659 27.56 20.05 21.94 -1029 -962 -1007 -2072 -4147 -2674 -1818 1364 2048 1217 -506 -982 78 75 768 243 -463 -423 -4 165 522 -601 507 476 -43 333 43 -221 -252 527 1276 1662 2135 929 -1608 -1097 -841 -308 225 -117 -968 -1145 -878 -1202 -733 -795 -991 -867 -1021 -669 826 734 878 1098 628 809 813 572 333 662 987 1309 1349 1567 507 -490 57 -320 863 1125 311 253 9 271 253 30 188 -227 443 203 -543 -859 -1544 -1529 -874 -821 -510 -310 -177 -5 30 260 78 744 801 412 318 571 49 -268 -212 -585 -311 193 -239 -928 -582 -807 -415 69 57 58 18 112 88 340 417 217 129 -102 -527 -237 -25 253 680 874 543 1198 686 456 461 91 107 -40 -282 -326 -202 197 -110 -160 4 -330 -407 -137 -142 -154 -308 -581 -332 -226 181 305 196 -82 -155 13 14 159 56 -112 -103 -1 42 137 -159 131 128 -12 98 13 -66 -69 134 326 448 612 283 -476 -300 -240 -100 87 -54 -497 -618 -485 -674 -407 -440 -538 -453 -514 -344 430 407 513 669 396 517 529 374 214 418 633 887 988 1221 404 -364 40 -212 580 852 250 214 7 239 211 23 126 -149 289 147 -445 -735 -1423 -1468 -887 -898 -591 -373 -215 -6 33 274 74 655 726 409 348 689 64 -349 -260 -660 -350 221 -300 -1176 -766 -1111 -593 103 90 92 27 170 120 432 520 283 180 -154 -833 -374 -39 396 1004 1226 720 1551 941 669 709 143 169 -65 -492 -601 -382 381 -216 -310 8 -598 -720 SU 20210116T201039.3Z 7686.840733 8 1 44.60 2 51.12 267.84 22.21 332.66 0.00 1 0.00 1 0 17 8.679e-03 5.165e-03 1.232e-03 4.187e-04 1.825735e-01 2.087757e-04 1.982598e-03 -6.000000e+00 4.923149e-03 229.21 -2.00 3.11 -2.00 317.73 0.00e+00 2.073391e-04 3.202743e-05 3.325276e-05 -6.000000e+00 2.212476e-04 288.41 -2.00 20.00 -2.00 316.81 0.00e+00 1.590 0.000 302.00 328.00 3 1.6695e-01 5.5807e-04 1.7427e-02 -6.0000e+00 1.2254e-02 2.4385e-02 6.2936e-04 8.5228e-03 -6.0000e+00 1.3281e-02 -5.7364e-03 3.7266e-04 4.1491e-03 -6.0000e+00 7.9322e-03 -5.5530e-03 1.8220e-04 1.1609e-03 -6.0000e+00 3.3859e-03 8.1277e-02 -8.2719e-04 1.2277e-05 1.3343e-05 -6.0000e+00 2.2466e-04 -1.5657e-03 0.0000e+00 10 0 0 10 0 0 11.94 22.00 0.25 -0.00157 -0.00778 2347 467 1 5 0 18.934 27.56 20.04 22.00 -981 -1100 -1522 -2152 -3772 -2775 -927 569 2026 850 -157 -1243 600 -247 1196 216 -647 -361 -98 425 414 -376 57 598 124 578 -161 -309 -384 364 1646 1686 2324 899 -1589 -1405 -617 -846 573 -237 -967 -1270 -741 -1221 -731 -614 -1174 -843 -1063 -413 483 901 613 1094 438 992 811 625 318 592 946 1205 1420 1558 554 -495 112 -390 901 1092 446 197 80 185 291 54 296 -178 304 231 -541 -729 -1601 -1523 -995 -725 -619 -338 -123 11 14 319 30 817 822 467 383 527 82 -295 -139 -705 -243 221 -221 -936 -625 -799 -401 65 28 92 -18 120 13 413 343 285 109 -26 -534 -232 -61 196 630 853 607 1098 740 373 545 34 131 -58 -285 -361 -176 169 -135 -107 2 -271 -408 -123 -154 -222 -305 -501 -329 -109 72 287 131 -24 -188 95 -44 237 48 -150 -85 -24 105 105 -95 14 155 34 165 -47 -89 -102 90 407 442 647 267 -458 -377 -172 -270 216 -106 -485 -671 -400 -670 -397 -332 -626 -431 -525 -208 248 491 353 656 273 623 520 402 202 369 598 806 1025 1198 436 -364 77 -256 599 819 354 166 72 162 240 41 197 -116 197 166 -439 -619 -1468 -1453 -1005 -788 -715 -404 -148 13 15 334 28 716 742 462 419 636 107 -384 -170 -797 -273 252 -277 -1184 -822 -1097 -570 98 44 146 -27 182 18 525 458 371 152 -39 -845 -365 -94 308 933 1199 805 1426 1018 550 840 54 209 -96 -500 -670 -335 328 -267 -208 4 -493 -726 SU 20210116T201553.4Z 7686.844368 11 1 44.80 2 52.23 267.19 22.76 329.69 0.00 1 0.00 1 0 25 8.911e-03 5.034e-03 1.333e-03 4.359e-04 1.868907e-01 2.167320e-04 2.021271e-03 -6.000000e+00 5.054888e-03 229.21 -2.00 3.11 -2.00 317.84 0.00e+00 1.500379e-04 3.417788e-05 3.302257e-05 -6.000000e+00 2.271586e-04 288.41 -2.00 20.00 -2.00 316.90 0.00e+00 1.629 0.000 302.00 328.00 3 1.9876e-01 5.8108e-04 1.7846e-02 -6.0000e+00 1.2582e-02 2.2155e-02 6.5658e-04 8.7130e-03 -6.0000e+00 1.3636e-02 -5.4639e-03 3.8989e-04 4.2388e-03 -6.0000e+00 8.1443e-03 -5.2222e-03 1.9101e-04 1.1807e-03 -6.0000e+00 3.4767e-03 7.5303e-02 -8.3371e-04 1.2761e-05 1.3478e-05 -6.0000e+00 2.3066e-04 -1.9351e-03 0.0000e+00 10 0 0 10 0 0 11.18 22.05 0.25 -0.00194 -0.00820 2248 447 1 5 0 19.869 27.67 20.04 22.05 -99 -1160 -1104 -2123 -4482 -2728 -1861 1042 913 1575 -1688 -388 -254 292 597 703 -1027 -545 -51 -227 586 -648 762 426 465 215 477 -667 21 148 1866 1475 2220 1285 -1486 -1209 -1169 -364 -17 48 -1085 -999 -1037 -1009 -898 -524 -939 -822 -1024 -531 685 799 909 923 677 669 976 472 457 444 972 1222 1365 1556 440 -429 -87 -232 710 1312 276 320 -178 262 127 59 304 -174 517 151 -435 -877 -1488 -1566 -801 -799 -376 -357 -131 4 -9 225 89 748 683 516 243 635 -3 -238 -200 -561 -235 313 -211 -857 -631 -791 -430 59 -25 7 51 79 79 265 492 163 211 -118 -533 -237 -52 246 665 897 457 1233 586 448 410 120 44 16 -326 -340 -181 172 -88 -108 27 -314 -349 -12 -155 -153 -286 -571 -308 -210 126 125 231 -253 -56 -39 50 114 148 -230 -123 -12 -54 143 -159 183 107 123 60 133 -188 5 36 446 376 602 370 -417 -315 -318 -113 -6 21 -532 -514 -548 -540 -477 -276 -489 -412 -521 -263 344 427 513 545 413 415 615 300 285 272 604 804 970 1178 341 -311 -60 -150 468 970 229 266 -159 226 104 44 200 -112 331 107 -351 -739 -1353 -1484 -801 -863 -430 -424 -157 5 -11 234 83 654 614 507 265 762 -4 -309 -244 -632 -262 356 -263 -1079 -828 -1084 -611 88 -39 11 78 119 108 338 657 212 295 -180 -844 -374 -80 387 984 1261 608 1600 807 661 634 191 71 26 -574 -633 -346 335 -174 -211 50 -575 -667 SU 20210116T202215.5Z 7686.848790 14 1 44.96 2 53.58 266.41 23.48 326.25 0.00 1 0.00 1 0 25 8.572e-03 5.063e-03 1.454e-03 4.522e-04 1.925133e-01 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