File name: Pandora179s1_CornwallCT_20231104_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240124T081640.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20231104_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20231104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231104T123720.3Z 8708.525929 285 1 17.32 2 79.41 121.98 32.92 248.52 0.00 1 0.00 1 0 17 4.539e-01 1.226e-02 2.489e-01 6.600e-03 6.575131e-01 3.451350e-03 7.446220e-03 -6.000000e+00 2.560191e-01 223.78 -2.00 3.52 -2.00 320.84 0.00e+00 4.945975e-03 1.484551e-03 1.212723e-03 -6.000000e+00 1.136094e-02 278.24 -2.00 20.00 -2.00 320.31 0.00e+00 5.233 0.003 302.00 328.00 3 2.7853e+00 1.0819e-02 6.0478e-02 -6.0000e+00 6.3120e-01 1.5611e-01 1.4513e-02 3.7210e-02 -6.0000e+00 6.8848e-01 -1.6098e-01 1.4850e-02 1.8127e-02 -6.0000e+00 4.1089e-01 5.7161e-02 7.2534e-03 8.5423e-03 -6.0000e+00 1.7493e-01 1.1618e-04 -1.1049e-03 1.8062e-04 7.3999e-05 -6.0000e+00 1.2413e-02 7.4435e-03 0.0000e+00 12 9 9 12 1 1 99.13 22.61 0.58 0.00744 -0.00086 10 7 1 5 0 1573.960 25.79 20.00 22.61 11.37 26.6 914.20 -213031 900000 -158302 -138641 -138165 -163704 -37646 -182795 31793 -28769 -143144 -129995 -69721 -83094 900000 -30769 5199 -11568 -24109 122917 -34769 148258 18577 -16827 33278 17862 -15180 -2614 -27427 -39791 28434 -37997 18636 60170 35784 5381 -20481 -3026 2213 17013 -115 -1780 -7702 1987 -1478 12896 -7964 17137 2950 -2422 7835 24852 -3028 5553 6272 6443 7619 -1958 3267 -2226 6154 5497 5514 6911 4865 586 1834 2409 -3120 919 1460 2003 -899 -1153 -840 -3099 1751 -3873 159 -4321 -4224 -549 -1696 -3854 -1795 2146 -1095 749 1249 758 1296 -342 -1059 1133 483 -22 84 655 776 -965 -452 38 -111 -436 -1123 -941 445 -1334 -1204 299 505 99 -375 406 -566 638 113 247 194 -394 -130 7 41 536 -9 1597 79 922 671 88 565 -155 -400 54 -873 679 35 326 24 -165 -101 -462 -395 -4226 900000 -2461 -1784 -1630 -2370 -242 -3724 205 -185 -2533 -2230 -822 -1470 900000 -511 76 -223 -530 791 -932 954 326 -453 584 387 -471 -70 -930 -1629 698 -2200 719 1689 1256 249 -1318 -191 162 1294 -11 -185 -900 218 -171 1328 -1038 1965 375 -347 1122 3371 -598 1096 1308 1396 1679 -474 730 -516 1346 1326 1517 2127 1633 203 615 825 -1235 401 704 1008 -463 -562 -373 -1263 631 -1487 65 -2203 -2335 -335 -1154 -2846 -1384 1696 -939 650 1078 635 1006 -252 -754 811 389 -21 85 754 976 -1239 -542 40 -109 -427 -1188 -1052 518 -1695 -1563 429 801 156 -599 662 -881 939 167 384 319 -676 -220 12 64 806 -13 2199 115 1298 1069 149 1044 -307 -787 112 -1954 1571 78 740 53 -380 -218 -941 -831 SS 20231104T124226.8Z 8708.529477 288 1 9.47 2 78.60 122.93 33.80 249.84 0.00 1 0.00 1 0 17 4.411e-01 1.329e-02 3.108e-01 8.969e-03 6.293103e-01 4.653548e-03 7.166055e-03 -6.000000e+00 2.490600e-01 223.78 -2.00 3.52 -2.00 320.61 0.00e+00 -8.689456e-04 1.883049e-03 4.540191e-04 -6.000000e+00 1.133662e-02 278.24 -2.00 20.00 -2.00 320.07 0.00e+00 4.894 0.002 302.00 328.00 3 3.1032e+00 1.4285e-02 5.6209e-02 -6.0000e+00 6.1530e-01 7.5067e-02 1.8849e-02 3.2977e-02 -6.0000e+00 6.7134e-01 -6.7598e-02 1.9098e-02 1.7001e-02 -6.0000e+00 3.9931e-01 2.0872e-02 9.4573e-03 5.1111e-03 -6.0000e+00 1.7009e-01 1.2103e-04 -8.0427e-04 2.4817e-04 5.9980e-05 -6.0000e+00 1.2032e-02 5.0497e-03 