File name: Pandora125s1_Cordoba_20210420_L2Fit_fout2c5d20170323p1-8.txt File generation date: 20250311T142846.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 125 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora125_OF_v5d20170323.txt Instrument calibration file used: Pandora125s1_CF_v5d20170323.txt Level 1 file used: Pandora125s1_Cordoba_20210420_L1_smca1c5d20170323p1-8.txt Full location name: CITEDEF/SMN Cordoba Short location name: Cordoba Country of location: Argentina Location latitude [deg]: -31.6755 Location longitude [deg]: -63.8730 Location altitude [m]: 332 Local noon date: 20210420 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 213 355 Nominal wavelengths inside fitting window [nm]: 305.0083 305.1495 305.2906 305.4318 305.5729 305.7140 305.8551 305.9962 306.1373 306.2783 306.4194 306.5604 306.7015 306.8425 306.9835 307.1245 307.2655 307.4065 307.5474 307.6884 307.8294 307.9703 308.1112 308.2521 308.3930 308.5339 308.6748 308.8157 308.9565 309.0974 309.2382 309.3790 309.5198 309.6606 309.8014 309.9422 310.0830 310.2237 310.3645 310.5052 310.6459 310.7866 310.9273 311.0680 311.2087 311.3494 311.4900 311.6307 311.7713 311.9119 312.0525 312.1931 312.3337 312.4743 312.6149 312.7554 312.8960 313.0365 313.1770 313.3175 313.4580 313.5985 313.7390 313.8794 314.0199 314.1603 314.3008 314.4412 314.5816 314.7220 314.8624 315.0027 315.1431 315.2835 315.4238 315.5641 315.7044 315.8448 315.9851 316.1253 316.2656 316.4059 316.5461 316.6864 316.8266 316.9668 317.1070 317.2472 317.3874 317.5276 317.6677 317.8079 317.9480 318.0881 318.2282 318.3683 318.5084 318.6485 318.7886 318.9286 319.0687 319.2087 319.3488 319.4888 319.6288 319.7688 319.9087 320.0487 320.1887 320.3286 320.4685 320.6085 320.7484 320.8883 321.0282 321.1680 321.3079 321.4477 321.5876 321.7274 321.8672 322.0071 322.1468 322.2866 322.4264 322.5662 322.7059 322.8457 322.9854 323.1251 323.2648 323.4045 323.5442 323.6839 323.8235 323.9632 324.1028 324.2424 324.3820 324.5217 324.6612 324.8008 324.9404 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210420T114316.3Z 7780.488384 61 1 2.68 2 77.95 67.96 164.98 119.01 0.00 1 0.00 1 0 25 5.237e-01 5.051e-02 3.838e-01 4.269e-02 5.179622e-01 2.324271e-02 6.535661e-03 -6.000000e+00 3.011458e-01 226.13 -2.00 3.11 -2.00 320.91 0.00e+00 -7.329950e-03 9.083820e-03 5.111057e-03 -6.000000e+00 1.518103e-02 286.17 -2.00 20.00 -2.00 320.21 0.00e+00 4.646 0.001 302.00 328.00 3 2.6536e+00 7.4869e-02 5.4551e-02 -6.0000e+00 7.4731e-01 3.6238e-01 9.3029e-02 3.5938e-02 -6.0000e+00 8.1586e-01 -5.1219e-01 7.0795e-02 2.1361e-02 -6.0000e+00 4.8412e-01 2.0999e-01 3.4777e-02 7.6485e-03 -6.0000e+00 2.0824e-01 2.3974e-04 -1.8711e-03 1.3416e-03 1.3684e-04 -6.0000e+00 1.4155e-02 -1.6380e-03 0.0000e+00 12 9 9 12 1 1 999.00 22.41 0.33 -0.00164 -0.01570 1 8 1 5 0 1253.177 27.99 20.02 22.41 96071 900000 900000 217212 900000 -106914 900000 139105 900000 -138441 166007 -28267 900000 28004 900000 -45015 35022 900000 -534 900000 -10986 900000 -36162 900000 -33486 900000 13852 211199 -58480 900000 -30685 900000 -32047 270136 127701 -8298 61438 -9047 77555 27773 69750 -17621 37036 -4522 27117 57112 14777 122993 -31399 -7069 -2216 10768 1731 29350 -11521 60776 -5932 13583 14131 27285 11079 -9422 28746 9287 19040 1961 72336 2934 -14369 -5527 12476 4722 264 1096 4264 -7009 15529 20794 -11791 18277 -12022 17000 -18991 -3596 -2555 2520 -3897 8879 -4979 11864 -1795 -11555 1254 355 8497 -3162 3323 -10223 9184 -2843 3197 -2979 8327 -3379 4929 1050 -4466 -3770 -2949 1500 -2838 1906 -2405 5314 -1578 1590 -2817 1714 -571 -2567 -1514 -1693 5266 1595 -2384 1982 894 3208 5692 985 1193 -1193 4066 -1468 -552 297 -371 -500 1585 2178 -5347 184 -263 3988 900000 900000 9017 900000 -5548 900000 5775 900000 -14727 6891 -1173 900000 1163 900000 -3364 1454 900000 -30 900000 -699 900000 -2902 900000 -3151 900000 882 8767 -6474 900000 -2730 900000 -3611 11214 5301 -714 2733 -939 4139 2965 5584 -3605 4502 -831 3538 5419 2103 6284 -6983 -1354 -432 2029 387 5342 -3348 8927 -1762 3340 3339 5402 2547 -2798 6426 2788 5472 645 12011 890 -5506 -2224 4701 2036 120 512 1785 -2934 4674 5683 -4691 6196 -6405 7704 -13599 -2339 -1750 1761 -3073 6389 -4134 8085 -1310 -8594 768 216 5611 -2439 2736 -10927 8896 -3157 3163 -2845 7070 -3214 4669 1106 -5208 -4239 -3529 1894 -4113 2788 -3677 7225 -2346 2160 -3955 2393 -869 -4223 -2497 -2728 7652 2329 -3472 2655 1154 4488 7776 1576 2070 -2237 7503 -3013 -1201 678 -876 -1202 3751 4973 -12451 382 -528 SS 20210420T114929.0Z 7780.492697 64 1 50.10 2 76.73 67.03 163.86 116.17 0.00 1 0.00 1 0 25 1.957e-01 7.839e-03 1.486e-01 6.251e-03 4.503825e-01 3.257936e-03 4.676875e-03 -6.000000e+00 1.097111e-01 226.13 -2.00 3.11 -2.00 321.10 0.00e+00 8.564148e-04 1.420115e-03 1.299792e-03 -6.000000e+00 4.940509e-03 286.17 -2.00 20.00 -2.00 320.41 0.00e+00 4.248 0.001 302.00 328.00 3 1.6188e+00 1.0896e-02 4.6254e-02 -6.0000e+00 2.7131e-01 9.6572e-02 1.3971e-02 2.3701e-02 -6.0000e+00 2.9484e-01 -1.1160e-01 1.2268e-02 1.0955e-02 -6.0000e+00 1.7629e-01 3.1366e-02 6.0069e-03 3.4315e-03 -6.0000e+00 7.5567e-02 1.0879e-03 -1.2743e-03 1.9342e-04 3.6966e-05 -6.0000e+00 5.0613e-03 -1.0079e-03 0.0000e+00 11 9 0 11 8 0 99.99 22.44 0.29 -0.00101 -0.01058 234 47 1 5 0 214.081 27.99 20.01 22.44 -36530 -42512 -16083 -47729 -91867 -82804 -55661 -16240 -78129 -62646 -82765 9700 -70548 -27217 -32685 24809 -8061 -13324 11037 5522 5521 -18719 -28356 -4166 -5525 -663 -4524 -16268 1325 -22590 -15938 -2662 3949 -4956 -6362 -5148 439 -10113 5349 5322 -1022 2415 5106 6039 361 2032 1893 3099 6790 1149 -932 6047 4327 2428 250 -1127 5364 -2726 6424 2326 3539 2222 3622 4056 2594 -1302 318 -1135 -1231 3073 -72 579 -1080 1658 2272 2004 873 -465 -4301 1495 -491 -1154 -2253 -822 -18 -1205 -104 64 -160 -482 476 85 452 621 -603 -41 -16 396 299 42 -391 -876 -139 -273 -135 -1053 -1164 -1479 -720 -49 -260 233 53 170 -85 447 385 122 -14 -600 -369 -507 727 76 276 1063 465 1052 775 772 532 545 221 278 -494 -270 -488 340 -196 -90 -198 17 -317 -374 -566 -178 -722 -1950 -1477 -779 -172 -1764 -1329 -2290 109 -2034 -619 -950 477 -238 -444 308 171 177 -764 -1283 -165 -240 -29 -212 -829 53 -1140 -820 -138 217 -339 -428 -323 27 -814 450 541 -126 309 664 832 53 295 276 447 952 175 -155 1032 815 523 58 -275 1266 -702 1476 544 829 566 1013 1252 898 -451 102 -363 -418 1145 -31 263 -501 721 960 763 304 -157 -1593 602 -234 -626 -1354 -514 -12 -866 -78 52 -133 -392 358 59 291 390 -412 -32 -14 390 341 49 -429 -876 -126 -250 -134 -1122 -1302 -1755 -906 -67 -389 364 88 266 -124 610 520 172 -21 -970 -604 -814 1188 120 419 1537 643 1459 1181 1305 974 1046 440 580 -1110 -640 -1192 842 -526 -235 -492 40 -727 SS 20210420T121835.1Z 7780.512906 73 1 50.14 2 71.13 62.44 158.35 106.37 0.00 1 0.00 1 0 17 3.452e-02 5.044e-03 1.974e-02 1.706e-03 3.283925e-01 8.581328e-04 3.466403e-03 -6.000000e+00 1.935423e-02 226.12 -2.00 3.11 -2.00 320.07 0.00e+00 4.890049e-04 2.653343e-04 2.599157e-04 -6.000000e+00 8.715773e-04 286.17 -2.00 20.00 -2.00 319.27 0.00e+00 3.055 0.000 302.00 328.00 3 1.0103e+00 2.5499e-03 3.2900e-02 -6.0000e+00 4.7862e-02 9.2481e-03 3.0381e-03 1.5407e-02 -6.0000e+00 5.2013e-02 -1.5683e-02 2.3116e-03 7.5415e-03 -6.0000e+00 3.1100e-02 -2.0349e-03 1.1905e-03 2.1950e-03 -6.0000e+00 1.3331e-02 7.1026e-03 -1.0637e-03 5.2202e-05 2.5141e-05 -6.0000e+00 8.9290e-04 -7.9435e-04 0.0000e+00 10 0 0 10 0 0 88.20 22.40 0.21 -0.00079 -0.00879 563 112 1 5 0 88.890 27.99 19.98 22.40 -15032 -8522 -9169 -10598 -12695 -12650 -11651 -5484 -11575 -1225 -11072 -1721 -7832 -40 -3875 -3116 -2715 -3779 957 -2672 -1723 -4806 509 -4638 -926 -1421 1494 -3200 -1552 -4578 -8696 371 1515 383 -2752 -4052 -1987 -2989 -711 558 -1550 613 -1341 -91 -313 221 -418 -1174 -867 -689 792 735 2522 633 1322 591 1917 710 962 310 1183 1429 2297 2226 1604 534 277 -75 583 1091 -62 691 -21 185 499 -262 271 -495 360 200 -429 -695 -1136 -1599 -904 -888 -333 -465 10 407 257 -87 8 293 686 517 233 454 219 -206 -322 -532 -548 279 -428 -1256 -699 -629 -340 1 6 -166 115 174 184 180 302 184 129 -167 -667 -381 59 184 727 899 345 1425 545 526 387 215 185 -34 -322 -366 -278 283 -40 -92 8 -246 -316 -387 -238 -275 -317 -348 -317 -297 -147 -378 -41 -416 -59 -318 -2 -209 -192 -180 -265 68 -204 -135 -388 39 -398 -82 -134 146 -316 -141 -414 -865 37 167 46 -329 -462 -234 -410 -121 107 -361 149 -345 -24 -81 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