File name: Pandora179s1_CornwallCT_20240426_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240429T095606.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240426_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240426 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240426T104007.3Z 8882.444529 204 1 48.63 2 82.86 77.92 87.53 231.57 0.00 1 0.00 1 0 25 6.196e-01 1.896e-02 3.145e-01 5.456e-03 1.281984e+00 3.272852e-03 1.354387e-02 -6.000000e+00 3.593782e-01 229.20 -2.00 3.52 -2.00 322.57 0.00e+00 -7.329445e-04 2.080130e-03 1.680273e-02 -6.000000e+00 1.567755e-02 278.29 -2.00 20.00 -2.00 322.18 0.00e+00 7.414 0.007 302.00 328.00 3 1.9177e-01 1.3879e-02 1.4663e-01 -6.0000e+00 8.9877e-01 1.4297e+00 2.2472e-02 1.6735e-01 -6.0000e+00 9.7957e-01 -1.8059e+00 2.3721e-02 7.3623e-02 -6.0000e+00 5.7926e-01 7.0061e-01 1.0341e-02 1.4189e-02 -6.0000e+00 2.4428e-01 9.4463e-05 -1.3501e-03 1.2656e-04 3.2464e-04 -6.0000e+00 1.7335e-02 1.3929e-02 0.0000e+00 12 8 8 10 0 0 11.97 22.64 0.44 0.01393 0.00378 113 27 1 5 0 430.250 25.79 19.99 22.64 6.41 29.2 941.76 900000 900000 -137156 -115709 -30433 -185807 -225305 -250529 -119546 -86635 -271099 -133634 -195356 -51867 900000 -44052 -30793 -101422 -27965 11065 -19593 -32800 900000 -105245 66670 96994 -93216 -78112 -61494 -107836 -29584 -57308 -19915 900000 8 172143 -64264 40990 13526 900000 49284 33582 30707 55377 14393 19783 -27811 50783 19751 8116 55015 73126 13775 64708 36302 79652 48366 41608 62090 49189 21493 22225 35254 18667 39635 7883 30617 19484 17715 29896 33423 24660 25081 17271 4126 12948 11182 10599 7340 8718 617 8491 4827 2972 4219 9365 6927 3662 7025 -1452 2413 -2567 143 1156 -1086 -2734 -2682 -1243 -1709 -2428 -2317 -1912 -1331 -1869 -1833 -305 -518 -3108 -2740 -2787 -1073 -1654 -1832 -1169 -1010 -531 204 131 -351 538 582 1677 1872 2369 1504 2816 203 2502 219 705 401 185 88 -29 -455 655 868 697 -53 -520 -185 -1250 -1846 900000 900000 -1259 -783 -162 -1885 -3374 -5084 -693 -460 -7727 -1098 -3870 -326 900000 -404 -283 -2058 -284 75 -170 -301 900000 -2136 354 515 -1932 -1287 -817 -2522 -409 -1340 -381 900000 0 915 -1878 479 252 900000 864 732 702 971 367 473 -1094 972 567 293 1433 1827 695 2166 1736 2582 2185 1946 2178 1804 1017 1134 1855 1379 2654 754 2457 1916 2015 3479 4121 3407 3306 2212 522 1307 1099 1143 991 1459 137 2080 1388 932 1377 3031 2367 1306 2375 -508 758 -817 46 412 -481 -1380 -1648 -898 -1394 -2031 -1806 -1293 -776 -1051 -1084 -187 -340 -2323 -2380 -2923 -1315 -2297 -2706 -1742 -1481 -763 297 200 -514 850 863 2262 2379 2904 1811 3269 241 3246 355 1260 834 431 224 -76 -1267 1882 2507 2012 -149 -1366 -471 -2902 -4104 SS 20240426T105102.7Z 8882.452114 207 1 48.52 2 80.86 79.68 89.10 233.36 0.00 1 0.00 1 0 17 9.747e-01 1.391e-02 1.441e-01 2.257e-03 1.078004e+00 1.267424e-03 1.138766e-02 -6.000000e+00 5.602861e-01 229.20 -2.00 3.52 -2.00 322.05 0.00e+00 8.389198e-03 7.350766e-04 3.175899e-03 -6.000000e+00 2.420633e-02 278.29 -2.00 20.00 -2.00 321.61 0.00e+00 5.981 0.004 302.00 328.00 3 2.9015e-01 4.7977e-03 8.7052e-02 -6.0000e+00 1.3987e+00 6.0786e-01 7.9133e-03 7.5257e-02 -6.0000e+00 1.5198e+00 -7.4672e-01 8.9659e-03 3.4798e-02 -6.0000e+00 9.0218e-01 2.9209e-01 3.9784e-03 1.5310e-02 -6.0000e+00 3.7734e-01 4.1219e-04 -1.0962e-03 5.2685e-05 1.6827e-04 -6.0000e+00 2.6595e-02 1.3772e-02 0.0000e+00 12 8 8 10 0 0 55.40 22.65 0.38 0.01377 0.00553 256 61 1 5 0 189.490 25.79 19.99 22.65 7.49 29.4 948.85 -270457 -243838 -259145 -312325 -272106 -340734 -284651 -361384 -249027 -272306 -325075 -250683 -259366 -104497 -126295 -82444 -168108 -116469 -132015 -95285 -113465 -112584 -29942 -137665 -7992 -96475 -93011 -123115 -83208 -117368 -36060 -71709 -27358 52900 -20063 5771 -55122 113 -13872 18392 -10357 15498 -633 11240 9985 6451 -292 14737 12250 -556 24115 16717 16604 22554 19214 21356 13312 14754 10573 13604 3832 9003 10257 13920 11798 10081 12365 7584 10776 9860 14096 7659 9129 3805 2701 -826 360 555 971 3218 104 3007 -629 71 -415 1123 -74 340 1869 280 1176 -1074 -496 -1409 -852 -1937 -808 -451 -686 -899 -1004 -1079 -999 -1056 -2256 -1705 -1669 -1207 -1512 -501 -629 -599 -511 -351 -417 40 502 279 377 132 512 781 990 1262 919 1486 487 1332 392 385 303 211 -43 27 -262 11 293 266 -178 -195 -90 -703 -719 -1299 -1122 -1556 -3188 -1688 -3955 -1937 -5713 -1395 -2071 -4489 -1957 -3062 -414 -862 -472 -2739 -1308 -1918 -1007 -1449 -1388 -165 -2394 -40 -1232 -1167 -2060 -952 -2196 -397 -1484 -446 431 -331 71 -1335 2 -318 368 -317 399 -20 332 303 210 -11 506 477 -28 1083 935 1045 1485 1408 1603 1111 1195 850 1018 322 801 1066 1655 1595 1431 1783 1239 1926 2064 3128 1880 2146 865 550 -154 63 105 219 882 33 1075 -261 31 -195 547 -38 176 946 138 536 -478 -221 -694 -495 -1381 -685 -413 -700 -931 -969 -998 -813 -836 -1910 -1513 -1573 -1139 -1636 -631 -920 -890 -787 -538 -621 63 796 428 604 214 787 1208 1451 1782 1259 1967 644 1911 624 724 647 460 -101 69 -669 28 785 716 -472 -517 -217 -1560 -1651 SS 20240426T110227.4Z 8882.460040 212 1 48.47 2 78.76 81.52 90.79 235.20 0.00 1 0.00 1 0 17 8.525e-01 8.641e-03 6.324e-02 1.127e-03 9.176635e-01 6.155808e-04 9.927451e-03 -6.000000e+00 4.901180e-01 229.20 -2.00 3.52 -2.00 321.49 0.00e+00 4.129592e-03 3.138888e-04 1.047481e-03 -6.000000e+00 2.117411e-02 278.29 -2.00 20.00 -2.00 321.01 0.00e+00 4.958 0.002 302.00 328.00 3 2.8598e-01 2.1051e-03 6.8569e-02 -6.0000e+00 1.2235e+00 2.2836e-01 3.2479e-03 5.1202e-02 -6.0000e+00 1.3294e+00 -2.4279e-01 3.6842e-03 2.8172e-02 -6.0000e+00 7.8918e-01 8.5701e-02 1.6982e-03 1.1174e-02 -6.0000e+00 3.3010e-01 1.2825e-03 -6.8863e-04 2.7377e-05 1.2760e-04 -6.0000e+00 2.3262e-02 1.3357e-02 0.0000e+00 11 8 0 10 0 0 26.47 22.65 0.28 0.01336 0.00818 451 108 1 5 0 107.460 25.90 20.00 22.65 8.46 29.5 954.40 -282626 -240553 -270485 -269750 -284861 -284199 -263126 -274323 -258064 -207699 -254654 -207170 -208842 -161694 -113457 -117779 -113753 -98142 -75415 -74645 -63613 -72558 -60273 -83286 -55977 -61029 -74435 -70827 -66011 -60808 -44223 -25377 -21682 -2371 -19316 -18858 -26022 -10083 -7251 -2266 44 -199 3185 4282 5083 1216 -2240 2884 776 1982 4410 8542 4717 7770 5480 7677 4992 3183 3103 1145 2412 2763 5360 5727 5191 3009 3955 2384 2820 3319 3038 2612 1811 1637 -70 13 -567 -1423 -333 -288 -760 -301 -1595 -1671 -437 -652 33 74 787 405 526 -107 -621 -359 -529 -511 -1 626 -41 -197 -489 -958 -581 -532 -1162 -1646 -915 -938 -420 54 16 -78 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