File name: Pandora179s1_CornwallCT_20231027_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240124T080906.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20231027_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20231027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231027T133517.3Z 8700.566173 293 1 48.42 2 68.78 131.80 126.08 323.11 0.00 1 0.00 1 0 17 1.206e-02 5.502e-03 1.267e-03 3.230e-04 3.033855e-01 1.609934e-04 3.658182e-03 -6.000000e+00 6.818659e-03 224.49 -2.00 3.52 -2.00 317.69 0.00e+00 4.214793e-04 2.589680e-05 7.942476e-05 -6.000000e+00 3.007864e-04 279.27 -2.00 20.00 -2.00 317.01 0.00e+00 2.738 0.000 302.00 328.00 3 9.2753e-01 4.2560e-04 2.9921e-02 -6.0000e+00 1.6832e-02 1.6184e-02 4.8177e-04 1.5491e-02 -6.0000e+00 1.8340e-02 -5.5350e-03 3.0038e-04 7.6727e-03 -6.0000e+00 1.0934e-02 -2.3887e-03 1.5201e-04 2.2111e-03 -6.0000e+00 4.6301e-03 1.1256e-02 -3.8831e-04 9.3257e-06 2.4663e-05 -6.0000e+00 3.2854e-04 3.4664e-03 0.0000e+00 10 0 0 10 0 0 99.92 22.92 0.32 0.00347 0.00055 1022 244 1 5 0 47.370 26.11 20.00 22.92 23.53 27.6 975.97 -766 -2138 -1302 -4271 -4967 -5427 -3272 -2889 -569 -1492 -3601 -2946 -2173 -1281 -287 215 -671 637 263 1049 989 122 1217 863 546 614 253 -687 -614 -124 1173 1064 2031 342 -2467 -1764 -2177 -1259 -422 -250 -943 -787 -537 -651 -288 -87 -540 -438 -511 -343 841 676 906 1062 617 812 928 467 278 525 779 1277 1445 1525 439 -248 68 -383 803 859 327 341 38 278 16 -192 -136 -617 -101 -501 -1045 -1106 -2019 -1666 -985 -753 -402 -114 292 234 349 495 242 675 763 324 629 746 30 -319 -234 -706 -345 121 -585 -1018 -723 -674 -364 286 121 102 75 134 73 396 478 241 266 -203 -487 2 118 236 568 617 483 1216 548 273 172 -164 -94 76 -110 -179 -66 191 -313 -214 -46 -393 -282 -60 -191 -121 -398 -418 -428 -262 -257 -56 -159 -396 -327 -267 -181 -47 39 -120 118 51 211 205 25 254 191 129 152 64 -167 -139 -27 270 269 556 101 -713 -486 -644 -427 -171 -110 -464 -409 -288 -356 -157 -48 -293 -233 -269 -181 463 402 529 657 399 537 626 317 186 345 524 915 1131 1194 353 -188 51 -284 622 699 295 324 37 255 14 -161 -103 -446 -76 -425 -938 -1104 -2043 -1765 -1107 -850 -478 -139 358 277 384 531 239 692 771 365 741 977 40 -421 -307 -855 -392 140 -740 -1291 -958 -938 -533 421 190 163 116 194 103 526 631 333 393 -303 -744 3 172 350 797 825 656 1654 760 409 258 -254 -150 126 -183 -313 -118 332 -549 -385 -80 -654 -460 SS 20231027T134448.7Z 8700.572786 296 1 49.40 2 67.48 133.87 127.03 325.67 0.00 1 0.00 1 0 17 1.093e-02 5.717e-03 6.211e-04 1.972e-04 2.876916e-01 9.809789e-05 3.484410e-03 -6.000000e+00 6.181107e-03 224.49 -2.00 3.52 -2.00 317.28 0.00e+00 3.945114e-04 1.405237e-05 6.492781e-05 -6.000000e+00 2.726644e-04 279.26 -2.00 20.00 -2.00 316.60 0.00e+00 2.590 0.000 302.00 328.00 3 1.7554e-01 2.5717e-04 2.8315e-02 -6.0000e+00 1.5258e-02 1.1649e-02 2.8993e-04 1.4666e-02 -6.0000e+00 1.6625e-02 -7.4622e-03 1.7515e-04 7.2507e-03 -6.0000e+00 9.9115e-03 -5.8204e-04 8.6734e-05 2.0756e-03 -6.0000e+00 4.1971e-03 2.8034e-02 -4.1377e-04 5.6816e-06 2.4199e-05 -6.0000e+00 2.9783e-04 3.6320e-03 0.0000e+00 10 0 0 10 0 0 98.94 22.93 0.30 0.00363 0.00052 1821 436 1 5 0 26.580 26.11 20.00 22.93 24.56 28.0 984.18 -1164 -1245 -1323 -2895 -5266 -3938 -3240 -1282 -780 -1023 -3543 -2856 -1634 -1136 332 163 -237 300 572 810 934 40 1003 849 495 730 257 -515 -814 76 1090 1071 1952 386 -2424 -1977 -1918 -1482 -288 -347 -741 -760 -431 -649 -248 -36 -479 -277 -541 -163 818 791 884 1180 660 890 931 500 462 465 825 1229 1519 1512 450 -345 45 -496 721 837 123 234 -101 265 -91 -207 -145 -592 -62 -500 -1021 -1148 -1978 -1752 -927 -835 -420 -223 226 209 349 493 246 794 746 369 606 726 -1 -285 -207 -740 -335 135 -583 -1053 -662 -683 -298 237 139 49 55 116 90 444 492 292 250 -156 -453 42 116 261 672 668 482 1222 614 281 206 -166 -62 68 -80 -181 -116 183 -355 -234 -113 -402 -325 -119 -144 -160 -345 -574 -394 -333 -144 -98 -139 -497 -402 -252 -202 61 34 -52 69 137 201 238 10 258 231 143 220 79 -152 -225 20 303 324 640 135 -834 -649 -673 -548 -127 -166 -398 -431 -252 -386 -147 -21 -281 -159 -307 -92 482 503 555 781 457 629 672 362 329 327 593 942 1182 1267 386 -280 36 -388 588 719 110 220 -96 242 -83 -170 -115 -448 -48 -413 -959 -1124 -2099 -1835 -1029 -994 -497 -273 276 247 405 522 255 792 785 406 702 935 -2 -371 -267 -882 -396 163 -726 -1398 -870 -941 -431 347 216 74 85 166 124 609 671 395 362 -229 -683 62 168 380 925 926 637 1618 831 410 303 -253 -96 110 -130 -312 -196 314 -616 -395 -192 -659 -522 SS 20231027T135123.8Z 8700.577359 300 1 3.16 2 66.61 135.34 127.65 327.48 0.00 1 0.00 1 0 17 1.838e-02 7.496e-03 1.251e-02 4.262e-03 2.737957e-01 2.126911e-03 3.288710e-03 -6.000000e+00 1.040149e-02 224.49 -2.00 3.52 -2.00 317.08 0.00e+00 4.061038e-04 2.921984e-04 6.318389e-05 -6.000000e+00 4.587801e-04 279.26 -2.00 20.00 -2.00 316.42 0.00e+00 2.500 0.000 302.00 328.00 3 3.4109e+00 5.5564e-03 2.7191e-02 -6.0000e+00 2.5676e-02 6.0725e-03 6.2621e-03 1.3884e-02 -6.0000e+00 2.7972e-02 -1.1600e-03 3.7399e-03 6.8530e-03 -6.0000e+00 1.6676e-02 -1.6367e-03 1.8313e-03 1.9691e-03 -6.0000e+00 7.0660e-03 1.2238e-03 4.4096e-05 1.2264e-04 2.2730e-05 -6.0000e+00 5.0098e-04 -1.3159e-04 0.0000e+00 12 9 1 12 1 1 -490.29 22.92 0.35 -0.00013 0.00020 3 15 1 5 0 788.240 26.11 20.00 22.92 25.42 27.9 986.68 1526 -1999 -2263 -4549 -6087 -1212 -10836 1131 -1811 1752 -8617 -896 -2865 -2524 467 1436 -1615 909 3128 627 1955 -2458 3586 25 -952 1925 -709 254 -4878 763 2131 1630 1945 2516 -3074 -686 -2468 -1887 -528 977 -479 -513 -634 -639 -103 -514 -868 -809 -133 978 953 2326 -45 1945 -631 3154 -93 604 669 711 831 534 2272 1076 346 -1746 26 -1348 295 442 -193 809 -178 731 148 528 -1330 524 315 -555 -1174 -1445 -1613 -1759 -1297 -929 -504 -568 1053 25 875 57 228 262 826 658 63 516 -340 459 -584 -729 -990 -230 -460 -725 -432 -686 73 37 267 -148 519 -62 -206 269 750 490 602 72 -130 53 235 576 -208 895 203 1077 526 312 240 -27 201 -703 -85 -258 400 -249 -288 370 -114 -400 -773 160 -245 -291 -577 -701 -136 -1383 142 -240 241 -1322 -128 -462 -468 97 330 -407 232 816 174 550 -720 1000 8 -284 584 -223 82 -1552 223 644 538 638 864 -1063 -222 -868 -763 -253 502 -278 -292 -373 -382 -61 -307 -514 -468 -81 588 559 1446 -31 1364 -471 2320 -67 435 506 532 594 410 1867 900 295 -1517 20 -1046 237 375 -183 795 -177 698 132 454 -1051 412 240 -479 -1081 -1480 -1673 -1918 -1421 -1089 -622 -688 1261 30 994 63 231 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