File name: Pandora125s1_Cordoba_20210418_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142842.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210418_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210418 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210418T112037.0Z 7778.472650 50 1 49.92 2 82.16 71.87 149.87 92.88 0.00 1 0.00 1 0 25 5.588e-01 4.575e-02 4.460e-01 3.843e-02 6.029260e-01 2.161477e-02 6.203342e-03 -6.000000e+00 3.187492e-01 226.22 -2.00 3.11 -2.00 321.99 0.00e+00 7.987940e-03 1.068050e-02 3.970447e-04 -6.000000e+00 1.562632e-02 286.30 -2.00 20.00 -2.00 321.42 0.00e+00 6.836 0.003 302.00 328.00 3 1.6836e+00 8.0719e-02 7.1256e-02 -6.0000e+00 7.9129e-01 9.3465e-01 9.6840e-02 3.1118e-02 -6.0000e+00 8.6388e-01 -1.2796e+00 6.0512e-02 1.3834e-02 -6.0000e+00 5.1538e-01 4.9892e-01 3.0488e-02 7.0516e-03 -6.0000e+00 2.2126e-01 7.3610e-05 -1.7836e-03 1.2374e-03 9.4522e-05 -6.0000e+00 1.4794e-02 1.3503e-03 0.0000e+00 12 9 8 11 8 0 99.03 22.30 0.67 0.00135 -0.01205 43 9 1 5 0 1160.822 27.88 19.99 22.30 -39446 900000 -15925 900000 241293 900000 -61321 112274 -59368 8199 900000 85595 -55227 -21923 96230 900000 900000 46599 900000 69564 299594 -51860 99817 -57359 102930 13892 33652 32138 -26591 -48708 900000 900000 10003 109336 -675 134692 6142 136882 110926 99821 57532 128334 27776 77544 -18476 40350 19693 36913 37361 28848 78355 -22310 132462 -2824 13010 97407 80201 8691 40872 35107 6693 58749 -442 49029 19117 63632 -20405 62940 -9711 9548 -19275 27072 9289 33732 4803 8444 10533 -15938 32805 -24929 2399 682 1821 5924 8200 -5161 607 2717 8267 -11456 -84 -3904 -8540 7360 -2827 -2112 -4794 -13 -28 6058 -1158 4825 -15683 351 -5153 -2668 1041 -3627 4494 -1099 1011 -10520 3214 -887 2963 1659 2685 1861 -4522 2847 -5045 6857 970 4135 1829 1905 -4338 4639 -1325 2495 692 5066 394 -263 -214 -1076 -556 40 -271 -1453 2170 -3703 1909 -3714 900000 -1371 900000 9029 900000 -4818 4201 -4749 328 900000 3203 -4275 -1471 3601 900000 900000 2345 900000 2782 11210 -6445 3735 -6899 3851 798 1529 1374 -1883 -4388 900000 900000 707 4091 -52 5040 400 5122 4151 3879 3726 4802 2558 4352 -2659 3194 1899 3094 3131 2677 4691 -3974 5353 -465 1889 6378 6252 1355 4397 3831 970 5404 -82 6192 3608 7453 -5245 6963 -2354 2175 -6491 5990 2433 6827 1184 1781 1971 -3795 5189 -8268 710 234 714 2354 3375 -2593 304 1380 3992 -6552 -40 -1885 -4074 3002 -1407 -1209 -3274 -10 -24 4862 -996 3535 -12786 242 -4059 -2197 871 -3407 4248 -1233 1241 -15517 4410 -1230 3739 2025 3248 2386 -6617 4101 -7928 9840 1429 5743 2508 2525 -5882 5902 -2012 4146 1290 9646 824 -624 -546 -2933 -1548 113 -770 -4057 5512 -9379 4401 SS 20210418T113746.0Z 7778.484560 55 1 49.96 2 78.72 69.41 146.39 90.53 0.00 1 0.00 1 0 25 3.141e-01 1.287e-02 2.690e-01 9.229e-03 5.172479e-01 4.929596e-03 5.282316e-03 -6.000000e+00 1.761220e-01 226.22 -2.00 3.11 -2.00 321.47 0.00e+00 -7.390002e-04 2.455734e-03 8.557290e-04 -6.000000e+00 7.934102e-03 286.30 -2.00 20.00 -2.00 320.85 0.00e+00 4.937 0.001 302.00 328.00 3 1.6053e+00 1.7756e-02 5.3313e-02 -6.0000e+00 4.3561e-01 1.6563e-01 2.3415e-02 2.6008e-02 -6.0000e+00 4.7339e-01 -2.3547e-01 2.0829e-02 1.2582e-02 -6.0000e+00 2.8305e-01 8.7783e-02 9.9322e-03 3.9909e-03 -6.0000e+00 1.2129e-01 5.4687e-04 -1.3891e-03 2.8734e-04 4.8046e-05 -6.0000e+00 