File name: Pandora125s1_Cordoba_20210306_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142843.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210306_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210306T105041.2Z 7735.451866 236 1 50.47 2 82.03 91.55 8.61 341.51 0.00 1 0.00 1 0 25 7.655e-01 6.313e-02 4.209e-01 4.726e-02 6.131888e-01 2.537164e-02 7.327138e-03 -6.000000e+00 4.327737e-01 228.28 -2.00 3.11 -2.00 321.45 0.00e+00 -2.574142e-02 7.677732e-03 8.203118e-04 -6.000000e+00 1.951751e-02 288.22 -2.00 20.00 -2.00 320.61 0.00e+00 6.738 0.002 302.00 328.00 3 2.1375e+00 8.0744e-02 7.1796e-02 -6.0000e+00 1.0746e+00 9.5513e-01 9.6354e-02 4.3898e-02 -6.0000e+00 1.1653e+00 -1.2906e+00 5.5877e-02 1.6072e-02 -6.0000e+00 6.9678e-01 5.1079e-01 2.8977e-02 2.0864e-02 -6.0000e+00 2.9868e-01 5.5443e-05 -1.3826e-03 1.4438e-03 2.7102e-04 -6.0000e+00 1.9811e-02 1.5494e-03 0.0000e+00 12 9 8 11 8 0 95.45 22.18 0.30 0.00155 -0.00884 28 6 1 5 0 1802.270 27.78 19.98 22.18 -25535 227846 4738 63726 -43995 151495 -44650 46565 25620 -15220 40167 -18658 269188 -8626 20674 -15616 -30554 99679 361564 21798 168216 10010 79752 238194 45900 -46082 -8919 281025 -10290 296455 900000 26714 -20743 200624 606 155903 -67820 14502 -3955 61792 92308 -2590 180600 -11971 23309 32833 104472 -2922 204249 60264 49027 -13792 15925 83832 -20186 113395 5283 1105 6264 51733 47295 27261 -46849 54398 -10877 66080 29490 11278 -8190 12105 -10290 7644 24798 9122 26417 -11748 71473 -33580 -3215 8275 20070 510 7734 826 5621 353 5673 10217 4977 16492 2744 10678 -20672 15495 -10448 16503 -13713 -5140 3286 -5285 -2518 -3141 2341 -9678 7261 -907 -3500 -7946 13581 -1472 7431 -1445 101 -5530 1161 1523 -981 981 -9329 791 -1585 10145 1354 7385 -3871 2197 83 -1198 1130 -2972 -895 991 4077 -787 1261 885 1611 -392 1963 -1397 -1450 -2623 22 -3795 10498 493 3220 -5297 6980 -4977 2575 2085 -2080 3208 -2579 12403 -1073 1969 -2206 -4974 4593 16659 2009 7751 954 3801 10975 4084 -11202 -1474 12948 -1270 13659 900000 2022 -2697 9244 62 7183 -12946 1460 -594 5905 7404 -561 8321 -2635 3429 4073 5924 -461 9411 5019 4865 -2811 2596 7725 -5618 8778 1266 277 1408 6770 6102 4553 -17719 8146 -3258 8753 5322 2447 -2327 3230 -3999 2619 7153 2924 6509 -3742 8877 -11436 -889 2340 5843 206 3223 393 2720 193 3101 5499 2949 8395 1493 4990 -12563 6596 -6304 8654 -11072 -4535 2929 -5211 -2286 -2605 1683 -7870 5420 -786 -3438 -8671 12943 -1820 9352 -2127 149 -8341 1549 1924 -1333 1364 -15306 1239 -2561 14153 1997 9981 -5648 2913 114 -1704 1755 -5428 -1757 2031 8486 -1828 3086 2308 4278 -1081 5626 -3996 -3900 -6700 52 SS 20210306T111240.0Z 7735.467129 244 1 49.94 2 77.36 88.66 11.01 315.89 0.00 1 0.00 1 0 17 4.053e-01 1.220e-02 1.959e-01 6.206e-03 4.780835e-01 3.286079e-03 4.868470e-03 -6.000000e+00 2.300793e-01 228.28 -2.00 3.11 -2.00 321.24 0.00e+00 2.377334e-03 1.524931e-03 3.900112e-04 -6.000000e+00 1.050564e-02 288.22 -2.00 20.00 -2.00 320.56 0.00e+00 4.444 0.001 302.00 328.00 3 1.5555e+00 1.1441e-02 4.8155e-02 -6.0000e+00 5.7064e-01 1.2423e-01 1.4814e-02 2.3417e-02 -6.0000e+00 6.1885e-01 -1.4709e-01 1.3042e-02 1.1496e-02 -6.0000e+00 3.6948e-01 4.7912e-02 6.3442e-03 4.2171e-03 -6.0000e+00 1.5817e-01 9.2135e-04 -1.4675e-03 1.9179e-04 4.4180e-05 -6.0000e+00 1.0501e-02 