File name: Pandora125s1_Cordoba_20210419_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142855.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210419_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210419T114438.0Z 7779.489329 61 1 50.03 2 77.52 68.08 155.38 98.27 0.00 1 0.00 1 0 17 5.087e-01 1.352e-02 3.098e-01 9.006e-03 4.874519e-01 4.826305e-03 4.927296e-03 -6.000000e+00 2.859602e-01 226.17 -2.00 3.11 -2.00 321.35 0.00e+00 -9.878024e-05 2.352228e-03 1.081314e-03 -6.000000e+00 1.363037e-02 286.24 -2.00 20.00 -2.00 320.70 0.00e+00 4.497 0.001 302.00 328.00 3 1.8975e+00 1.7065e-02 4.8994e-02 -6.0000e+00 7.0838e-01 7.2095e-02 2.2951e-02 2.4808e-02 -6.0000e+00 7.7010e-01 -1.0694e-01 2.1324e-02 1.2309e-02 -6.0000e+00 4.5949e-01 3.5236e-02 1.0159e-02 3.6256e-03 -6.0000e+00 1.9828e-01 6.3155e-04 -1.3255e-03 2.8429e-04 4.2291e-05 -6.0000e+00 1.3594e-02 -8.3018e-04 0.0000e+00 12 8 8 10 0 0 99.98 22.38 0.33 -0.00083 -0.01079 181 36 1 5 0 276.359 27.99 20.02 22.38 -30560 -53736 38265 900000 900000 277248 -92722 -19813 -109233 900000 -122420 164346 -94433 360180 -78589 47081 -40213 53778 104265 22961 55109 -13087 3423 -42709 25769 -16879 61823 -54219 88752 -20141 900000 -33247 75233 8322 20632 28369 -803 15147 -16589 16631 -15218 23906 -9354 3333 -18885 19983 -2820 26839 -3831 6125 10491 -1688 16560 254 11367 -7071 9765 1828 13639 -5385 8764 -1296 1241 7018 -313 -1314 -658 -1609 260 5190 -708 3050 -3788 6188 -898 5802 -2069 3696 4675 1483 96 -659 -1391 -756 2345 -2913 1416 -337 87 -1946 1548 -1772 -483 195 1384 109 17 596 -1615 245 -1416 -700 -1790 1928 -1800 260 -1513 -1281 -2205 -157 -500 370 522 -550 1721 -579 853 -60 1252 -607 811 44 943 261 517 821 -413 1379 -348 1657 -453 371 -844 2 -751 420 -321 381 -174 -37 30 -746 385 -268 -488 336 900000 900000 2433 -1221 -174 -2226 900000 -3262 1442 -2279 3161 -2504 505 -1150 647 915 425 770 -362 81 -1735 578 -644 1106 -3002 1108 -741 900000 -1773 1549 368 818 986 -39 739 -1363 1191 -1715 1964 -1123 362 -2673 1937 -345 2454 -483 721 1274 -257 2289 45 1978 -1538 1859 380 2462 -1147 1639 -288 300 1867 -95 -390 -183 -449 76 1659 -269 1185 -1588 2366 -343 1860 -650 1056 1403 532 41 -320 -747 -448 1436 -2022 998 -252 65 -1446 1039 -1134 -285 118 897 81 14 572 -1742 263 -1459 -650 -1536 1684 -1768 267 -1659 -1485 -2768 -212 -743 575 804 -819 2338 -759 1157 -86 1883 -987 1318 70 1446 391 738 1122 -578 1918 -543 2820 -853 730 -1739 5 -1739 1019 -806 969 -448 -94 72 -1805 892 SS 20210419T115025.8Z 7779.493354 64 1 39.59 2 76.38 67.21 154.21 97.21 0.00 1 0.00 1 0 25 3.733e-01 2.475e-02 2.809e-01 1.544e-02 4.402340e-01 8.178600e-03 4.934730e-03 -6.000000e+00 2.113799e-01 226.17 -2.00 3.11 -2.00 321.03 0.00e+00 9.911372e-03 3.465218e-03 1.738157e-03 -6.000000e+00 1.026700e-02 286.24 -2.00 20.00 -2.00 320.33 0.00e+00 4.146 0.001 302.00 328.00 3 2.9285e+00 2.7008e-02 4.4577e-02 -6.0000e+00 5.2473e-01 2.6114e-01 3.3461e-02 2.0669e-02 -6.0000e+00 5.7092e-01 -2.8955e-01 2.7289e-02 1.3755e-02 -6.0000e+00 3.3871e-01 1.0545e-01 1.3575e-02 9.0211e-03 -6.0000e+00 1.4636e-01 3.0211e-04 -1.0100e-03 4.8629e-04 1.0985e-04 -6.0000e+00 9.8528e-03 1.8145e-03 0.0000e+00 12 9 9 12 9 1 99.99 22.41 0.36 0.00181 -0.00578 77 20 1 5 0 505.409 27.99 20.02 22.41 -22966 900000 -87712 