File name: Pandora125s1_Cordoba_20210128_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142825.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210128_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210128 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210128T160647.3Z 7698.671381 13 1 10.57 2 14.52 21.05 169.72 205.52 0.00 1 0.00 1 0 25 7.932e-03 5.619e-03 1.742e-03 1.054e-03 1.241938e-01 5.301749e-04 1.366800e-03 -6.000000e+00 4.498807e-03 229.14 -2.00 3.11 -2.00 315.73 0.00e+00 1.281264e-04 5.252210e-05 3.293364e-05 -6.000000e+00 2.023114e-04 288.52 -2.00 20.00 -2.00 314.93 0.00e+00 1.033 0.000 302.00 328.00 3 1.8247e+00 1.3734e-03 1.1450e-02 -6.0000e+00 1.1195e-02 2.4769e-02 1.5287e-03 5.7627e-03 -6.0000e+00 1.2133e-02 -7.0056e-03 8.7493e-04 2.8134e-03 -6.0000e+00 7.2480e-03 -4.5119e-03 3.9351e-04 7.8560e-04 -6.0000e+00 3.0949e-03 2.9685e-02 -5.6350e-04 2.9581e-05 9.7116e-06 -6.0000e+00 2.0533e-04 -2.1087e-03 0.0000e+00 12 1 1 12 9 1 99.85 22.01 0.22 -0.00211 -0.00634 142 134 1 5 0 72.731 27.67 19.99 22.01 30 -500 -640 -1049 -2772 -1081 132 1854 2846 1908 518 -968 804 203 558 -6 -522 -223 -245 -70 451 -361 271 89 -308 438 -69 -198 137 700 1350 1758 2220 1358 -1374 -857 -1142 -765 -9 -414 -899 -1242 -1026 -1379 -955 -884 -940 -1158 -845 -545 710 608 637 967 586 416 552 472 463 744 785 977 1197 1486 711 -170 -71 -212 952 1304 512 131 23 212 153 -13 407 -430 529 189 -362 -656 -1646 -1456 -993 -694 -442 -256 -142 -13 41 357 -69 632 742 280 236 429 168 -232 -75 -617 -201 130 -256 -986 -628 -829 -424 116 60 208 110 167 -23 362 307 186 162 -49 -517 -113 73 185 531 808 610 1076 570 265 479 -47 124 54 -385 -354 -220 181 -77 -73 22 -412 -375 9 -158 -207 -325 -764 -280 34 511 873 591 170 -308 262 69 210 -3 -220 -94 -105 -31 202 -161 119 40 -146 214 -34 -92 62 292 556 751 995 639 -624 -359 -501 -381 -5 -270 -611 -883 -744 -1012 -692 -675 -701 -826 -572 -355 465 421 462 727 453 326 438 375 361 571 613 807 1060 1387 671 -148 -59 -164 742 1139 469 127 22 202 148 -12 337 -328 396 156 -313 -622 -1680 -1542 -1044 -784 -530 -319 -178 -16 46 390 -72 612 732 301 260 518 217 -299 -90 -693 -227 151 -302 -1253 -829 -1141 -601 172 87 303 163 228 -31 444 370 232 218 -72 -741 -161 109 265 716 1033 790 1358 758 375 653 -66 172 77 -587 -570 -365 306 -133 -124 37 -660 -587 SS 20210128T164619.4Z 7698.698835 31 1 48.73 2 14.25 342.55 169.71 155.39 0.00 1 0.00 1 0 17 8.568e-03 5.594e-03 1.893e-03 9.435e-04 1.227660e-01 4.696352e-04 1.348213e-03 -6.000000e+00 4.859648e-03 229.14 -2.00 3.11 -2.00 316.61 0.00e+00 1.104484e-04 5.521286e-05 2.615496e-05 -6.000000e+00 2.185369e-04 288.52 -2.00 20.00 -2.00 315.71 0.00e+00 1.032 0.000 302.00 328.00 3 2.2300e+00 1.2334e-03 1.1412e-02 -6.0000e+00 1.2093e-02 2.5427e-02 1.3810e-03 5.7124e-03 -6.0000e+00 1.3107e-02 -4.1135e-03 7.9058e-04 2.7869e-03 -6.0000e+00 7.8293e-03 -5.8578e-03 3.6323e-04 7.7899e-04 -6.0000e+00 3.3432e-03 1.9861e-02 -4.3501e-04 2.7191e-05 9.2976e-06 -6.0000e+00 2.2180e-04 -2.1843e-03 0.0000e+00 10 0 0 10 0 0 99.99 21.99 0.23 -0.00218 -0.00545 804 160 1 5 0 60.531 27.67 20.00 21.99 -339 -516 -776 -642 -3316 -1191 -499 2000 3215 1247 -32 -609 1365 -144 1329 -653 -23 -1118 311 -311 739 -318 94 224 -330 561 -389 -107 -625 954 1695 2148 1936 1534 -1498 -834 -863 -385 981 -639 -742 -1435 -694 -1470 -653 -898 -970 -1028 -1021 -842 500 913 696 1072 362 646 529 809 -24 784 756 1174 1045 1759 321 -445 -41 -239 992 1047 417 105 244 239 473 -192 660 -301 728 248 -302 -686 -1680 -1330 -975 -555 -558 -163 -261 167 -124 401 -16 800 705 425 370 409 103 -483 -89 -603 -209 74 -147 -1064 -559 -994 -315 -35 61 89 -12 249 -102 480 293 280 51 -29 -501 -112 -96 285 746 853 593 1064 783 428 567 -16 195 -217 -272 -414 -72 182 -69 -152 40 -257 -503 -75 -126 -202 -159 -735 -232 -96 414 739 312 -8 -145 347 -39 397 -216 -8 -380 106 -109 275 -118 34 84 -131 227 -160 -42 -221 322 566 743 707 585 -554 -284 -307 -155 466 -362 -464 -941 -462 -995 -434 -595 -626 -634 -626 -498 296 569 456 728 254 456 379 578 -17 568 558 913 875 1479 287 -367 -30 -164 684 811 360 96 225 216 422 -156 471 -208 493 185 -253 -603 -1588 -1301 -1011 -618 -661 -200 -324 201 -147 425 -15 737 664 435 415 479 129 -605 -109 -690 -225 82 -177 -1382 -752 -1399 -456 -52 96 141 -18 366 -136 590 354 351 69 -43 -772 -172 -145 434 1067 1158 758 1327 1025 595 820 -23 289 -332 -440 -710 -126 326 -126 -273 74 -465 -889 SS 20210128T165806.0Z 7698.707014 34 1 50.06 2 15.22 332.21 168.47 143.34 0.00 1 0.00 1 0 17 1.620e-02 9.163e-03 1.274e-02 6.194e-03 1.305083e-01 3.090133e-03 1.428349e-03 -6.000000e+00 9.184487e-03 229.14 -2.00 3.11 -2.00 316.74 0.00e+00 -3.364152e-04 3.711961e-04 9.444865e-05 -6.000000e+00 4.130601e-04 288.52 -2.00 20.00 -2.00 315.82 0.00e+00 1.036 0.000 302.00 328.00 3 5.4367e+00 8.1168e-03 1.1637e-02 -6.0000e+00 2.2856e-02 5.8629e-02 9.1038e-03 6.1005e-03 -6.0000e+00 2.4772e-02 -1.3346e-02 5.2198e-03 2.9534e-03 -6.0000e+00 1.4797e-02 -9.9089e-04 2.4049e-03 9.0836e-04 -6.0000e+00 6.3179e-03 7.8242e-04 -4.7684e-04 1.8006e-04 1.0650e-05 -6.0000e+00 4.1923e-04 -1.4095e-03 0.0000e+00 11 8 0 10 0 0 99.98 21.98 -0.02 -0.00141 -0.00499 40 8 1 5 0 1251.432 27.56 20.00 21.98 -903 1457 -1103 5664 -3918 -1130 -4737 6539 392 1318 -2624 1114 -994 -1532 -431 -1588 693 149 -35 346 1474 -3701 2471 910 -1458 -976 744 -1453 1475 103 1538 2124 -1301 2626 -4752 -2084 -5795 1553 248 1581 -1177 -1572 -258 321 -1287 -1348 -522 -2253 463 -112 2676 -955 1813 817 1222 1168 1292 1281 439 1804 256 1451 -76 3236 861 343 144 870 -1907 2487 -728 -219 133 -313 982 -446 1711 -762 1177 -2258 2180 -1345 -1720 -1751 -791 -1250 181 -30 -471 281 -146 460 -940 2042 -121 684 -732 155 -322 -255 -890 -811 116 -249 -196 -1667 -73 -1171 60 170 434 -694 1088 -423 -118 -209 76 205 -40 664 -497 835 -340 713 198 1228 260 1180 177 896 614 319 385 -184 844 -529 70 -712 545 21 86 -1093 -794 -194 347 -275 1255 -834 -210 -913 1279 92 326 -664 259 -246 -420 -129 -522 229 49 -12 119 515 -1344 834 322 -572 -395 297 -560 501 33 499 713 -476 961 -1758 -697 -2099 597 115 851 -718 -1002 -166 206 -832 -896 -335 -1404 268 -63 1487 -582 1167 553 844 815 914 906 307 1228 180 1065 -61 2650 752 276 103 579 -1331 1869 -626 -197 125 -289 848 -353 1174 -509 766 -1670 1721 -1205 -1648 -1744 -829 -1420 216 -38 -591 340 -165 488 -904 1770 -110 665 -791 183 -406 -320 -1103 -924 124 -273 -235 -2160 -97 -1633 85 255 675 -1099 1694 -616 -155 -254 94 266 -56 998 -788 1305 -525 1046 276 1606 340 1496 237 1266 905 478 579 -287 1375 -924 125 -1312 1005 39 160 -1998 -1414 SS 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