File name: Pandora125s1_Cordoba_20210417_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142833.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210417_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210417T113702.0Z 7777.484051 56 1 49.99 2 78.71 69.84 135.95 85.78 0.00 1 0.00 1 0 17 5.326e-01 2.151e-02 3.168e-01 1.057e-02 5.104945e-01 5.701759e-03 5.191692e-03 -6.000000e+00 3.001706e-01 226.26 -2.00 3.11 -2.00 321.48 0.00e+00 4.369686e-03 2.845453e-03 1.632316e-03 -6.000000e+00 1.466746e-02 286.37 -2.00 20.00 -2.00 320.85 0.00e+00 4.932 0.001 302.00 328.00 3 1.8618e+00 2.0495e-02 5.4539e-02 -6.0000e+00 7.4558e-01 2.4153e-01 2.6803e-02 3.1306e-02 -6.0000e+00 8.1195e-01 -3.1610e-01 2.3760e-02 1.2296e-02 -6.0000e+00 4.8162e-01 1.1356e-01 1.1381e-02 7.1135e-03 -6.0000e+00 2.0805e-01 4.1473e-04 -1.1143e-03 3.3258e-04 6.0475e-05 -6.0000e+00 1.4148e-02 8.3838e-04 0.0000e+00 12 8 8 10 0 0 97.86 22.37 0.45 0.00084 -0.00754 99 20 1 5 0 504.857 27.99 19.99 22.37 900000 -75803 122074 -55934 165310 -104726 294820 -153905 900000 -125676 900000 -89799 900000 -4274 42646 8575 -18701 95489 -30457 171486 69417 76063 -31543 213051 -20901 106027 -36167 51587 10715 35319 -111483 -12276 23285 -25754 176207 -30078 74480 -2823 44239 -6780 37751 -801 32676 26320 37471 12229 16579 24631 9042 8407 4199 37167 8014 14096 2187 14286 1391 10319 2425 18994 2581 3919 8986 3089 7270 1269 6490 -3096 -1003 2787 7069 -259 7465 4157 3673 3732 -6801 8 -1235 570 -5789 3821 -7388 2634 -3700 764 -2220 90 2834 707 -3323 1509 -368 -5956 2013 -5452 1968 -1319 1958 -2629 139 -2331 1540 -1949 648 223 -2387 70 -791 566 -1317 882 -1375 1759 -1610 694 -1617 868 -1078 559 -801 -187 1459 402 2181 38 1630 -168 1131 829 1692 -300 1166 -195 486 44 -732 696 -740 386 -794 933 -1915 900000 -1359 1258 -875 1703 -2158 3037 -5696 900000 -4332 900000 -2242 900000 -66 507 170 -541 984 -1134 1767 1018 1025 -1287 2195 -853 1267 -1818 1042 309 800 -12219 -606 919 -1813 1815 -2001 1822 -172 2032 -620 2495 -83 2649 2334 2987 1271 1663 2295 1000 964 540 3968 1242 2205 406 2415 274 1860 460 2979 485 784 2006 817 1954 350 1611 -838 -283 871 2365 -98 2761 1520 1249 1136 -2088 2 -372 197 -2481 1691 -4015 1439 -2293 486 -1540 63 1953 484 -2215 884 -206 -3675 1247 -4156 1597 -1261 1992 -2838 137 -2143 1244 -1631 572 224 -2579 78 -964 752 -1956 1352 -2149 2550 -2258 900 -2137 1171 -1584 909 -1336 -302 2243 605 3093 52 2134 -227 1676 1379 3033 -579 2454 -439 1088 111 -1923 1840 -1996 1000 -1977 2160 -4419 SS 20210417T114404.8Z 7777.488945 59 1 49.67 2 77.31 68.80 134.53 85.00 0.00 1 0.00 1 0 25 3.345e-01 1.677e-02 2.736e-01 1.125e-02 4.696541e-01 6.037472e-03 4.866153e-03 -6.000000e+00 1.904830e-01 226.26 -2.00 3.11 -2.00 321.26 0.00e+00 4.928598e-04 2.816310e-03 1.218698e-03 -6.000000e+00 9.305962e-03 286.37 -2.00 20.00 -2.00 320.59 0.00e+00 4.427 0.001 302.00 328.00 3 2.5945e+00 2.0892e-02 4.8123e-02 -6.0000e+00 4.7252e-01 9.1225e-02 2.7294e-02 2.4322e-02 -6.0000e+00 5.1508e-01 -1.3210e-01 2.4372e-02 1.1584e-02 -6.0000e+00 3.0463e-01 4.3208e-02 1.1771e-02 3.4815e-03 -6.0000e+00 1.3183e-01 3.4232e-04 -1.1317e-03 3.5612e-04 4.0155e-05 -6.0000e+00 9.0629e-03 4.8151e-04 0.0000e+00 12 8 8 10 0 0 97.97 22.36 0.59 0.00048 -0.00802 64 13 1 5 0 775.953 27.88 20.00 