89946 -59028 97756 -134859 900000 -118847 900000 -2836 900000 -35364 141420 24017 208307 43002 70873 107273 -9074 -979 -6617 900000 -39890 52529 2513 39976 -20994 63293 -43741 900000 80272 27180 32140 -18697 59774 -35910 40072 -25087 20266 -635 45064 -8834 28850 12531 16137 -10930 11370 35168 9513 8910 8583 16012 -5034 17006 421 17591 -984 8254 -674 5336 -2683 14013 6492 5999 7172 -7652 6410 -12223 2711 3765 15017 -1610 7517 -4341 9550 1554 4233 1507 -1225 -2203 -637 199 -7452 2084 -5884 674 -2131 3106 -3717 -1801 -1924 -3900 -1041 -2343 335 -2216 3535 -1721 998 -3440 3071 -1414 1521 -1331 -1895 -1953 -1199 -778 93 803 -2020 1943 -1241 3842 -2294 1072 -280 1376 -1354 893 653 133 651 1869 2327 -1334 2961 -543 3047 -744 1082 -465 1415 -1462 -26 -219 458 -497 -1168 429 -702 68 -426 900000 -3957 1353 -1746 1470 -7692 900000 -6533 900000 -50 900000 -1027 2127 598 3132 1160 1544 1786 -502 -51 -355 900000 -2956 1580 127 1396 -1356 1692 -3459 900000 2370 1544 1880 -1739 2364 -3988 2364 -3366 2028 -87 4144 -1456 3371 1747 2300 -2064 1723 4231 1505 1506 1590 2957 -1217 3570 106 3770 -252 1877 -165 1264 -746 3688 2131 2079 2354 -2727 1941 -4699 1025 1566 5861 -742 3165 -1908 3277 523 1334 518 -502 -1054 -338 120 -5075 1370 -4491 510 -1721 2398 -2989 -1326 -1302 -2616 -664 -1630 257 -1993 3405 -1912 1089 -3693 2799 -1301 1364 -1331 -2030 -2196 -1417 -980 128 1187 -3207 2928 -1832 5287 -3165 1423 -394 2036 -2189 1433 1027 203 1014 2750 3267 -1849 3976 -829 4973 -1360 2032 -915 2864 -3245 -61 -521 1104 -1293 -2976 1023 -1610 151 SS 20210419T115637.0Z 7779.497650 67 1 50.00 2 75.17 66.26 152.97 96.14 0.00 1 0.00 1 0 25 2.703e-01 1.351e-02 1.795e-01 5.569e-03 4.152326e-01 2.884448e-03 4.292949e-03 -6.000000e+00 1.527409e-01 226.17 -2.00 3.11 -2.00 320.88 0.00e+00 2.731589e-03 1.185658e-03 2.239550e-04 -6.000000e+00 6.997902e-03 286.24 -2.00 20.00 -2.00 320.17 0.00e+00 3.830 0.000 302.00 328.00 3 1.8526e+00 9.4442e-03 4.1404e-02 -6.0000e+00 3.7742e-01 7.3804e-02 1.1825e-02 1.9925e-02 -6.0000e+00 4.1021e-01 -8.6676e-02 1.0080e-02 9.9259e-03 -6.0000e+00 2.4453e-01 2.3808e-02 5.0226e-03 3.9174e-03 -6.0000e+00 1.0460e-01 1.3085e-03 -1.2538e-03 1.7345e-04 4.1042e-05 -6.0000e+00 7.1481e-03 -1.5165e-03 0.0000e+00 12 8 8 10 0 0 99.99 22.43 0.35 -0.00152 -0.01094 265 53 1 5 0 188.632 27.99 20.00 22.43 134131 -66268 101619 -74993 900000 -64925 900000 -96464 137100 -55627 39364 11944 -3946 -7019 -52230 28083 -48067 67081 -11159 25262 -35023 30413 -21734 26501 2288 -641 -5053 -12626 20095 -18256 39872 -20052 19962 -11698 35218 -13377 36637 -13608 16998 -1215 3959 3832 251 3277 -8143 16163 -1650 10740 -8690 11323 -3409 10272 -990 9435 -1356 5967 2685 924 5236 -3405 6477 -4211 5640 -193 4544 -2744 6071 -1995 4452 1514 1383 1312 -1703 1219 -1911 3735 -2918 890 -3237 2519 -2456 3358 -4071 52 -1623 -102 259 -867 27 -1976 506 -1242 2298 -2137 2097 -2584 1517 -453 1113 41 363 -1507 -1040 650 -1489 -405 -2118 1114 -1305 1236 -1024 925 -576 1055 -645 298 267 247 522 -1207 126 -920 762 -616 2635 -628 1474 595 1655 -85 432 267 -132 385 -818 4 -828 883 -577 523 -436 609 -957 728 -1465 552 -1948 900000 -1305 900000 -3006 744 -1421 396 161 -71 -159 -2258 638 -2581 1214 -489 807 -2121 953 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