File name: Pandora125s1_Cordoba_20210212_L2Fit_fout2c3d20170323p1-8.txt File generation date: 20250228T141425.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v3d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210212_L1_smca1c3d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 214 355 Nominal wavelengths inside fitting window [nm]: 305.0972 305.2384 305.3797 305.5210 305.6622 305.8035 305.9447 306.0859 306.2272 306.3684 306.5095 306.6507 306.7919 306.9330 307.0742 307.2153 307.3564 307.4975 307.6386 307.7797 307.9208 308.0619 308.2029 308.3439 308.4850 308.6260 308.7670 308.9080 309.0490 309.1899 309.3309 309.4719 309.6128 309.7537 309.8946 310.0355 310.1764 310.3173 310.4582 310.5990 310.7399 310.8807 311.0215 311.1624 311.3032 311.4439 311.5847 311.7255 311.8662 312.0070 312.1477 312.2884 312.4291 312.5698 312.7105 312.8512 312.9919 313.1325 313.2732 313.4138 313.5544 313.6950 313.8356 313.9762 314.1168 314.2573 314.3979 314.5384 314.6789 314.8194 314.9599 315.1004 315.2409 315.3814 315.5218 315.6623 315.8027 315.9431 316.0835 316.2239 316.3643 316.5047 316.6451 316.7854 316.9257 317.0661 317.2064 317.3467 317.4870 317.6273 317.7675 317.9078 318.0481 318.1883 318.3285 318.4687 318.6089 318.7491 318.8893 319.0295 319.1696 319.3098 319.4499 319.5900 319.7301 319.8702 320.0103 320.1504 320.2904 320.4305 320.5705 320.7105 320.8505 320.9905 321.1305 321.2705 321.4105 321.5504 321.6904 321.8303 321.9702 322.1101 322.2500 322.3899 322.5298 322.6697 322.8095 322.9494 323.0892 323.2290 323.3688 323.5086 323.6484 323.7881 323.9279 324.0676 324.2074 324.3471 324.4868 324.6265 324.7662 324.9058 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210212T112320.9Z 7713.474547 67 1 49.72 2 71.66 94.88 79.91 101.21 0.00 1 0.00 1 0 17 1.490e-01 1.376e-02 1.398e-01 9.579e-03 3.671381e-01 4.906221e-03 3.823793e-03 -6.000000e+00 8.440228e-02 229.06 -2.00 3.11 -2.00 320.74 0.00e+00 4.820410e-05 1.896825e-03 1.559184e-03 -6.000000e+00 3.810944e-03 288.66 -2.00 20.00 -2.00 319.95 0.00e+00 3.137 0.000 302.00 328.00 3 2.9621e+00 1.5856e-02 3.5408e-02 -6.0000e+00 2.0997e-01 -4.5931e-02 1.9475e-02 2.0293e-02 -6.0000e+00 2.2780e-01 -1.0526e-01 1.5125e-02 8.9742e-03 -6.0000e+00 1.3600e-01 4.4451e-02 7.5770e-03 2.4875e-03 -6.0000e+00 5.8302e-02 9.4936e-04 1.3327e-03 3.0116e-04 2.8964e-05 -6.0000e+00 3.8910e-03 4.2365e-02 0.0000e+00 12 8 8 10 0 0 95.52 22.28 0.50 0.04236 0.05238 47 9 1 5 0 1057.796 27.88 20.02 22.28 1240 -18319 -69329 -42176 -22637 11712 -102776 -27587 -7077 -49874 -23415 1190 -766 -47235 34950 -5408 8094 -23977 6900 3795 -2226 -702 -20157 21176 434 22655 -170 -14253 -9613 -2191 -7493 3632 -4933 23091 11164 -5283 