File name: Pandora179s1_CornwallCT_20240519_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240520T045450.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240519_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240519T130921.8Z 8905.548169 268 1 48.42 2 51.07 97.72 142.62 342.77 0.00 1 0.00 1 0 17 1.674e-02 6.168e-03 7.892e-03 2.579e-03 2.428108e-01 1.313383e-03 2.916567e-03 -6.000000e+00 9.697308e-03 231.06 -2.00 3.52 -2.00 317.37 0.00e+00 3.741847e-05 1.861786e-04 6.267393e-05 -6.000000e+00 4.204515e-04 280.92 -2.00 20.00 -2.00 316.64 0.00e+00 1.588 0.000 302.00 328.00 3 4.2974e+00 3.4898e-03 1.9786e-02 -6.0000e+00 2.4297e-02 4.5608e-02 3.9187e-03 1.2689e-02 -6.0000e+00 2.6342e-02 5.6124e-04 2.3348e-03 6.1848e-03 -6.0000e+00 1.5638e-02 -6.4670e-03 1.1294e-03 1.7061e-03 -6.0000e+00 6.5388e-03 1.1712e-03 -2.9076e-04 7.5817e-05 1.9973e-05 -6.0000e+00 4.5689e-04 6.8064e-03 0.0000e+00 10 0 0 10 0 0 100.00 22.90 0.32 0.00681 0.00462 151 36 2 5 0 320.640 26.11 20.00 22.90 19.75 31.1 1002.50 -4703 6890 -5112 -3890 -6334 -1512 1444 -4051 2659 2385 -5548 -3838 -2757 -3285 2248 -801 843 -557 955 2683 137 2202 2181 -19 35 1880 -1348 315 -479 1388 2348 424 3985 3255 -949 -970 -3884 -2048 31 519 -621 -397 -623 -357 -1284 -677 -2213 -16 -1143 -444 1297 885 278 1348 456 1300 492 164 857 493 759 599 1806 975 669 -609 -298 -1047 333 667 172 230 -249 462 -89 -149 -55 -283 -175 -789 -1050 -1501 -1836 -1909 -284 -569 13 -81 838 84 -99 484 174 736 647 912 -38 1014 147 -255 114 -526 192 -310 -581 -906 -40 -834 -100 603 525 -345 -179 146 231 125 52 118 -200 -284 -337 -209 36 476 233 1081 -64 657 650 110 320 -265 -135 60 -89 206 34 248 -404 -182 -394 25 -150 -552 800 -694 -500 -742 -157 150 -494 340 327 -821 -558 -433 -590 435 -177 192 -133 233 664 36 557 557 -5 10 556 -414 90 -128 350 609 121 1178 1010 -291 -285 -1254 -749 13 261 -348 -233 -346 -200 -787 -411 -1339 -9 -647 -249 744 545 182 919 297 856 332 111 616 352 553 427 1380 800 552 -472 -231 -788 259 535 153 213 -233 414 -75 -123 -41 -198 -126 -640 -959 -1391 -1825 -1988 -311 -670 16 -103 1065 104 -113 501 179 725 669 947 -45 1290 200 -344 144 -612 210 -351 -715 -1184 -54 -1189 -148 944 864 -534 -287 216 315 159 66 156 -285 -433 -525 -321 53 677 314 1377 -79 802 844 153 467 -398 -207 95 -149 363 61 458 -694 -329 -689 42 -247 SS 20240519T131400.6Z 8905.551396 271 1 48.45 2 50.22 98.59 142.87 344.56 0.00 1 0.00 1 0 17 8.964e-03 5.578e-03 1.761e-03 7.043e-04 2.345939e-01 3.595277e-04 2.822154e-03 -6.000000e+00 5.193354e-03 231.06 -2.00 3.52 -2.00 316.76 0.00e+00 3.110406e-04 4.420963e-05 4.439840e-05 -6.000000e+00 2.251672e-04 280.92 -2.00 20.00 -2.00 316.06 0.00e+00 1.560 0.000 302.00 328.00 3 3.3475e+00 9.4614e-04 1.9271e-02 -6.0000e+00 1.3012e-02 3.7322e-02 1.0573e-03 1.2230e-02 -6.0000e+00 1.4107e-02 -1.2544e-03 6.1787e-04 5.9621e-03 -6.0000e+00 8.3750e-03 -4.8368e-03 2.9266e-04 1.6528e-03 -6.0000e+00 3.5019e-03 3.1683e-03 -1.5410e-04 2.0433e-05 1.9364e-05 -6.0000e+00 2.4468e-04 6.5780e-03 0.0000e+00 10 0 0 10 0 0 100.00 22.91 0.36 0.00658 0.00542 519 124 1 5 0 93.340 26.11 20.00 22.91 20.01 31.2 1004.04 207 -821 -552 -2936 -3230 -2872 -1413 -812 1017 -291 -2974 -1812 -1417 -538 765 435 -690 448 513 964 547 139 1287 462 712 616 454 -573 -410 336 1297 1113 1843 383 -2253 -1203 -1825 -900 -154 -266 -1098 -644 -826 -678 -451 -227 -865 -479 -603 -237 776 667 715 1010 500 785 890 699 497 690 1059 1234 1459 1491 223 -538 -109 -509 713 654 282 188 61 348 -19 -176 -320 -809 -35 -457 -1078 -1056 -2018 -1617 -756 -705 -452 -119 261 160 408 281 232 679 731 325 579 732 34 -227 -69 -719 -323 190 -666 -867 -565 -606 -238 303 123 112 196 89 53 370 490 219 247 -116 -360 37 41 242 545 556 422 1251 492 232 158 -203 -161 -26 -128 -127 19 201 -331 -124 -49 -428 -339 29 -131 -91 -472 -463 -380 -190 -120 166 -51 -535 -322 -273 -117 187 117 -198 131 155 300 175 44 409 155 251 226 168 -203 -134 105 416 383 678 149 -850 -430 -701 -359 -73 -148 -680 -417 -550 -456 -301 -151 -567 -303 -372 -145 489 451 509 754 355 566 652 512 390 536 839 955 1220 1326 201 -452 -84 -413 549 568 271 189 61 339 -17 -144 -259 -618 -28 -400 -976 -1054 -2172 -1815 -829 -829 -560 -152 333 196 464 315 237 663 748 367 667 929 46 -303 -87 -834 -383 232 -818 -1129 -766 -859 -353 440 188 172 289 132 71 467 615 288 348 -175 -519 56 61 343 731 708 511 1636 636 320 229 -302 -243 -38 -198 -207 32 341 -567 -207 -79 -666 -517 SS 20240519T133119.4Z 8905.563420 277 1 26.29 2 47.04 101.99 143.59 351.38 0.00 1 0.00 1 0 17 9.441e-03 6.116e-03 2.062e-03 1.146e-03 2.213614e-01 5.893194e-04 2.663358e-03 -6.000000e+00 5.469063e-03 231.06 -2.00 3.52 -2.00 315.77 0.00e+00 2.727171e-04 5.841628e-05 3.048836e-05 -6.000000e+00 2.371276e-04 280.93 -2.00 20.00 -2.00 315.13 0.00e+00 1.465 0.000 302.00 328.00 3 4.1433e+00 1.5337e-03 1.8102e-02 -6.0000e+00 1.3703e-02 4.1911e-02 1.7090e-03 1.1471e-02 -6.0000e+00 1.4857e-02 -5.6694e-03 9.7687e-04 5.5901e-03 -6.0000e+00 8.8197e-03 -1.1194e-03 4.3842e-04 1.5474e-03 -6.0000e+00 3.6877e-03 1.5978e-03 -1.2551e-04 3.2642e-05 1.9065e-05 -6.0000e+00 2.5768e-04 6.8975e-03 0.0000e+00 12 1 1 12 1 1 99.94 22.91 0.24 0.00690 0.00595 33 15 1 5 0 773.070 26.11 20.00 22.91 20.84 31.1 1008.33 321 317 -716 -2622 -3796 -2299 -2120 -887 408 515 -3341 -1824 -1710 -1111 1036 -288 -289 561 473 973 727 871 1878 512 1078 1103 459 -309 -1082 707 1044 1100 2214 861 -1945 -870 -2019 -847 120 -256 -877 -567 -537 -599 -425 -200 -857 -189 -676 -416 780 757 509 1253 592 1088 924 315 965 591 885 1113 1360 1133 250 -776 -206 -786 777 644 12 185 178 169 -364 -520 -426 -742 -425 -569 -1221 -1049 -2041 -1776 -784 -700 -377 -42 309 -2 294 456 153 690 640 398 461 691 -42 -173 -103 -577 -187 282 -563 -890 -428 -584 -238 188 346 -3 126 262 148 317 237 235 296 -158 -266 35 96 213 687 953 597 1223 544 156 69 -381 120 -25 -234 -218 -143 291 -372 -110 -125 -425 -462 72 78 -184 -656 -851 -470 -445 -204 103 139 -927 -496 -505 -338 349 -108 -113 224 196 413 316 375 806 215 473 502 211 -136 -478 295 448 503 993 406 -891 -409 -945 -451 70 -177 -624 -422 -410 -462 -326 -152 -643 -137 -476 -289 558 578 411 987 484 899 778 266 794 483 740 990 1228 1089 242 -701 -180 -665 677 596 12 187 181 176 -355 -485 -357 -624 -366 -514 -1169 -1104 -2185 -1984 -877 -840 -477 -52 381 -2 341 506 165 706 685 442 537 886 -55 -222 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