File name: Pandora179s1_CornwallCT_20240401_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240402T052820.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240401_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240401 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240401T174727.2Z 8857.741287 439 1 11.48 2 38.57 200.48 120.42 256.87 0.00 1 0.00 1 0 17 9.099e-03 6.293e-03 1.953e-03 1.111e-03 2.275544e-01 5.637114e-04 2.778563e-03 -6.000000e+00 5.193734e-03 227.20 -2.00 3.52 -2.00 315.65 0.00e+00 2.947094e-04 5.409328e-05 2.928013e-05 -6.000000e+00 2.234128e-04 275.47 -2.00 20.00 -2.00 315.11 0.00e+00 1.278 0.000 302.00 328.00 3 3.4928e+00 1.4547e-03 1.6863e-02 -6.0000e+00 1.2917e-02 2.3109e-02 1.6250e-03 1.1603e-02 -6.0000e+00 1.4060e-02 -5.6012e-03 9.3298e-04 5.7453e-03 -6.0000e+00 8.3460e-03 -1.0311e-03 4.2090e-04 1.6231e-03 -6.0000e+00 3.4986e-03 3.6219e-03 -2.2832e-04 3.1556e-05 2.0652e-05 -6.0000e+00 2.4810e-04 9.8002e-03 0.0000e+00 12 1 1 12 1 1 99.27 22.68 0.28 0.00980 0.00808 25 26 1 5 0 441.380 25.90 20.00 22.68 16.36 30.0 1012.86 -371 131 -821 -1902 -3198 -3445 -1414 -802 936 -306 -2805 -1881 -990 -1042 131 196 -597 678 586 917 748 296 1520 1093 1290 821 630 -428 -64 366 1721 1162 2311 657 -2060 -1253 -1557 -1087 -204 -114 -913 -617 -946 -721 -618 -3 -674 -150 -662 -178 618 745 785 976 477 568 665 324 423 670 920 1210 1095 1232 130 -340 -87 -638 793 757 113 153 68 382 -169 -173 -96 -542 29 -643 -1221 -1053 -2120 -1774 -906 -729 -409 -285 18 29 351 376 346 748 892 433 698 662 -50 -340 -182 -667 -197 182 -648 -922 -724 -631 -370 250 269 33 28 112 4 606 605 388 309 -232 -410 36 270 316 757 762 760 1389 560 214 248 -102 -43 56 -280 -256 -43 161 -426 -296 -166 -521 -393 -89 32 -207 -461 -759 -760 -315 -197 252 -81 -758 -503 -286 -341 48 73 -235 270 242 389 325 128 654 494 612 406 314 -203 -28 153 737 536 1132 315 -1031 -596 -794 -591 -123 -75 -667 -471 -701 -538 -458 -2 -518 -111 -479 -127 457 587 614 800 405 490 582 283 363 567 797 1053 1033 1168 125 -319 -75 -562 682 734 115 154 68 392 -163 -158 -83 -445 25 -574 -1163 -1103 -2274 -1984 -1023 -880 -496 -356 23 35 408 417 367 761 950 483 820 819 -65 -441 -222 -786 -230 208 -810 -1167 -956 -831 -510 348 392 49 39 152 5 772 767 492 420 -323 -586 51 370 432 975 977 926 1690 731 285 345 -139 -60 80 -411 -394 -66 247 -662 -447 -252 -765 -566 SS 20240401T175116.9Z 8857.743946 442 1 4.64 2 38.83 201.95 121.08 257.39 0.00 1 0.00 1 0 17 8.611e-03 6.032e-03 1.670e-03 9.481e-04 2.291232e-01 4.808085e-04 2.795389e-03 -6.000000e+00 4.914989e-03 227.20 -2.00 3.52 -2.00 315.68 0.00e+00 2.103423e-04 4.661560e-05 3.025084e-05 -6.000000e+00 2.114262e-04 275.48 -2.00 20.00 -2.00 315.14 0.00e+00 1.283 0.000 302.00 328.00 3 2.2817e+00 1.2414e-03 1.6949e-02 -6.0000e+00 1.2223e-02 2.0710e-02 1.3869e-03 1.1673e-02 -6.0000e+00 1.3305e-02 -4.8495e-03 7.9459e-04 5.7798e-03 -6.0000e+00 7.8982e-03 -1.7034e-03 3.5847e-04 1.6245e-03 -6.0000e+00 3.3107e-03 1.2085e-02 -2.9839e-04 2.6888e-05 2.0380e-05 -6.0000e+00 2.3480e-04 1.0159e-02 0.0000e+00 12 1 1 12 1 1 96.42 22.68 0.32 0.01016 0.00792 35 90 1 5 0 128.700 25.90 19.99 22.68 16.53 30.0 1014.31 235 -734 -478 -2237 -3897 -2210 -1617 949 77 -426 -2282 -1758 -1114 -634 69 -360 123 656 787 715 812 100 1101 844 833 848 628 243 -67 713 1654 1372 1427 531 -1984 -1275 -1278 -1114 154 -409 -968 -985 -738 -962 -362 -77 -522 -472 -712 -138 647 515 777 1204 493 956 671 457 584 552 812 1224 1264 1223 84 -396 -241 -274 826 621 195 15 -35 266 -22 2 -385 -557 18 -371 -1201 -1182 -1988 -1614 -965 -733 -564 -341 97 41 316 544 265 809 688 364 646 731 -154 -294 -105 -678 -235 273 -636 -909 -534 -713 -281 237 86 36 206 8 2 501 591 338 336 -148 -388 265 113 321 735 713 642 1189 453 310 178 -120 -91 65 -125 -164 -134 112 -354 -194 -289 -478 -334 56 -179 -120 -546 -935 -483 -362 230 19 -114 -618 -473 -324 -208 26 -136 49 264 327 307 356 44 480 387 402 394 293 116 -30 302 718 639 714 258 -934 -615 -612 -614 94 -275 -719 -721 -554 -731 -272 -57 -383 -356 -524 -100 486 389 618 1001 402 790 565 385 480 451 677 1085 1148 1181 82 -359 -212 -232 725 583 192 16 -36 264 -22 2 -342 -466 15 -337 -1168 -1202 -2175 -1753 -1113 -863 -699 -417 124 50 375 615 274 840 713 415 776 924 -199 -374 -130 -817 -267 319 -777 -1177 -688 -962 -379 337 123 52 298 11 3 624 734 438 448 -202 -546 366 158 429 970 895 803 1485 579 404 243 -168 -129 92 -188 -248 -208 170 -542 -301 -433 -720 -494 SS 20240401T175527.6Z 8857.746847 445 1 20.22 2 39.13 203.54 121.81 257.97 0.00 1 0.00 1 0 17 8.719e-03 6.105e-03 4.606e-04 2.554e-04 2.306961e-01 1.296632e-04 2.812698e-03 -6.000000e+00 4.977177e-03 227.20 -2.00 3.52 -2.00 315.78 0.00e+00 2.878234e-04 1.275532e-05 3.100140e-05 -6.000000e+00 2.140942e-04 275.48 -2.00 20.00 -2.00 315.23 0.00e+00 1.288 0.000 302.00 328.00 3 1.1272e+00 3.3500e-04 1.7044e-02 -6.0000e+00 1.2378e-02 2.0139e-02 3.7437e-04 1.1757e-02 -6.0000e+00 1.3473e-02 -6.0082e-03 2.1493e-04 5.8219e-03 -6.0000e+00 7.9979e-03 -1.0704e-03 9.7071e-05 1.6461e-03 -6.0000e+00 3.3529e-03 3.8042e-02 -1.8316e-04 7.2392e-06 2.0305e-05 -6.0000e+00 2.3774e-04 9.4649e-03 0.0000e+00 12 1 1 12 1 1 99.89 22.69 0.31 0.00946 0.00809 596 344 1 5 0 33.690 25.90 20.00 22.69 16.78 30.2 1016.80 -64 -980 -471 -2630 -3515 -2394 -1706 21 412 -159 -2325 -1533 -853 -490 280 267 -261 544 700 1074 997 175 1310 922 787 887 472 -218 -147 722 1422 1431 2017 362 -2091 -1235 -1536 -913 -125 -347 -920 -836 -667 -892 -321 -317 -567 -496 -658 -186 797 632 903 1057 559 864 779 443 436 559 832 1204 1316 1244 112 -478 -113 -516 799 696 51 199 -89 281 10 -108 -81 -447 25 -464 -1053 -1188 -2127 -1675 -980 -932 -483 -318 133 73 299 431 225 829 792 412 662 705 -118 -252 -181 -618 -212 210 -633 -916 -652 -624 -286 223 85 -13 99 148 145 478 526 297 349 -124 -393 130 151 323 759 723 607 1254 590 308 193 -184 -60 90 -109 -254 -88 103 -414 -255 -150 -455 -400 -14 -246 -121 -659 -788 -492 -359 5 105 -43 -644 -420 -232 -151 97 102 -97 206 274 432 410 72 537 397 357 417 224 -99 -61 311 583 628 946 179 -1001 -562 -749 -474 -77 -234 -644 -613 -501 -679 -241 -238 -418 -354 -457 -137 565 479 721 832 456 715 656 374 360 456 695 1069 1193 1200 109 -433 -99 -438 703 652 51 204 -92 278 10 -101 -68 -376 22 -424 -1024 -1207 -2328 -1815 -1126 -1093 -595 -404 169 89 354 488 232 863 820 470 794 888 -151 -319 -225 -743 -240 245 -770 -1181 -837 -836 -400 315 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