File name: Pandora125s1_Cordoba_20210224_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142904.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210224_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210224T104324.0Z 7725.446805 165 1 49.93 2 82.03 96.03 135.63 272.90 0.00 1 0.00 1 0 123 2.025e+00 1.271e-01 4.678e-01 3.609e-02 5.541419e-01 1.929545e-02 9.668690e-03 -6.000000e+00 1.164623e+00 228.66 -2.00 3.11 -2.00 321.51 0.00e+00 8.551394e-02 9.104253e-03 3.779382e-03 -6.000000e+00 5.287665e-02 288.45 -2.00 20.00 -2.00 320.76 0.00e+00 6.735 0.002 302.00 328.00 3 1.0485e+00 7.1339e-02 1.0176e-01 -6.0000e+00 2.8931e+00 2.3192e+00 8.1692e-02 1.2732e-01 -6.0000e+00 3.1350e+00 -2.4061e+00 4.8270e-02 1.6646e-02 -6.0000e+00 1.8719e+00 8.1196e-01 2.7084e-02 5.0170e-02 -6.0000e+00 8.0238e-01 8.3832e-05 7.8387e-03 1.0507e-03 5.9954e-04 -6.0000e+00 5.5162e-02 1.3194e-04 0.0000e+00 12 8 8 10 0 0 -5.70 22.33 0.57 0.00013 0.05904 47 9 1 5 0 1062.251 27.88 19.97 22.33 517684 450895 599254 432144 455593 696671 333413 900000 165235 165446 309600 559551 287210 900000 296947 474798 493644 468120 713397 308592 506949 302700 259603 310140 337154 60593 248102 165075 900000 106842 -79390 187755 297039 210239 280721 155190 184505 900000 144448 346972 95907 900000 69401 278425 134157 900000 77359 106137 174913 203141 167668 102385 153108 96801 124874 37005 70404 19627 95011 42923 143722 133245 115208 41322 80834 81599 115223 55748 29504 65687 37525 37258 38262 3431 -6064 13524 16411 12568 22134 9923 12618 -823 15337 8011 30020 12143 14050 1945 7190 -1509 -2601 -13280 10346 -10720 3671 9168 6455 18313 6726 1201 -10085 -2437 -5806 2819 -4301 2966 -13023 -744 1138 1536 1906 -6071 -3572 -14719 -3634 -9785 180 -2962 4100 -4631 -2273 -4323 1451 -528 -2189 3074 -2946 6730 5476 10783 2967 7726 2552 3736 1066 -226 -2139 146 -2057 -3978 -130 -3598 6027 18198 33286 21066 31396 18685 24490 17190 900000 17619 12234 10884 19670 10096 900000 17638 16691 17353 16456 25078 19452 17821 13301 12059 10903 11852 6542 8722 6010 900000 10731 -69173 14178 10442 12865 9868 11315 9128 900000 9570 12197 8947 900000 9008 9788 10883 900000 12656 13880 11314 9712 11553 13677 12056 12659 10887 6660 8250 3450 7654 6224 8631 10344 12319 10229 14208 13220 12328 10310 7395 12449 9635 9282 8714 1036 -1773 2874 3199 2691 5128 3140 4436 -360 6188 3527 11005 5549 6539 1042 3635 -793 -1263 -6816 3928 -5238 1800 5108 4402 12875 5710 1052 -8987 -1858 -4200 1919 -3382 2294 -12674 -698 1170 1770 2387 -8458 -4987 -21703 -4529 -12784 223 -4096 5701 -7290 -3445 -6442 2094 -749 -3041 3903 -3923 8893 8448 17750 5729 14954 5451 8374 2614 -620 -6108 417 -5976 -11302 -335 -9123 13772 SS 20210224T105924.8Z 7725.457926 170 1 49.68 2 78.64 93.98 138.87 270.96 0.00 1 0.00 1 0 25 3.160e-01 1.549e-02 2.015e-01 7.818e-03 5.234014e-01 4.178492e-03 5.355801e-03 -6.000000e+00 1.797773e-01 228.66 -2.00 3.11 -2.00 321.48 0.00e+00 3.375160e-03 2.054687e-03 9.713897e-04 -6.000000e+00 8.116509e-03 288.45 -2.00 20.00 -2.00 320.83 0.00e+00 4.903 0.001 302.00 328.00 3 1.3685e+00 1.5174e-02 5.2979e-02 -6.0000e+00 4.4779e-01 2.7086e-01 1.9580e-02 2.5144e-02 -6.0000e+00 4.8575e-01 -3.7692e-01 1.6347e-02 1.3048e-02 -6.0000e+00 2.8916e-01 1.4856e-01 7.8461e-03 4.4332e-03 -6.0000e+00 