File name: Pandora179s1_CornwallCT_20240319_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240320T050253.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240319_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240319 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240319T180541.6Z 8844.753954 17 1 49.24 2 44.46 203.53 85.66 60.42 0.00 1 0.00 1 0 17 9.463e-03 5.708e-03 6.510e-04 2.622e-04 2.637643e-01 1.312367e-04 3.186297e-03 -6.000000e+00 5.383363e-03 226.20 -2.00 3.52 -2.00 316.70 0.00e+00 3.863572e-04 1.594510e-05 5.078820e-05 -6.000000e+00 2.310230e-04 274.02 -2.00 20.00 -2.00 316.14 0.00e+00 1.399 0.000 302.00 328.00 3 1.7083e+00 3.4203e-04 1.8925e-02 -6.0000e+00 1.3364e-02 3.8854e-02 3.8392e-04 1.3360e-02 -6.0000e+00 1.4559e-02 -9.3953e-03 2.2615e-04 6.6446e-03 -6.0000e+00 8.6416e-03 -1.4164e-03 1.0795e-04 1.9018e-03 -6.0000e+00 3.6274e-03 1.7954e-02 -1.1102e-04 7.4976e-06 2.2281e-05 -6.0000e+00 2.5794e-04 6.4355e-03 0.0000e+00 10 0 0 10 0 0 99.98 22.71 0.29 0.00644 0.00560 1716 410 1 5 0 28.210 25.90 20.00 22.71 8.87 29.2 968.67 53 -1407 -611 -3182 -3878 -2964 -1872 -501 138 -520 -3136 -1942 -1362 -783 -65 286 -459 291 597 956 965 131 1427 697 683 562 307 -545 -371 471 1446 1402 1985 454 -2309 -1383 -1758 -1014 -177 -233 -912 -802 -597 -808 -243 -250 -531 -456 -552 -178 866 708 832 1154 536 905 831 542 428 637 898 1303 1370 1330 237 -484 -142 -609 786 729 148 236 -67 303 -46 -141 -199 -544 -88 -459 -1051 -1127 -2065 -1719 -998 -880 -435 -228 222 183 381 387 155 718 708 330 651 723 2 -230 -207 -659 -296 202 -574 -935 -629 -622 -273 258 124 40 100 76 74 409 522 289 364 -46 -347 198 163 295 647 593 452 1131 433 228 108 -209 -71 48 -96 -206 -50 169 -309 -192 -87 -437 -365 7 -226 -101 -519 -566 -398 -257 -75 23 -93 -577 -355 -272 -162 -15 75 -127 83 176 290 300 41 442 228 236 203 112 -190 -119 146 463 485 739 179 -888 -505 -688 -454 -87 -134 -582 -495 -379 -520 -155 -159 -361 -301 -357 -114 576 467 580 845 408 700 654 426 330 484 698 1077 1141 1184 215 -410 -119 -496 664 645 145 241 -69 299 -42 -126 -160 -415 -69 -406 -977 -1158 -2138 -1858 -1143 -1078 -525 -283 275 219 448 414 163 724 751 362 790 909 2 -305 -257 -806 -341 238 -737 -1194 -838 -866 -399 376 191 62 149 112 99 517 699 380 512 -66 -502 281 240 414 857 796 578 1446 558 316 157 -313 -108 72 -151 -342 -80 275 -508 -306 -142 -686 -561 SS 20240319T180944.0Z 8844.756760 20 1 0.25 2 44.76 204.90 85.03 61.04 0.00 1 0.00 1 0 17 1.147e-02 6.846e-03 8.011e-03 3.971e-03 2.687366e-01 2.004104e-03 3.262155e-03 -6.000000e+00 6.522219e-03 226.20 -2.00 3.52 -2.00 316.09 0.00e+00 5.869407e-04 2.128638e-04 5.266903e-05 -6.000000e+00 2.799045e-04 274.02 -2.00 20.00 -2.00 315.56 0.00e+00 1.406 0.000 302.00 328.00 3 1.6552e+00 5.1807e-03 1.9152e-02 -6.0000e+00 1.6191e-02 5.2347e-02 5.8019e-03 1.3613e-02 -6.0000e+00 1.7639e-02 -1.7717e-02 3.3547e-03 6.7572e-03 -6.0000e+00 1.0470e-02 1.9619e-03 1.5522e-03 1.9524e-03 -6.0000e+00 4.3945e-03 1.8549e-02 -4.6907e-04 1.1236e-04 2.3846e-05 -6.0000e+00 3.1252e-04 6.8189e-03 0.0000e+00 12 9 1 12 1 1 999.00 22.72 0.27 0.00682 0.00329 2 141 1 5 0 82.240 25.90 20.00 22.72 9.23 29.2 970.69 -1566 -458 -3637 -1548 -6159 1134 -3498 610 -556 -2713 147 -3325 -883 -2168 294 169 1968 724 94 598 1461 1980 1444 1155 748 1564 851 -242 -1540 -333 588 1115 2196 -374 -1343 -2283 361 -693 -396 -246 -1436 -554 -416 13 -936 727 -845 -277 -1151 83 681 401 1074 774 434 838 725 539 295 637 293 815 1700 889 680 -667 -593 -698 513 679 96 610 -407 417 370 -765 29 -747 360 -65 -1257 -2046 -1757 -1942 -1098 -1351 374 -62 127 281 9 682 -81 830 283 755 685 1453 317 -494 -40 -1008 -178 252 -509 -1464 -480 -133 -166 274 -194 -336 206 577 -6 618 366 173 424 -72 -314 -60 109 210 1163 282 658 980 516 109 -161 96 94 -190 -409 -335 74 -92 -112 67 -438 -102 -381 -302 -90 -764 -306 -1236 196 -651 121 -124 -608 32 -752 -215 -613 93 55 665 256 35 228 564 754 558 469 322 644 355 -105 -624 -129 237 483 946 -173 -594 -975 160 -358 -227 -156 -956 -384 -297 9 -677 516 -599 -190 -779 56 473 300 842 606 352 691 608 452 242 516 244 681 1531 820 633 -616 -504 -607 439 620 97 612 -413 425 351 -695 25 -609 300 -58 -1209 -2088 -1914 -2117 -1267 -1600 459 -76 154 345 11 769 -84 864 296 828 800 1865 418 -649 -51 -1195 -206 298 -628 -1850 -628 -181 -228 384 -288 -506 298 803 -8 803 474 224 587 -102 -456 -86 151 291 1509 367 810 1209 683 148 -222 136 136 -274 -625 -517 117 -148 -181 106 -664 -154 -564 SS 20240319T182555.4Z 8844.768002 29 1 0.82 2 46.16 210.24 82.46 63.50 0.00 1 0.00 1 0 17 1.374e-02 7.144e-03 8.596e-03 4.068e-03 2.752094e-01 2.056527e-03 3.354264e-03 -6.000000e+00 7.816381e-03 226.21 -2.00 3.52 -2.00 316.21 0.00e+00 1.080043e-04 2.238278e-04 4.380088e-05 -6.000000e+00 3.354374e-04 274.02 -2.00 20.00 -2.00 315.67 0.00e+00 1.441 0.000 302.00 328.00 3 2.8421e+00 5.3230e-03 1.9651e-02 -6.0000e+00 1.9404e-02 5.0598e-02 5.9585e-03 1.3968e-02 -6.0000e+00 2.1139e-02 -1.2284e-02 3.4617e-03 6.9429e-03 -6.0000e+00 1.2547e-02 1.0704e-03 1.6128e-03 1.9613e-03 -6.0000e+00 5.2667e-03 5.4190e-03 -2.8593e-04 1.1523e-04 2.4405e-05 -6.0000e+00 3.7451e-04 6.5345e-03 0.0000e+00 12 9 1 12 1 1 999.00 22.74 0.25 0.00653 0.00439 2 43 1 5 0 272.460 25.90 20.00 22.74 9.60 28.8 970.81 -1427 3645 -2934 -477 -7609 -5639 -2949 339 -2157 1781 -2775 -3727 774 -3146 -269 -318 719 -1007 1583 1046 1043 1699 1514 1663 -129 2332 185 1456 -1761 1219 329 161 2898 -228 -1013 -2147 -52 -1350 546 -1179 -30 -1886 -193 -627 -357 1597 -653 -24 -884 -28 315 358 73 1207 -435 -3 1441 327 677 496 117 1037 1691 1072 361 -398 -465 -156 536 380 159 62 117 568 20 -1154 93 -642 1114 -720 -677 -1036 -1858 -1581 -904 -1198 -695 46 -58 180 756 768 -62 1015 653 497 540 695 118 -267 -337 -606 504 189 -602 -1610 -623 -465 -535 52 527 355 -75 -315 -277 1211 600 714 176 -235 -765 -354 614 315 656 269 1171 863 447 201 327 -588 227 232 172 -249 -332 154 -622 -580 209 -172 -326 -250 679 -564 -92 -1409 -952 -500 62 -453 385 -583 -796 174 -845 -80 -99 234 -345 551 378 386 620 559 646 -51 929 76 597 -691 450 128 68 1211 -103 -437 -897 -23 -649 308 -754 -20 -1338 -132 -435 -245 1132 -465 -17 -603 -19 222 257 56 960 -347 -3 1171 268 541 392 95 891 1497 977 334 -361 -408 -132 474 362 160 62 118 575 19 -1039 78 -538 906 -639 -646 -1052 -2036 -1738 -1053 -1441 -844 57 -72 216 867 834 -65 1056 688 554 644 883 154 -346 -425 -729 587 227 -758 -2086 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