File name: Pandora179s1_CornwallCT_20240306_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240307T051019.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240306_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240306T130644.0Z 8831.546342 148 1 21.38 2 71.60 115.42 69.68 172.57 0.00 1 0.00 1 0 17 8.010e-02 8.206e-03 3.096e-02 3.299e-03 4.179837e-01 1.649162e-03 4.920869e-03 -6.000000e+00 4.543371e-02 225.48 -2.00 3.52 -2.00 318.77 0.00e+00 1.124868e-03 3.571394e-04 1.610820e-04 -6.000000e+00 1.946470e-03 272.90 -2.00 20.00 -2.00 318.23 0.00e+00 3.129 0.001 302.00 328.00 3 4.0604e+00 4.4635e-03 3.6290e-02 -6.0000e+00 1.1264e-01 6.9168e-02 5.1157e-03 2.1403e-02 -6.0000e+00 1.2281e-01 -2.6231e-02 3.7259e-03 1.0664e-02 -6.0000e+00 7.2888e-02 2.4575e-03 1.9732e-03 3.2340e-03 -6.0000e+00 3.0604e-02 2.8349e-04 -5.3004e-04 9.3884e-05 3.4390e-05 -6.0000e+00 2.1829e-03 8.1451e-03 0.0000e+00 12 9 1 12 1 1 99.36 22.64 0.23 0.00815 0.00416 10 6 1 5 0 1942.790 25.79 20.01 22.64 11.62 29.2 991.75 27249 32067 -34123 -229 -29697 8403 -19581 -18692 -17543 17938 -40941 -7090 -20881 -10184 15912 -9500 18345 -4290 4786 2577 4270 -1627 8481 -5220 -611 3316 -167 2587 -7152 2174 -659 -1884 -2262 9038 -217 3700 -7730 -1989 3846 -76 -134 -1736 578 -2146 242 -1125 -881 615 86 -599 396 5305 -679 1526 -713 2812 952 -1203 909 557 804 582 2929 1228 1034 -1642 120 -1426 762 575 421 1241 140 141 -627 417 -953 0 -748 -268 -2428 -1237 -1169 -2570 -159 -499 241 -208 174 -236 1099 120 502 520 843 753 153 1340 -313 -197 -507 -399 -609 50 -510 -685 -21 -874 -691 -157 123 -240 318 66 2 958 176 673 -18 110 -639 176 117 837 -255 917 68 1066 560 285 52 -131 -129 -327 -323 -414 178 361 -341 68 -155 30 -381 587 762 -1681 -8 -1242 227 -732 -777 -816 635 -2675 -346 -1354 -716 1032 -919 1471 -461 500 288 484 -195 940 -709 -85 467 -25 360 -1039 289 -99 -324 -405 1545 -39 668 -1563 -442 978 -24 -44 -620 210 -819 90 -430 -336 231 32 -235 165 2300 -336 791 -371 1457 515 -664 480 291 429 336 1829 853 697 -1149 78 -935 523 424 342 1050 119 115 -478 300 -634 0 -513 -197 -2092 -1115 -1140 -2536 -163 -551 278 -236 197 -273 1161 124 483 495 862 821 180 1748 -424 -264 -671 -480 -721 60 -629 -896 -27 -1209 -1019 -238 191 -386 497 102 2 1353 250 994 -27 176 -1033 276 178 1270 -372 1266 95 1441 830 441 87 -217 -221 -561 -590 -762 334 687 -653 126 -284 53 -683 SS 20240306T134032.0Z 8831.569815 161 1 48.48 2 66.08 122.24 69.24 180.35 0.00 1 0.00 1 0 17 1.614e-02 5.712e-03 3.242e-03 8.453e-04 3.286569e-01 4.212381e-04 3.934885e-03 -6.000000e+00 9.153938e-03 225.48 -2.00 3.52 -2.00 317.62 0.00e+00 5.472384e-04 6.494744e-05 8.237649e-05 -6.000000e+00 3.921804e-04 272.90 -2.00 20.00 -2.00 317.06 0.00e+00 2.449 0.000 302.00 328.00 3 3.1171e+00 1.1100e-03 2.8410e-02 -6.0000e+00 2.2695e-02 4.4027e-02 1.2532e-03 1.6700e-02 -6.0000e+00 2.4744e-02 -1.9686e-02 7.8163e-04 8.2933e-03 -6.0000e+00 1.4686e-02 2.3750e-03 3.9461e-04 2.3996e-03 -6.0000e+00 6.1657e-03 1.5481e-03 -3.2004e-04 2.4107e-05 2.6066e-05 -6.0000e+00 4.3984e-04 8.5222e-03 0.0000e+00 10 0 0 10 0 0 99.60 22.64 0.31 0.00852 0.00612 96 23 1 5 0 504.560 25.79 20.00 22.64 13.42 29.4 1002.27 -3916 1286 -4976 -4615 -8289 -5438 -2827 -5341 877 -2064 -5691 -4823 -1884 -2577 1316 -82 -58 -143 -208 2722 658 1545 1363 1181 298 1036 -514 -1124 -1134 -597 1739 139 2243 822 -1765 -2228 -2240 -1384 -219 -104 -1043 -361 -710 -252 -410 99 -844 -347 -770 -412 993 838 1090 1108 948 1000 1068 204 740 421 880 1079 1539 1489 404 -218 -168 -177 614 1046 189 74 -2 100 39 -322 144 -789 126 -657 -1123 -1178 -1995 -1969 -962 -765 -379 -171 164 177 435 473 204 668 664 407 669 627 49 -334 -118 -629 -208 121 -508 -870 -410 -775 -329 238 90 -24 -95 146 75 600 480 393 279 -101 -353 50 207 128 614 636 494 1096 413 168 59 -219 -55 50 -176 -46 -102 196 -398 -153 -170 -363 -186 -317 112 -485 -433 -724 -432 -228 -493 86 -223 -644 -554 -236 -381 218 -14 -11 -28 -42 562 143 330 296 272 74 266 -136 -285 -269 -139 421 38 655 256 -539 -658 -710 -505 -87 -49 -508 -185 -377 -135 -220 53 -452 -182 -402 -216 545 498 690 743 615 665 725 140 492 278 592 778 1210 1179 328 -179 -129 -133 485 870 175 72 -2 93 34 -270 109 -575 96 -569 -1034 -1131 -2077 -2153 -1047 -890 -463 -203 194 215 487 515 206 654 692 445 817 806 68 -455 -151 -782 -242 145 -622 -1131 -556 -1050 -470 345 139 -37 -145 219 104 822 657 533 406 -148 -528 77 310 183 878 867 645 1441 590 246 92 -335 -85 81 -291 -80 -181 338 -690 -270 -287 -588 -310 SS 20240306T134546.4Z 8831.573453 164 1 48.31 2 65.26 123.35 69.25 181.56 0.00 1 0.00 1 0 17 1.292e-02 5.668e-03 2.445e-03 6.904e-04 3.190238e-01 3.448244e-04 3.829541e-03 -6.000000e+00 7.329338e-03 225.48 -2.00 3.52 -2.00 317.45 0.00e+00 4.201597e-04 5.056372e-05 7.719428e-05 -6.000000e+00 3.140101e-04 272.90 -2.00 20.00 -2.00 316.89 0.00e+00 2.374 0.000 302.00 328.00 3 2.7979e+00 9.0763e-04 2.7554e-02 -6.0000e+00 1.8171e-02 4.1944e-02 1.0222e-03 1.6201e-02 -6.0000e+00 1.9812e-02 -1.8027e-02 6.2917e-04 8.0417e-03 -6.0000e+00 1.1759e-02 1.6405e-03 3.1498e-04 2.3116e-03 -6.0000e+00 4.9367e-03 2.3165e-03 -3.7071e-04 1.9760e-05 2.5835e-05 -6.0000e+00 3.5217e-04 8.5609e-03 0.0000e+00 10 0 0 10 0 0 99.55 22.63 0.31 0.00856 0.00578 142 34 1 5 0 340.140 25.79 20.00 22.63 13.68 29.4 1003.82 -1764 -514 -3315 -3345 -6467 -2706 -5024 -2177 -1497 -273 -5048 -3981 -2155 -1505 779 -460 -8 -652 615 906 1011 -275 1732 365 414 809 -358 -503 -716 731 1260 1068 1709 812 -2491 -1587 -2338 -1320 -14 -220 -798 -748 -472 -694 -211 -176 -437 -233 -635 -159 838 1013 782 1375 462 1154 709 433 543 600 985 1346 1512 1389 277 -482 46 -531 778 765 235 369 -21 238 -163 -191 -164 -527 -226 -504 -1046 -1282 -1929 -1870 -958 -844 -366 -199 265 110 338 452 185 690 618 361 592 623 11 -184 -128 -669 -229 230 -619 -973 -524 -759 -313 165 12 -117 -16 65 113 447 567 349 352 -5 -308 193 127 328 496 637 576 1208 459 174 177 -266 -81 97 -164 -207 17 109 -320 -158 -117 -374 -361 -155 -51 -352 -343 -612 -231 -456 -214 -165 -32 -625 -497 -296 -240 128 -87 -2 -138 134 205 235 -64 403 91 110 224 -101 -136 -181 179 326 305 531 268 -809 -492 -783 -465 -6 -109 -408 -404 -263 -394 -119 -99 -245 -128 -346 -87 480 625 516 887 313 795 501 306 376 410 687 1003 1231 1138 233 -382 36 -412 630 655 223 343 -20 228 -146 -153 -128 -393 -176 -415 -982 -1257 -2046 -1959 -1062 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