File name: Pandora179s1_CornwallCT_20240209_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240210T051048.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240209_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240209T145715.9Z 8805.623100 138 1 48.75 2 63.99 144.64 68.82 150.37 0.00 1 0.00 1 0 17 5.212e-02 8.922e-03 1.304e-02 2.511e-03 3.562016e-01 1.250249e-03 4.243986e-03 -6.000000e+00 2.944167e-02 224.40 -2.00 3.52 -2.00 317.98 0.00e+00 8.512214e-04 2.143085e-04 2.111890e-04 -6.000000e+00 1.259076e-03 271.46 -2.00 20.00 -2.00 317.46 0.00e+00 2.267 0.000 302.00 328.00 3 5.2971e+00 3.3116e-03 2.7915e-02 -6.0000e+00 7.2850e-02 7.0354e-02 3.7509e-03 1.8048e-02 -6.0000e+00 7.9503e-02 -1.5683e-02 2.4593e-03 8.9882e-03 -6.0000e+00 4.7186e-02 -2.1657e-03 1.2763e-03 2.6898e-03 -6.0000e+00 1.9835e-02 1.9336e-04 -4.1362e-04 7.1749e-05 2.9336e-05 -6.0000e+00 1.4198e-03 7.2147e-03 0.0000e+00 11 9 0 11 32 0 99.96 22.63 0.37 0.00721 0.00411 14 3 1 5 0 3481.250 25.79 19.99 22.63 6.88 28.2 959.34 4853 28886 -10172 6520 -8206 4660 -14170 -24593 4730 8852 -23607 -3713 -22939 -4782 6197 -659 7415 545 -1258 5711 1153 -1569 11185 -3528 6316 2218 -1219 -1159 -3605 56 256 -3844 1489 8422 -4747 1517 -5445 -1808 1229 2319 -1183 -380 -3 45 -2545 -465 -395 -374 -1497 -865 1695 4052 362 1913 204 8 839 143 1118 46 992 908 1824 1500 1088 -2209 -2032 -1417 109 448 337 755 656 -134 -1296 26 321 111 -998 51 -2151 -1201 -1391 -2205 -313 39 89 -180 872 39 1123 476 276 1653 523 883 112 986 182 -190 -324 -739 -162 -290 -928 -448 46 -1638 -738 179 660 -207 -17 -24 13 447 -180 622 -239 101 -585 100 203 535 -72 1415 69 1050 448 -166 -64 -131 298 -14 -397 125 14 228 -152 -16 18 -167 -696 249 1431 -731 386 -505 255 -972 -1940 338 654 -2271 -325 -2560 -526 719 -93 1044 87 -215 947 205 -286 1824 -707 1221 468 -270 -245 -734 11 53 -927 376 2100 -1291 373 -1537 -570 423 935 -551 -174 -1 22 -1257 -226 -190 -178 -716 -417 845 2140 212 1172 132 5 533 91 734 30 658 609 1332 1190 883 -1747 -1502 -1021 82 360 299 698 606 -120 -1086 20 228 81 -725 41 -1926 -1186 -1404 -2358 -350 45 106 -222 1065 46 1285 502 284 1645 532 997 135 1259 250 -259 -414 -910 -186 -339 -1181 -571 61 -2326 -1052 272 1019 -329 -26 -37 18 612 -247 884 -350 155 -917 152 301 756 -102 1882 93 1428 631 -243 -100 -211 468 -23 -666 218 25 416 -278 -28 31 -282 -1161 SS 20240209T150547.8Z 8805.629025 144 1 3.13 2 63.09 146.71 68.05 152.28 0.00 1 0.00 1 0 17 2.531e-02 8.334e-03 2.563e-02 5.850e-03 3.398378e-01 2.906322e-03 4.123684e-03 -6.000000e+00 1.427929e-02 224.40 -2.00 3.52 -2.00 317.76 0.00e+00 1.269424e-03 4.647478e-04 1.018186e-04 -6.000000e+00 6.111677e-04 271.46 -2.00 20.00 -2.00 317.23 0.00e+00 2.198 0.000 302.00 328.00 3 4.0705e+00 7.6794e-03 2.6945e-02 -6.0000e+00 3.5331e-02 6.1403e-02 8.6714e-03 1.7298e-02 -6.0000e+00 3.8577e-02 -2.5487e-02 5.5140e-03 8.6468e-03 -6.0000e+00 2.2896e-02 5.2963e-03 2.8294e-03 2.5726e-03 -6.0000e+00 9.6078e-03 7.2449e-04 -2.0202e-03 1.6693e-04 2.8995e-05 -6.0000e+00 6.8970e-04 1.8248e-02 0.0000e+00 12 9 1 12 1 1 99.97 22.63 0.44 0.01825 0.00307 3 15 1 5 0 779.850 25.79 20.00 22.63 6.84 28.1 958.76 -4514 -2157 2072 1254 -8524 2653 6004 -9854 2700 -5904 -11076 -6095 -6284 2302 7056 3838 245 2547 -4927 5265 -7729 1710 4235 2971 1828 2676 671 -2694 1352 -981 1278 -3966 674 707 -4781 -1250 -2178 17 -5 975 341 -1691 -790 -766 -2421 -950 -2067 393 -1041 -695 2585 2784 1531 1048 1209 126 -819 225 -964 3278 768 1592 533 1743 109 -1013 504 -95 -62 -64 -19 926 1888 618 -164 1268 -613 -1840 -530 -742 -1038 -236 -1988 -1699 -721 -121 -1175 636 129 1322 378 -608 294 -88 784 393 740 1329 389 -912 -307 -1449 -638 -118 -1589 -794 -514 -563 -596 -166 -79 5 -151 139 527 332 805 693 743 -264 104 -24 -144 388 1131 846 201 810 256 889 72 201 -164 -83 -742 -224 -604 376 -546 -102 543 -435 -263 -319 -169 165 97 -655 170 385 -822 223 -570 -1137 -610 -711 282 966 616 44 468 -954 1031 -1641 354 864 648 397 602 156 -619 301 -221 301 -1012 181 200 -1366 -331 -622 5 -2 414 162 -868 -416 -410 -1318 -512 -1116 204 -544 -366 1394 1621 903 659 789 85 -569 154 -655 2105 518 1143 400 1394 90 -797 365 -72 -47 -55 -16 853 1722 549 -144 988 -468 -1360 -406 -607 -913 -229 -2003 -1791 -803 -136 -1408 773 158 1539 434 -644 300 -88 828 439 878 1747 524 -1232 -405 -1771 -763 -143 -2011 -1054 -679 -782 -837 -249 -120 8 -239 206 749 446 1071 963 1103 -400 160 -36 -210 566 1557 1169 267 1083 354 1321 109 315 -263 -133 -1269 -384 -1062 667 -979 -177 932 -722 -427 SS 20240209T150934.8Z 8805.631653 147 1 48.57 2 62.71 147.65 67.73 153.14 0.00 1 0.00 1 0 17 1.389e-02 5.611e-03 9.137e-04 2.404e-04 3.360678e-01 1.195615e-04 4.041372e-03 -6.000000e+00 7.843742e-03 224.40 -2.00 3.52 -2.00 317.55 0.00e+00 5.387664e-04 1.798271e-05 8.330065e-05 -6.000000e+00 3.354445e-04 271.46 -2.00 20.00 -2.00 317.01 0.00e+00 2.170 0.000 302.00 328.00 3 8.6735e-01 3.1436e-04 2.6543e-02 -6.0000e+00 1.9409e-02 3.7832e-02 3.5454e-04 1.6962e-02 -6.0000e+00 2.1181e-02 -1.7897e-02 2.2093e-04 8.4709e-03 -6.0000e+00 1.2571e-02 1.6421e-03 1.1185e-04 2.4618e-03 -6.0000e+00 5.2842e-03 1.8648e-02 -3.0272e-04 6.8433e-06 2.7599e-05 -6.0000e+00 3.7828e-04 7.5515e-03 0.0000e+00 10 0 0 10 0 0 99.99 22.62 0.31 0.00755 0.00528 1260 301 1 5 0 38.420 25.79 20.00 22.62 6.90 28.4 960.84 -1787 -2881 -1770 -4660 -6539 -5535 -4515 -2841 -2007 -1823 -4924 -3530 -2740 -1432 -287 51 -407 333 541 1105 1062 -12 1268 805 427 420 -145 -897 -1013 17 995 1249 2015 365 -2416 -1867 -2167 -1288 -317 -285 -690 -723 -380 -619 -36 11 -364 -329 -502 -48 966 854 1002 1318 678 1022 912 506 385 510 868 1204 1536 1457 424 -312 -1 -616 692 714 183 269 -59 282 -69 -211 -266 -725 -194 -616 -1050 -1197 -2079 -1759 -968 -833 -361 -174 244 212 373 447 243 655 717 261 592 706 14 -173 -205 -717 -342 142 -654 -958 -667 -662 -263 270 100 42 61 117 123 452 497 307 291 -98 -370 147 168 255 626 559 465 1171 491 231 169 -249 -96 25 -114 -202 -24 200 -315 -203 -84 -388 -321 -142 -263 -168 -442 -566 -444 -373 -258 -203 -198 -559 -405 -351 -213 -45 9 -77 66 112 237 234 -3 282 190 108 111 -39 -232 -246 4 249 344 606 118 -765 -566 -706 -442 -130 -138 -345 -382 -207 -344 -20 6 -200 -178 -270 -26 548 524 609 847 456 703 641 356 265 347 603 893 1162 1192 356 -248 0 -481 528 617 164 252 -55 254 -62 -170 -208 -545 -153 -514 -936 -1189 -2109 -1868 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