File name: Pandora125s1_Cordoba_20210203_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142750.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210203_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210203 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210203T190602.5Z 7704.795862 3 1 46.99 2 38.69 284.09 128.00 225.49 0.00 1 0.00 1 0 17 8.285e-03 5.329e-03 9.856e-04 4.137e-04 1.578121e-01 2.070727e-04 1.726244e-03 -6.000000e+00 4.699513e-03 229.11 -2.00 3.11 -2.00 317.15 0.00e+00 1.456697e-04 2.752475e-05 3.172144e-05 -6.000000e+00 2.113665e-04 288.58 -2.00 20.00 -2.00 316.24 0.00e+00 1.280 0.000 302.00 328.00 3 6.0067e-01 5.4768e-04 1.4297e-02 -6.0000e+00 1.1694e-02 2.7855e-02 6.1463e-04 7.3450e-03 -6.0000e+00 1.2672e-02 -7.4280e-03 3.5600e-04 3.5880e-03 -6.0000e+00 7.5705e-03 -4.8857e-03 1.6927e-04 1.0034e-03 -6.0000e+00 3.2342e-03 7.3971e-02 -8.7250e-04 1.2053e-05 1.1787e-05 -6.0000e+00 2.1446e-04 -4.0998e-03 0.0000e+00 10 0 0 10 0 0 37.84 22.12 0.25 -0.00410 -0.01066 1905 379 1 5 0 24.610 27.67 20.00 22.12 425 -1110 -124 -1722 -3184 -1187 -764 1748 2024 1944 -350 -98 266 703 892 406 -672 -490 -253 -62 164 -649 185 69 187 -12 116 -412 -198 450 2240 1531 2414 1079 -1496 -1104 -1144 -349 203 8 -957 -1282 -1120 -1211 -986 -746 -1224 -984 -988 -601 556 846 808 1033 548 727 848 562 435 600 832 1270 1460 1528 562 -299 12 -248 871 1283 360 306 -41 253 181 176 344 -140 533 59 -492 -816 -1611 -1496 -827 -745 -458 -265 -106 -55 36 221 42 842 849 374 303 528 -28 -245 -230 -528 -248 230 -194 -895 -622 -815 -415 56 -59 -13 30 134 117 409 481 285 222 -103 -542 -276 -23 180 641 849 573 1194 689 410 422 70 71 31 -264 -355 -167 179 -129 -146 -8 -312 -365 71 -209 -24 -324 -534 -183 -118 288 375 387 -71 -19 54 158 223 112 -194 -143 -75 -19 51 -202 56 22 62 -4 41 -137 -63 133 651 472 783 372 -500 -341 -368 -127 88 4 -548 -735 -689 -755 -608 -457 -738 -567 -546 -321 300 483 485 646 354 475 563 394 300 408 573 922 1141 1268 476 -236 9 -173 613 958 301 270 -37 221 159 139 242 -96 360 42 -391 -716 -1525 -1472 -859 -834 -543 -326 -132 -67 40 239 40 755 779 375 335 641 -37 -321 -284 -600 -281 265 -230 -1141 -824 -1127 -594 84 -93 -21 45 190 160 514 593 365 306 -154 -848 -431 -34 263 939 1180 751 1524 928 591 635 107 110 50 -448 -637 -307 337 -246 -276 -15 -552 -632 SU 20210203T190747.5Z 7704.797078 5 1 47.03 2 39.05 283.75 128.25 225.07 0.00 1 0.00 1 0 17 8.165e-03 5.264e-03 9.969e-04 4.166e-04 1.585042e-01 2.085118e-04 1.734997e-03 -6.000000e+00 4.631555e-03 229.11 -2.00 3.11 -2.00 317.16 0.00e+00 1.170088e-04 2.773391e-05 2.734936e-05 -6.000000e+00 2.083128e-04 288.58 -2.00 20.00 -2.00 316.24 0.00e+00 1.287 0.000 302.00 328.00 3 6.0894e-01 5.5189e-04 1.4369e-02 -6.0000e+00 1.1525e-02 2.7186e-02 6.1940e-04 7.3821e-03 -6.0000e+00 1.2489e-02 -7.0192e-03 3.5880e-04 3.6056e-03 -6.0000e+00 7.4610e-03 -4.7867e-03 1.7072e-04 1.0077e-03 -6.0000e+00 3.1874e-03 7.2814e-02 -8.7684e-04 1.2134e-05 1.1816e-05 -6.0000e+00 2.1136e-04 -3.9864e-03 0.0000e+00 10 0 0 10 0 0 53.26 22.13 0.23 -0.00399 -0.01058 1873 373 1 5 0 25.050 27.67 20.00 22.13 102 -830 -370 -1724 -3095 -1491 -401 2037 2536 1786 -180 -90 711 914 880 587 -929 -627 -294 74 200 -537 245 361 225 98 112 -643 -191 385 1288 1459 2175 1102 -1487 -1065 -960 -349 357 -113 -1163 -1109 -1054 -1182 -1053 -693 -1293 -779 -949 -523 638 851 823 944 518 683 941 571 458 431 918 1164 1359 1458 528 -443 102 -259 752 1329 334 330 2 268 128 78 244 47 582 234 -513 -793 -1522 -1434 -913 -759 -405 -355 -101 -57 7 258 112 758 911 374 340 541 51 -257 -208 -501 -270 313 -249 -846 -682 -790 -457 83 1 76 -10 112 88 388 533 181 184 -151 -517 -289 -46 128 651 825 627 1224 605 378 446 76 61 74 -288 -378 -257 207 -128 -101 28 -319 -329 17 -155 -71 -321 -538 -229 -61 332 464 354 -36 -17 142 203 219 161 -267 -181 -87 22 62 -166 74 113 74 34 39 -214 -61 113 376 448 704 378 -495 -328 -307 -127 154 -58 -665 -663 -646 -734 -648 -423 -777 -447 -522 -278 343 484 492 589 334 445 655 400 315 293 630 843 1060 1208 447 -349 72 -180 529 991 279 292 1 234 112 61 171 32 392 175 -408 -695 -1438 -1408 -948 -849 -480 -437 -125 -69 8 278 108 679 835 374 375 655 67 -336 -256 -569 -305 359 -295 -1077 -904 -1092 -654 125 1 121 -15 159 120 488 656 232 254 -226 -809 -451 -70 186 953 1147 821 1563 816 544 671 117 94 118 -487 -679 -475 391 -244 -190 52 -565 -569 SU 20210203T190932.5Z 7704.798293 7 1 47.08 2 39.41 283.42 128.49 224.65 0.00 1 0.00 1 0 17 8.399e-03 5.301e-03 1.022e-03 4.233e-04 1.588532e-01 2.119054e-04 1.738869e-03 -6.000000e+00 4.763919e-03 229.11 -2.00 3.11 -2.00 317.19 0.00e+00 1.471892e-04 2.836409e-05 2.986142e-05 -6.000000e+00 2.142660e-04 288.58 -2.00 20.00 -2.00 316.27 0.00e+00 1.293 0.000 302.00 328.00 3 6.2980e-01 5.6103e-04 1.4432e-02 -6.0000e+00 1.1854e-02 2.5635e-02 6.2978e-04 7.4003e-03 -6.0000e+00 1.2846e-02 -6.1581e-03 3.6505e-04 3.6144e-03 -6.0000e+00 7.6743e-03 -5.0498e-03 1.7389e-04 1.0108e-03 -6.0000e+00 3.2785e-03 7.0819e-02 -8.9170e-04 1.2337e-05 1.1845e-05 -6.0000e+00 2.1740e-04 -3.9925e-03 0.0000e+00 10 0 0 10 0 0 64.20 22.13 0.24 -0.00399 -0.01069 1845 367 1 5 0 25.456 27.78 20.00 22.13 -341 -443 -823 -1098 -3820 -920 -618 2215 2337 2272 -490 36 1023 478 1038 50 -475 -736 -50 -267 650 -910 493 173 232 223 132 -490 -172 360 1180 1628 1893 1184 -1689 -952 -1090 -302 139 -27 -1069 -1198 -1103 -1264 -955 -832 -1078 -1084 -892 -718 724 826 783 1015 638 662 846 546 380 609 941 1189 1277 1620 433 -204 3 -131 784 1352 383 385 -32 262 171 55 383 -216 640 189 -471 -775 -1492 -1523 -768 -759 -435 -278 -136 -53 -15 366 -26 807 746 430 276 515 -75 -263 -199 -512 -240 250 -168 -969 -572 -840 -380 30 27 -15 59 95 136 378 490 234 146 -84 -561 -254 -127 229 570 889 556 1223 679 451 436 66 127 -18 -255 -408 -198 195 -109 -102 42 -364 -363 -56 -81 -157 -202 -633 -139 -93 358 425 444 -97 7 202 106 256 14 -135 -212 -15 -80 200 -281 149 54 76 76 45 -162 -54 105 343 496 612 404 -561 -291 -348 -109 60 -14 -608 -715 -674 -782 -585 -506 -644 -621 -489 -382 387 468 467 631 410 431 559 382 261 411 644 859 995 1338 365 -160 2 -91 550 1006 320 339 -29 229 149 43 268 -147 431 141 -373 -678 -1408 -1497 -796 -848 -515 -343 -169 -64 -17 395 -25 723 685 431 305 625 -99 -344 -245 -582 -272 287 -199 -1236 -758 -1162 -543 45 43 -24 91 134 186 475 604 301 201 -125 -878 -397 -194 335 836 1237 730 1563 916 649 656 102 196 -29 -432 -733 -365 368 -209 -193 78 -646 -628 SU 20210203T191116.6Z 7704.799497 9 1 47.12 2 39.77 283.09 128.73 224.22 0.00 1 0.00 1 0 17 8.248e-03 5.294e-03 1.031e-03 4.259e-04 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