0.0000e+00 12 9 9 12 1 1 -45.88 22.61 0.42 0.00505 -0.00099 4 6 1 5 0 1892.300 25.79 19.99 22.61 11.56 26.6 915.34 -65343 900000 -118070 -142027 -55995 -103685 -178864 -12401 -73403 900000 -158479 -133575 -113499 -116316 181560 -15255 67394 -12462 -12570 -577 69649 64821 49129 -28587 65281 49648 -33545 26336 -46628 69855 -23942 32864 14853 167659 4942 53702 -18390 -7064 19664 15662 9115 -110 25741 -7943 4668 5325 -1625 4232 2735 -7141 -4976 16600 -1279 11378 711 10090 -184 -1221 2085 -1072 6515 334 7601 -1317 5299 -4887 3322 632 -4170 -283 1256 1902 -479 217 -2686 2908 1667 2822 -1317 -827 -2620 -670 -2627 -2278 583 -195 669 -947 1648 -1689 970 -938 -2324 1052 -1394 519 -293 1950 350 -80 -274 -15 -653 -1704 -755 -1036 1014 -1864 -492 443 1611 -89 -237 215 178 407 -176 869 -506 250 -1101 -476 268 569 1080 1770 -727 734 960 -1049 959 -207 50 -442 -306 243 -318 150 64 -537 200 306 -404 -571 900000 -1327 -2040 -490 -907 -3574 -108 -688 900000 -4157 -3003 -2552 -3414 1587 -248 589 -249 -275 -12 796 785 727 -946 1010 968 -1445 655 -2155 1128 -1062 1061 669 1804 266 1734 -1229 -498 1314 1330 951 -14 2604 -1156 603 695 -231 584 400 -1226 -926 2799 -284 2437 182 2464 -52 -349 560 -290 1664 99 2364 -471 1887 -1894 1245 233 -1762 -132 644 1020 -262 112 -1307 1200 690 1155 -578 -426 -1608 -462 -1906 -1752 465 -167 599 -887 1503 -1536 801 -737 -1772 793 -1195 503 -311 2310 433 -99 -339 -16 -671 -1771 -835 -1216 1229 -2348 -668 664 2500 -148 -396 344 269 619 -270 1304 -815 415 -1839 -761 411 884 1601 2507 -1021 1059 1469 -1840 1712 -397 101 -899 -665 525 -707 338 143 -1158 421 608 -825 SS 20231104T124731.9Z 8708.533008 291 1 48.16 2 77.81 123.88 34.68 251.10 0.00 1 0.00 1 0 17 3.798e-01 1.678e-02 1.486e-01 5.763e-03 5.875782e-01 3.010983e-03 6.745515e-03 -6.000000e+00 2.145810e-01 223.78 -2.00 3.52 -2.00 320.58 0.00e+00 5.156412e-03 1.175659e-03 8.248124e-04 -6.000000e+00 9.948193e-03 278.24 -2.00 20.00 -2.00 320.02 0.00e+00 4.600 0.002 302.00 328.00 3 4.0498e+00 9.1126e-03 5.3172e-02 -6.0000e+00 5.2982e-01 1.7012e-01 1.1731e-02 3.2482e-02 -6.0000e+00 5.7834e-01 -1.6247e-01 1.1223e-02 1.6035e-02 -6.0000e+00 3.4407e-01 6.1327e-02 5.5982e-03 7.5564e-03 -6.0000e+00 1.4671e-01 6.0836e-05 -1.4004e-03 1.6367e-04 6.7401e-05 -6.0000e+00 1.0533e-02 8.9861e-03 0.0000e+00 12 9 8 11 8 0 99.95 22.61 0.53 0.00899 -0.00154 21 5 1 5 0 2293.120 25.79 20.00 22.61 11.72 26.6 916.10 -104523 900000 -155909 -7667 900000 -134655 -88865 -162214 -24749 900000 -142496 -83376 -120018 -58435 900000 28076 100279 10026 5043 44903 -19348 63610 81948 -47423 54937 70504 -24122 -8427 -9963 -10254 37134 -28857 26351 119838 23834 29830 -21826 10077 10273 20212 1286 4775 8117 7936 -3393 5941 -4489 12691 9656 3960 15783 26710 1764 6546 988 13379 1601 -3725 4601 -2749 1856 1063 7647 5390 4700 -4382 3785 823 -5109 675 432 3218 1650 -2061 -1911 250 1814 -3334 -518 -2340 -7851 -954 -1805 -4295 -1997 2422 -289 324 1615 -1252 1166 -2550 -1827 2529 222 574 -1301 1284 633 -339 -522 -731 574 -1356 -1004 352 1708 -1008 -1283 203 1475 -531 -637 725 251 358 -140 879 209 -926 20 -798 970 706 -836 2602 -841 863 823 29 270 80 201 -299 -1304 763 230 373 14 -121 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