22.36 900000 -52839 900000 -113186 900000 -99963 900000 -17527 900000 95009 900000 -111273 51505 -51372 -79300 900000 -58044 167572 -45348 148227 -22744 46185 44861 35233 -6711 25887 -23522 -16451 82492 8051 -85594 -16697 49799 12156 32641 -27443 10875 -10827 20012 -7958 6385 6965 -3473 3810 -4038 7333 7405 16972 -6435 27547 -7053 14182 5766 13926 473 11464 5674 6345 7745 -990 7431 -7265 11245 4844 7958 1688 6824 -275 8897 -1 907 -2648 2829 3588 -1561 4353 -4259 10813 -1662 4033 -4563 1493 -1343 -5202 -315 2213 -2112 312 -2160 -1423 -306 -2834 852 -1890 3444 -933 1106 569 171 -864 -1699 -202 1259 -528 -1615 -272 -2929 -667 315 79 -627 969 -1263 839 -518 1760 365 -1279 247 -1056 101 -274 498 -940 1389 1664 2470 -240 2173 1000 1131 73 28 426 -821 -302 -846 172 89 1213 -899 38 -1094 900000 -620 900000 -2710 900000 -1744 900000 -192 900000 1041 900000 -3516 564 -1255 -3107 900000 -2397 1836 -1892 1624 -824 837 832 772 -253 749 -1144 -721 1265 258 -7651 -863 1506 586 1296 -1879 536 -771 1279 -814 644 750 -434 454 -544 891 903 1884 -913 2860 -1112 1999 961 2302 99 2226 1206 1349 1585 -216 1510 -1838 2637 1346 2263 516 1869 -80 2511 0 357 -1144 1164 1409 -600 1488 -1437 3020 -557 1478 -2115 738 -749 -3188 -196 1443 -1526 241 -1719 -1093 -217 -1903 514 -1152 2146 -689 912 535 177 -964 -1803 -191 1079 -463 -1552 -276 -3193 -752 378 105 -909 1453 -2034 1261 -736 2305 482 -1791 363 -1673 160 -428 792 -1469 2030 2328 3266 -329 3207 1659 2028 138 56 879 -1834 -711 -2056 421 234 3082 -2219 88 -2490 SS 20210417T114926.3Z 7777.492665 62 1 42.57 2 76.25 67.99 133.44 84.41 0.00 1 0.00 1 0 17 6.697e-01 5.048e-02 2.357e-01 1.082e-02 4.043719e-01 5.612798e-03 6.017230e-03 -6.000000e+00 3.773168e-01 226.26 -2.00 3.11 -2.00 320.91 0.00e+00 1.405047e-02 2.320041e-03 5.035605e-03 -6.000000e+00 1.703040e-02 286.37 -2.00 20.00 -2.00 320.20 0.00e+00 4.109 0.001 302.00 328.00 3 2.8372e+00 1.8468e-02 4.6045e-02 -6.0000e+00 9.3551e-01 4.0249e-01 2.2275e-02 2.3600e-02 -6.0000e+00 1.0173e+00 -6.3888e-01 1.6878e-02 1.8721e-02 -6.0000e+00 6.0564e-01 2.7804e-01 8.6440e-03 1.1128e-02 -6.0000e+00 2.5870e-01 3.6422e-04 -7.7630e-04 3.3803e-04 1.7743e-04 -6.0000e+00 1.7481e-02 1.1994e-04 0.0000e+00 12 9 9 12 9 1 98.68 22.36 0.41 0.00012 -0.00571 43 10 1 5 0 963.679 27.99 20.00 22.36 131244 136261 199737 45581 155992 52421 118932 25889 900000 45448 409445 32138 250368 222212 93596 97314 110661 155672 113219 109858 66244 92471 56926 112793 83948 78045 49718 101854 12533 88782 -129622 44175 59611 61601 89925 32652 53628 34943 43138 48997 45945 32410 25972 34667 25522 39196 24275 36024 29380 32223 22270 34177 28934 32743 15260 15834 9654 8680 9170 9726 7142 9439 13038 10163 18555 6011 11836 3784 7823 6075 6301 5388 4306 2239 -922 910 -4054 -1037 -295 3713 -2112 2510 -3032 -2092 -3944 27 -3523 -4349 -2076 -845 431 -3687 -2399 -5041 -1473 -3784 -193 -2204 408 -3461 74 -4193 -3219 -2131 -2094 -2619 -3293 -2072 -926 437 -683 -90 637 -117 -2150 1102 113 813 432 366 768 523 2510 2040 3224 699 2269 2288 3499 2649 1536 289 235 844 250 -1271 -191 -327 -405 -102 -1195 -563 -1702 2307 2708 2188 2219 2151 1744 1882 1029 900000 1493 4318 1152 2641 2344 3119 3613 3875 3612 4156 4218 3913 3979 3290 3616 3652 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