1.2352e-01 6.8627e-04 -1.4831e-03 2.4081e-04 5.9490e-05 -6.0000e+00 8.2540e-03 -1.8837e-04 0.0000e+00 12 9 8 11 8 0 33.28 22.25 0.29 -0.00019 -0.01133 162 32 1 5 0 306.623 27.88 20.00 22.25 -128758 -101893 3579 -103817 -57896 -152681 10985 -117914 900000 -97319 16619 -133475 40213 -72164 -2551 -15468 -24350 62235 12160 4987 -12489 16328 -17939 56257 -36978 44250 -12431 41792 -1433 -808 900000 2149 9481 7681 20580 -13792 20223 -18878 25155 6511 31045 -8423 32427 6094 12595 22033 12446 6303 233 19835 5563 14208 2592 19375 6569 15913 3191 6423 1109 5225 4625 1772 4979 3487 4818 4050 6682 -1898 6578 1061 7098 615 4584 -601 2119 -667 -283 2177 -3992 5281 -3066 -816 -2134 -482 -2175 1528 -2711 2117 -1266 78 -1540 -447 -2071 -1762 372 -1441 -446 -2065 775 -1529 -187 -1908 -1810 -1196 -1513 -1770 -2055 -732 -814 1172 -674 418 -467 139 -107 1145 -1229 489 -317 522 176 -12 588 875 2709 971 1224 824 1554 -652 1187 -264 1238 -21 -243 -425 53 157 -554 565 -691 -91 -1010 -3671 -2617 36 -2982 -933 -5729 84 -3422 900000 -2739 151 -5556 356 -2420 -52 -424 -809 930 319 146 -445 428 -656 1029 -1826 1054 -529 995 -50 -28 900000 92 431 388 882 -814 885 -1401 1450 541 2284 -982 2622 656 1273 2137 1337 723 29 2075 721 1865 415 2812 1142 2596 636 1240 219 965 869 369 1122 891 1290 1060 1693 -519 1760 344 2429 237 1705 -225 715 -207 -84 608 -1265 1777 -1308 -388 -1130 -265 -1297 942 -1848 1427 -889 56 -1043 -277 -1218 -1021 229 -1033 -363 -1949 783 -1608 -184 -1826 -1578 -1034 -1419 -1779 -2175 -812 -974 1521 -980 636 -715 203 -156 1558 -1704 696 -485 841 288 -20 902 1297 3778 1414 1696 1163 2409 -1156 2251 -536 2574 -46 -578 -1073 137 412 -1472 1442 -1694 -210 -2427 SS 20210224T110625.8Z 7725.462798 173 1 49.57 2 77.15 93.08 140.28 270.07 0.00 1 0.00 1 0 25 2.239e-01 7.431e-03 1.435e-01 5.180e-03 4.718745e-01 2.723796e-03 4.824046e-03 -6.000000e+00 1.267382e-01 228.66 -2.00 3.11 -2.00 321.22 0.00e+00 2.860562e-03 1.262267e-03 4.158939e-04 -6.000000e+00 5.708788e-03 288.45 -2.00 20.00 -2.00 320.52 0.00e+00 4.375 0.001 302.00 328.00 3 1.3202e+00 9.4629e-03 4.7509e-02 -6.0000e+00 3.1503e-01 7.8488e-02 1.2322e-02 2.3410e-02 -6.0000e+00 3.4159e-01 -1.0108e-01 1.0920e-02 1.1386e-02 -6.0000e+00 2.0412e-01 2.8541e-02 5.2924e-03 4.6229e-03 -6.0000e+00 8.7217e-02 1.2690e-03 -1.3248e-03 1.5894e-04 4.7004e-05 -6.0000e+00 5.7956e-03 -4.0009e-04 0.0000e+00 11 9 0 11 8 0 19.68 22.27 0.28 -0.00040 -0.01036 229 46 1 5 0 216.426 27.88 20.02 22.27 -92099 -75654 -47467 -74979 -49480 -96877 -49112 -90788 -38472 -99802 -25228 -60747 11229 -33410 -35797 -4110 -6526 -29737 -3479 -14387 -11762 -19138 -18528 18138 -30627 -5898 -24708 7214 -9118 8488 4619 -10129 -3013 -4232 -11060 -10580 -12912 -13356 4453 -4127 2219 -4628 -2577 8771 3204 -430 -1745 -1209 1119 -2902 1487 6588 1569 5171 2795 4012 1079 5640 3749 715 3596 1086 6821 4622 4466 -186 705 -596 2664 1778 2271 -241 420 1692 739 998 -1144 -1449 -217 -1263 368 -24 -605 -1114 -1857 -658 -409 200 -127 -336 80 337 19 322 -435 -848 525 171 445 -909 -21 -1074 -483 -567 -835 -1159 -477 -1607 -658 6 29 528 31 285 192 116 384 66 -392 -244 -344 55 82 122 493 1673 306 846 578 -177 1130 21 184 202 -125 -326 -142 269 -342 -243 -274 43 -159 -1199 -1000 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