1.0867e-03 0.0000e+00 12 8 8 10 0 0 96.89 22.19 0.26 0.00109 -0.00994 174 35 1 5 0 286.987 27.78 20.01 22.19 -141354 -78084 -72757 17293 -75609 900000 -121152 345157 -106473 -2246 -70453 16404 -61893 -3216 43025 -42555 60554 -31243 19973 -38658 39122 -40723 70708 -22235 61680 -11160 27303 -20597 -4660 16020 900000 6517 3809 -2941 -21105 10785 -28824 22055 -24271 11136 -5674 4281 879 6558 2915 1599 18253 -1811 6921 -6076 17236 -214 16103 -1678 11574 -1377 8186 -1003 301 3562 -1161 5830 -702 8838 125 1648 -228 2842 -703 7248 -278 2431 1259 3840 2370 -1190 853 -1749 2516 221 532 -1693 293 -3747 212 -3225 896 -796 447 5 1148 337 -2904 367 -3070 1584 -804 294 -646 -70 -1240 -176 -1400 -371 -555 -1043 -23 -1744 19 -461 617 -548 355 -792 1152 13 789 16 127 389 -741 375 -556 845 -240 2175 -151 2003 -484 964 -46 1081 223 200 -513 -460 94 -279 -17 -256 724 -1056 -84 -3487 -1217 -1168 113 -1126 900000 -2678 2088 -2680 -22 -1381 139 -1333 -47 489 -1349 762 -1059 435 -1590 767 -1838 1052 -891 1151 -456 778 -919 -168 468 900000 279 191 -173 -1449 508 -2123 1131 -2407 934 -640 470 109 792 367 207 2013 -245 870 -894 2157 -35 2566 -343 2191 -307 1707 -231 67 747 -259 1307 -188 2391 41 514 -68 816 -222 2431 -113 1015 535 1529 890 -438 278 -564 825 86 239 -884 165 -2314 134 -2267 641 -602 355 4 824 225 -1863 224 -2089 1169 -693 284 -693 -75 -1354 -172 -1272 -334 -542 -1093 -25 -2045 23 -629 910 -859 548 -1180 1667 18 1073 23 194 629 -1230 601 -870 1263 -346 3140 -212 2790 -761 1661 -86 2118 457 430 -1188 -1126 235 -716 -43 -644 1711 -2411 -198 SS 20210306T111834.0Z 7735.471227 247 1 49.97 2 76.11 87.87 11.89 310.94 0.00 1 0.00 1 0 25 1.732e-01 7.499e-03 1.204e-01 4.925e-03 4.375472e-01 2.569149e-03 4.487146e-03 -6.000000e+00 9.793345e-02 228.28 -2.00 3.11 -2.00 321.00 0.00e+00 2.229373e-04 1.098428e-03 2.577222e-04 -6.000000e+00 4.486407e-03 288.22 -2.00 20.00 -2.00 320.28 0.00e+00 4.069 0.001 302.00 328.00 3 1.6542e+00 8.5718e-03 4.3954e-02 -6.0000e+00 2.4315e-01 4.9863e-02 1.0944e-02 2.0789e-02 -6.0000e+00 2.6376e-01 -7.1846e-02 9.4722e-03 1.0347e-02 -6.0000e+00 1.5763e-01 2.0181e-02 4.6652e-03 2.9791e-03 -6.0000e+00 6.7455e-02 1.2670e-03 -1.1298e-03 1.5236e-04 3.4158e-05 -6.0000e+00 4.5657e-03 8.2170e-04 0.0000e+00 11 8 0 10 0 0 99.81 22.19 0.33 0.00082 -0.00767 188 37 1 5 0 265.797 27.78 19.99 22.19 -71510 -38572 -5470 -86144 900000 -94139 8537 -71169 -26204 -60777 7803 -38917 -51082 -18026 13613 -6045 -9501 441 -18861 106 -16926 -3492 -2319 2592 -15140 20020 -20587 -8687 -5593 -19554 1872 -7495 172 149 -3519 -20831 2272 -2214 10330 -639 3289 5558 900 5491 4696 -4477 -4729 5755 -3047 9426 -709 4737 -43 3413 77 2236 3904 -923 -2791 2310 2156 2255 2741 417 3574 -1700 2417 -2507 1860 1287 1191 -763 1376 249 1208 1223 -66 -796 -1342 1535 -793 1648 -1416 -1063 -408 -44 -687 -417 582 -183 321 -671 362 -867 1649 -526 442 475 -62 -865 -91 -1084 -93 -723 -951 -739 -1461 -722 -1254 517 -257 302 3 232 173 938 82 327 -115 -8 -675 112 451 130 774 -85 634 733 1088 420 694 31 305 70 -251 -598 -613 320 -362 303 -60 157 -387 -1043 -496 -55 -1920 900000 -1899 64 -1340 -362 -1308 87 -740 -1257 -386 256 -162 -291 13 -725 4 -698 -126 -84 95 -724 748 -1186 -430 -252 -1000 84 -423 10 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