3095 -8262 10578 8504 9315 -700 3656 -5693 3321 -3700 6191 3746 12391 842 503 -1120 -8 451 1204 10159 -1699 6858 -5029 13595 -4675 6853 3600 4375 -115 2800 -833 4233 1433 2577 3733 -393 2701 -4475 2395 -4948 475 -4941 2646 -2387 848 -2451 -3095 -3017 497 -853 156 57 -266 3140 -2399 1113 -2133 -404 -486 -1903 521 -256 725 -1483 -785 -2741 -739 -1965 1076 -1694 800 -247 1211 79 1175 63 78 211 -613 1218 -1105 1172 -1048 128 -444 1296 326 841 -395 -236 1364 102 779 61 1257 -342 689 -1275 79 -358 644 -389 629 -876 121 -495 22 -425 -2614 -1080 -439 166 -5155 -744 -175 -1917 -698 31 -24 -2800 1042 -260 358 -1542 340 199 -123 -39 -1491 1116 30 1261 -11 -1022 -643 -146 -588 295 -468 1582 817 -485 305 -1109 1408 1297 1497 -129 686 -1172 628 -747 1119 691 2123 172 113 -275 -2 127 347 2756 -521 1887 -1533 3515 -1562 2255 1337 1662 -45 995 -301 1549 620 1224 1846 -204 1307 -2170 1023 -2059 179 -2074 1181 -1284 495 -1603 -2145 -2238 384 -708 133 49 -234 2480 -1839 761 -1475 -295 -399 -1788 537 -287 803 -1660 -795 -2649 -720 -2117 1195 -2030 987 -329 1722 122 1848 98 121 301 -834 1630 -1589 1770 -1724 212 -725 2023 495 1290 -587 -334 1930 160 1326 111 2350 -669 1400 -2821 181 -850 1547 -950 1478 -2132 279 -1125 SS 20210212T113020.3Z 7713.479401 71 1 48.55 2 70.18 94.00 78.50 100.36 0.00 1 0.00 1 0 17 4.579e-02 5.052e-03 1.514e-02 1.255e-03 3.486798e-01 6.415783e-04 3.597820e-03 -6.000000e+00 2.603593e-02 229.06 -2.00 3.11 -2.00 320.07 0.00e+00 7.637264e-04 2.018068e-04 1.247032e-04 -6.000000e+00 1.171892e-03 288.66 -2.00 20.00 -2.00 319.24 0.00e+00 2.916 0.000 302.00 328.00 3 -3.3000e-01 1.9158e-03 3.2263e-02 -6.0000e+00 6.4778e-02 2.7968e-02 2.2977e-03 1.6304e-02 -6.0000e+00 7.0200e-02 -1.7567e-02 1.7550e-03 8.0132e-03 -6.0000e+00 4.1908e-02 -2.9539e-03 8.9989e-04 2.5589e-03 -6.0000e+00 1.8031e-02 2.9562e-02 1.0978e-03 3.8142e-05 2.6815e-05 -6.0000e+00 1.1952e-03 1.8945e-02 0.0000e+00 10 0 0 10 0 0 45.34 22.31 0.24 0.01895 0.02719 956 190 1 5 0 50.670 27.88 20.02 22.31 -12315 -8317 -24406 -2075 -23707 -14659 -18515 -10349 -12098 -11139 -8255 -7184 -9946 -3558 -4462 -6316 -2459 -5609 1686 -2314 -462 -3223 -1541 -4324 -2142 -2672 -2739 -3710 -3064 -936 -1407 478 -58 -1338 -4282 -2979 -2242 -2442 -562 -1237 -562 -1105 -483 -579 157 88 -199 -362 -4 873 1537 1107 1568 1097 749 1335 879 1133 783 1619 1568 1986 2460 1561 711 810 369 866 869 216 418 17 645 712 576 710 102 298 -61 -907 -1007 -1579 -1679 -1046 -825 -388 -345 -205 51 386 549 435 705 581 250 159 335 -92 -338 -297 -520 -243 25 -277 -1012 -682 -840 -422 78 24 -57 116 88 68 277 366 195 174 -198 -655 -300 -97 182 563 705 503 1202 751 515 589 204 167 62 -188 -242 -255 306 -91 -237 -114 -307 -223 -308 -215 -743 -46 -589 -337 -515 -304 -398 -371 -268 -255 -429 -171 -250 -393 -155 -386 113 -168 -33 -237 -117 -382 -196 -252 -251 -320 -254 -80 -135 50 -7 -151 -465 -350 -301 -397 -108 -272 -131 -270 -120 -144 39 22 -49 -89 -1 223 446 348 522 385 271 494 329 415 282 587 607 843 1137 759 332 368 162 396 453 127 260 11 392 405 297 328 47 142 -33 -566 -705 -1144 -1354 -891 -756 -375 -348 -208 51 354 461 335 552 480 217 156 367 -111 -409 -360 -575 -248 25 -310 -1217 -855 -1109 -587 116 39 -95 189 135 95 389 507 282 269 -329 -1120 -503 -157 284 836 999 725 1717 1163 815 994 359 301 117 -377 -515 -556 678 -204 -559 -258 -663 -468 SS 20210212T113728.2Z 7713.484354 74 1 48.42 2 68.66 93.09 77.06 99.49 0.00 1 0.00 1 0 17 3.383e-02 4.997e-03 1.119e-02 1.108e-03 3.267758e-01 5.642324e-04 3.380528e-03 -6.000000e+00 1.923440e-02 229.06 -2.00 3.11 -2.00 319.86 0.00e+00 7.127895e-04 1.651458e-04 1.098560e-04 -6.000000e+00 8.657525e-04 288.66 -2.00 20.00 -2.00 319.02 0.00e+00 2.722 0.000 302.00 328.00 3 -3.0904e-01 1.6543e-03 3.0141e-02 -6.0000e+00 4.7856e-02 2.1889e-02 1.9602e-03 1.5244e-02 -6.0000e+00 5.1861e-02 -1.2448e-02 1.4477e-03 7.4637e-03 -6.0000e+00 3.0960e-02 -5.1842e-03 7.4653e-04 2.3760e-03 -6.0000e+00 1.3321e-02 3.5805e-02 1.2488e-03 3.3696e-05 2.4781e-05 -6.0000e+00 8.8298e-04 1.8954e-02 0.0000e+00 10 0 0 10 0 0 15.56 22.32 0.24 0.01895 0.02834 1031 205 1 5 0 46.859 27.88 19.98 22.32 -13311 -2222 -10811 -10819 -14318 -14364 -12074 -7574 -5721 -5569 -12529 -8946 -5191 -3453 -1568 -756 -1426 -908 -1881 -2062 -1938 -3581 -3157 -2849 -2492 -1775 -1462 -4606 -661 1705 -1474 314 492 -1589 -2709 -3708 -2895 -1624 -623 -1006 -1125 -397 -96 113 32 -832 -87 -360 -3 23 1206 1328 1815 532 1233 1328 1148 829 635 1557 1721 2019 1977 1262 486 659 314 959 987 333 365 7 499 368 340 556 -54 172 -157 -255 -996 -1504 -1458 -1346 -822 -638 -180 15 111 258 632 259 531 854 170 312 260 -38 -385 -165 -681 -238 124 -229 -1066 -693 -702 -414 145 -81 -49 59 153 -2 239 404 109 102 -126 -592 -289 -77 234 595 778 327 1169 872 476 567 92 245 144 -297 -264 -176 240 -88 -144 -57 -337 -337 -418 -67 -354 -334 -416 -422 -385 -265 -215 -213 -513 -389 -256 -197 -101 -52 -104 -70 -152 -174 -171 -321 -297 -286 -264 -191 -152 -460 -61 161 -160 37 63 -210 -339 -489 -435 -291 -133 -244 -292 -106 -26 31 9 -229 -23 -96 -1 7 380 448 647 201 476 525 458 326 245 604 711 914 977 652 240 316 145 459 537 204 237 5 318 220 184 269 -26 85 -88 -164 -720 -1186 -1206 -1183 -774 -637 -186 15 113 244 544 205 425 716 150 309 288 -46 -469 -201 -762 -246 129 -260 -1299 -880 -937 -581 217 -131 -81 96 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