8.1244e-03 5.1032e-04 0.0000e+00 12 8 8 10 0 0 96.68 22.32 0.43 0.00051 -0.00993 132 26 1 5 0 378.450 27.88 20.01 22.32 -91064 2759 -143815 21120 -55813 -67416 -143746 -122633 -13154 -113442 -65768 -79786 -58120 -71703 64419 -53395 30922 10891 -24784 -10231 -19353 -929 -22621 -16164 -35132 1414 -43258 74114 -66788 -7529 6554 35302 -21474 32481 -9500 16624 -1091 681 3234 10607 10945 5946 23017 -2764 8273 2559 21449 -3004 7453 6345 9102 1976 9787 4756 653 9823 6927 19313 3391 11737 -4034 14999 802 5512 4311 4407 -863 7957 2330 831 1560 1609 -1526 -1032 2119 -3641 5538 -5056 3742 -1498 -1539 1466 -1249 -1377 -1313 581 -5 -519 -2239 2437 -1301 -166 -1143 -1336 1644 -28 -1994 -368 1346 -927 -309 -3175 -491 -1655 -1680 -2527 539 -913 -118 -455 556 -695 907 394 -468 321 67 762 93 213 -899 35 544 828 1740 1385 151 935 246 279 790 125 821 -464 -222 -670 -59 380 -48 -139 155 -194 -796 -1184 25 -4027 190 -577 -719 -3402 -2759 -118 -2945 -1093 -1574 -1066 -1837 580 -1627 450 207 -721 -269 -576 -24 -725 -524 -1505 45 -2196 1121 -3871 -239 206 966 -1184 1145 -495 630 -52 37 210 776 951 584 1991 -316 845 278 1939 -348 790 703 1106 286 1429 788 120 1708 1284 3184 638 1974 -839 2764 190 1394 1171 1160 -227 1906 631 263 550 601 -621 -401 739 -1206 1518 -1490 1076 -528 -632 666 -676 -790 -803 374 -4 -372 -1643 1660 -861 -100 -690 -799 1037 -20 -1701 -352 1391 -993 -311 -2979 -410 -1397 -1627 -2635 572 -1044 -143 -616 818 -1096 1405 588 -659 424 88 1104 144 352 -1515 57 851 1251 2499 1919 202 1260 369 468 1435 258 1743 -1053 -538 -1726 -155 1013 -129 -363 385 -456 -1822 SS 20210418T114447.0Z 7778.489433 58 1 49.97 2 77.33 68.37 144.97 89.64 0.00 1 0.00 1 0 25 2.494e-01 9.080e-03 1.167e-01 4.734e-03 4.672616e-01 2.464771e-03 4.773608e-03 -6.000000e+00 1.398654e-01 226.22 -2.00 3.11 -2.00 321.19 0.00e+00 2.693658e-03 1.130757e-03 2.675873e-04 -6.000000e+00 6.300341e-03 286.30 -2.00 20.00 -2.00 320.52 0.00e+00 4.434 0.001 302.00 328.00 3 1.0943e+00 8.4602e-03 4.7637e-02 -6.0000e+00 3.4594e-01 9.2722e-02 1.0941e-02 2.2382e-02 -6.0000e+00 3.7592e-01 -1.3254e-01 9.7368e-03 1.1306e-02 -6.0000e+00 2.2478e-01 4.4430e-02 4.7309e-03 4.2826e-03 -6.0000e+00 9.6329e-02 1.5250e-03 -1.1285e-03 1.4511e-04 4.6472e-05 -6.0000e+00 6.4512e-03 -1.3148e-04 0.0000e+00 11 9 0 11 8 0 62.57 22.36 0.26 -0.00013 -0.00861 266 53 1 5 0 187.828 27.99 20.01 22.36 -72406 -21458 -88388 -55339 -121574 -94224 -116523 -45260 -85209 -57726 -13866 -27748 -59089 -44958 -23929 -30680 41677 -34616 36036 -34633 19915 -9629 24567 -10456 -5878 -6116 -26807 -9143 -13921 20792 -11783 15430 -4558 4524 -11618 16720 -14097 5164 -7028 3856 5112 3008 6078 -2787 3496 -4344 15452 -1564 8934 2764 7968 -337 4387 4137 5928 3865 5880 3812 -760 5663 -653 7261 -1805 6364 -1693 2856 1388 3463 -1076 558 2452 -1206 2756 -1569 1389 -2144 847 -1226 4417 -807 1842 -2187 -739 -3055 -576 -456 -461 126 -1998 1629 -729 798 -1689 1233 -1078 641 -504 -262 613 -470 152 -1125 -243 -1221 282 -1461 -341 -1339 454 -741 35 308 221 283 -114 34 179 747 -132 -17 -789 131 354 1116 -5 572 235 895 620 200 747 14 242 -183 -282 -265 129 -8 -184 -300 254 -122 -357 -936 -198 -1730 -777 -2986 -1618 -2561 -543 -1731 -1010 -160 -379 -1284 -1046 -552 -897 657 -1258 693 -1419 490 -317 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