File name: Pandora179s1_CornwallCT_20240424_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240425T045906.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240424_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240424 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240424T133906.3Z 8880.568823 324 1 49.24 2 50.44 110.08 129.12 281.35 0.00 1 0.00 1 0 17 6.973e-02 1.511e-02 2.263e-02 5.044e-03 3.364095e-01 2.546419e-03 3.950579e-03 -6.000000e+00 4.008238e-02 229.04 -2.00 3.52 -2.00 317.90 0.00e+00 -4.633966e-04 4.248494e-04 1.355133e-04 -6.000000e+00 1.730609e-03 278.07 -2.00 20.00 -2.00 317.25 0.00e+00 1.567 0.000 302.00 328.00 3 6.8568e+00 6.8076e-03 2.3036e-02 -6.0000e+00 1.0003e-01 1.1919e-01 7.7144e-03 1.7221e-02 -6.0000e+00 1.0868e-01 -2.8964e-02 4.8456e-03 8.4820e-03 -6.0000e+00 6.4518e-02 2.6384e-03 2.4413e-03 2.3893e-03 -6.0000e+00 2.7010e-02 7.5513e-05 -9.6186e-05 1.4466e-04 2.6022e-05 -6.0000e+00 1.9021e-03 8.6330e-03 0.0000e+00 12 9 8 11 32 0 99.98 22.62 0.77 0.00863 0.00791 14 3 1 5 0 3516.940 25.79 20.00 22.62 14.07 30.1 989.32 -6259 34952 -18164 1266 -5862 -20374 -3237 -21554 14912 18136 -33133 -17756 -20152 -9734 13253 -2708 6070 -5739 2831 -5041 -3963 12298 10535 -4578 3686 801 -1231 581 -3952 -5728 4795 -3548 6611 20539 -2330 4593 -9797 -3965 3924 7800 -2767 2849 1509 1050 -2479 157 2304 650 -1041 -3745 948 6254 -323 1958 927 4273 82 -2227 3615 -1084 -1551 635 428 2729 1248 -4836 660 -1143 -762 683 770 2514 -281 40 -1620 -505 1761 -1556 123 -752 -4263 -412 -2049 -2716 980 -1495 772 508 1596 -1184 1305 -741 -1176 606 710 -81 -590 1347 767 322 -152 -1880 -817 -747 -630 743 116 -813 -1219 84 1145 -159 -562 481 484 -409 -1234 1350 4 707 870 -856 1485 893 -844 3375 -1081 555 625 -45 273 528 51 -163 -1272 387 -575 206 -132 332 443 -820 -841 -448 1865 -1725 95 -424 -1596 -223 -1998 1083 1373 -4225 -1982 -2577 -1304 1635 -441 965 -1073 509 -1017 -810 2122 1882 -1010 798 187 -295 130 -860 -1242 994 -878 1619 4593 -623 1102 -2910 -1289 1420 2979 -1304 1337 740 523 -1272 78 1108 312 -501 -1871 478 3226 -189 1188 591 2695 55 -1523 2275 -703 -1033 443 326 2186 1025 -3952 476 -820 -578 577 666 2233 -256 35 -1423 -393 1211 -1055 86 -599 -3977 -382 -2076 -2905 1077 -1798 955 648 2012 -1474 1465 -776 -1138 601 698 -89 -728 1698 1033 429 -202 -2331 -941 -880 -801 982 151 -1121 -1784 130 1859 -266 -913 722 667 -572 -1733 1926 6 1073 1334 -1309 2149 1243 -1209 4407 -1406 720 872 -64 408 810 80 -269 -2246 663 -1017 368 -236 572 774 -1388 -1395 SS 20240424T140132.8Z 8880.584407 343 1 48.36 2 46.58 115.24 133.07 285.72 0.00 1 0.00 1 0 17 1.178e-02 5.556e-03 4.540e-03 1.396e-03 2.918789e-01 7.047909e-04 3.477094e-03 -6.000000e+00 6.769771e-03 229.04 -2.00 3.52 -2.00 317.25 0.00e+00 4.041406e-04 9.963112e-05 6.725289e-05 -6.000000e+00 2.922912e-04 278.08 -2.00 20.00 -2.00 316.60 0.00e+00 1.453 0.000 302.00 328.00 3 4.8108e+00 1.8639e-03 2.0579e-02 -6.0000e+00 1.6895e-02 4.8365e-02 2.0955e-03 1.4980e-02 -6.0000e+00 1.8356e-02 2.3779e-04 1.2607e-03 7.3729e-03 -6.0000e+00 1.0897e-02 -5.7149e-03 6.1868e-04 2.0738e-03 -6.0000e+00 4.5621e-03 7.1700e-04 -1.4975e-04 4.0143e-05 2.3363e-05 -6.0000e+00 3.2125e-04 8.3959e-03 0.0000e+00 10 0 0 10 0 0 100.00 22.61 0.27 0.00840 0.00727 82 20 1 5 0 589.650 25.79 20.00 22.61 16.05 30.3 1000.34 -879 2131 -2384 -3219 -4651 -3151 -2209 -3018 641 -315 -5298 -3210 -2397 -439 2120 59 -1059 -689 289 1738 89 211 1424 286 684 364 -898 -354 -1226 -149 1775 636 1699 1768 -2078 -1589 -2390 -1189 -87 482 -1189 -682 -149 -621 -321 299 -967 -234 -888 -465 728 992 474 795 535 1357 849 358 660 263 538 1141 1323 1503 486 -444 36 -481 609 595 353 181 -311 73 -169 -332 -238 -983 -78 -607 -1343 -1126 -1763 -1741 -800 -372 -450 -44 650 -181 430 478 512 638 757 272 612 774 116 -213 -191 -683 -401 18 -579 -719 -486 -663 -413 261 258 183 26 217 89 177 213 149 299 -76 -441 33 315 321 312 722 245 1087 591 151 146 -383 -155 58 -255 -15 105 196 -337 -79 45 -428 -371 -87 229 -280 -367 -481 -299 -216 -331 76 -40 -718 -431 -355 -74 400 13 -245 -165 72 441 22 55 374 74 187 104 -262 -97 -343 -40 496 196 520 566 -657 -520 -780 -444 -39 250 -645 -387 -87 -368 -189 175 -565 -132 -498 -260 423 619 315 557 389 999 640 271 486 192 402 846 1067 1296 427 -367 27 -383 473 522 341 171 -296 71 -154 -271 -188 -742 -61 -500 -1254 -1089 -1837 -1901 -924 -430 -549 -55 810 -219 508 515 539 649 763 305 715 1001 161 -291 -245 -855 -471 21 -714 -937 -660 -946 -584 392 409 279 41 313 125 233 279 204 437 -112 -662 49 448 463 426 934 322 1432 788 217 209 -566 -232 90 -423 -24 176 336 -582 -132 72 -699 -592 SS 20240424T140548.7Z 8880.587369 346 1 3.18 2 45.86 116.29 133.81 286.59 0.00 1 0.00 1 0 17 1.273e-02 6.702e-03 5.744e-03 2.443e-03 2.859026e-01 1.241597e-03 3.458290e-03 -6.000000e+00 7.314692e-03 229.04 -2.00 3.52 -2.00 316.48 0.00e+00 5.818687e-04 1.449753e-04 5.214764e-05 -6.000000e+00 3.158357e-04 278.08 -2.00 20.00 -2.00 315.86 0.00e+00 1.434 0.000 302.00 328.00 3 3.3757e+00 3.2424e-03 2.0262e-02 -6.0000e+00 1.8255e-02 4.3760e-02 3.6295e-03 1.4728e-02 -6.0000e+00 1.9834e-02 -5.4368e-03 2.1142e-03 7.2434e-03 -6.0000e+00 1.1774e-02 -1.8721e-03 9.9401e-04 2.0528e-03 -6.0000e+00 4.9286e-03 3.1066e-03 -3.5792e-04 6.9085e-05 2.4054e-05 -6.0000e+00 3.4717e-04 9.5403e-03 0.0000e+00 12 9 1 12 1 1 98.00 22.61 0.32 0.00954 0.00685 6 26 1 5 0 453.720 25.79 20.00 22.61 16.33 30.3 1001.70 -3323 -2024 -738 -4819 -3593 -4856 1034 -1816 -391 -1655 -3054 -5014 -976 -1362 -483 1082 -603 2924 528 2686 249 -18 1478 1051 1196 1766 353 -1521 318 -466 2312 538 1961 -428 -1712 -1214 -2452 -1215 -215 400 -1486 -240 -1154 -633 -219 -297 189 -659 -427 -523 1241 776 825 797 613 1125 488 816 710 719 607 1706 1216 1874 -393 -234 -339 -462 717 384 91 501 111 464 -113 -512 -160 -1319 111 -522 -1488 -1324 -2539 -1211 -1025 -451 -423 -224 71 53 128 437 -32 610 1419 285 727 480 -86 -286 74 -655 -551 36 -724 -749 -558 -403 -452 316 298 -57 -144 484 245 557 574 147 75 -435 -305 -67 116 540 665 948 820 1010 614 485 181 -27 1 177 -178 -217 61 -201 -566 -363 -170 -457 -170 -497 -335 -126 -823 -541 -690 143 -288 -68 -314 -589 -997 -207 -335 -124 306 -184 894 173 891 87 -6 511 384 425 650 133 -554 115 -165 839 200 780 -182 -700 -475 -1039 -588 -114 233 -976 -154 -768 -424 -146 -197 123 -452 -286 -352 862 546 615 627 471 877 390 648 552 553 479 1424 1048 1718 -371 -205 -292 -387 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