File name: Pandora179s1_CornwallCT_20240526_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240527T050439.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240526_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240526 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240526T103632.8Z 8912.442047 212 1 48.49 2 78.47 71.71 83.88 221.58 0.00 1 0.00 1 0 17 4.947e-01 6.357e-03 2.009e-01 2.238e-03 7.591153e-01 1.216595e-03 8.356916e-03 -6.000000e+00 2.869279e-01 231.47 -2.00 3.52 -2.00 321.25 0.00e+00 4.099616e-03 5.983175e-04 7.083455e-04 -6.000000e+00 1.255901e-02 281.65 -2.00 20.00 -2.00 320.72 0.00e+00 4.839 0.002 302.00 328.00 3 1.8910e+00 4.1134e-03 6.1961e-02 -6.0000e+00 7.1944e-01 6.7078e-02 5.9543e-03 4.2716e-02 -6.0000e+00 7.7979e-01 -9.9892e-02 6.4495e-03 2.2546e-02 -6.0000e+00 4.6322e-01 3.0007e-02 3.0322e-03 9.4390e-03 -6.0000e+00 1.9461e-01 3.6138e-04 -8.3250e-04 5.9278e-05 8.9853e-05 -6.0000e+00 1.3518e-02 9.4625e-03 0.0000e+00 10 0 0 10 0 0 83.98 22.86 0.34 0.00946 0.00321 133 32 1 5 0 364.560 26.11 19.97 22.86 23.03 31.5 1012.99 -220305 900000 -217028 -91792 -205279 -108872 -158886 -193418 -58336 -15734 -176458 -182092 -113584 -80794 48082 -20542 -44446 -45728 -36702 18046 -19102 20488 40813 -33438 -11538 22496 -64795 -7959 -54344 -11077 -6358 -26179 -788 21838 726 -1657 -21367 -10999 2961 6514 2959 -2502 3622 5449 -6508 -1340 -7634 5087 -4146 -2640 3097 6015 -1394 4413 3372 4103 2251 -934 2247 -95 2278 536 4325 1717 3809 -939 1535 1127 987 2289 1030 1355 533 786 -294 -490 610 -1263 9 -756 -1785 -875 -1067 -2718 -394 -17 222 402 827 32 717 654 -413 799 -365 305 -7 974 76 -211 115 -838 43 -443 -817 -1616 -501 -988 -315 192 175 -51 -80 103 -130 364 423 325 49 -156 -235 122 491 435 291 135 -70 583 316 191 264 -275 -194 -85 -273 -141 -63 514 -300 -113 105 23 -148 -1311 900000 -1765 -240 -1425 -309 -797 -1562 -140 -34 -1656 -2066 -843 -582 126 -134 -436 -519 -424 130 -208 152 258 -489 -149 221 -1584 -109 -1186 -172 -115 -720 -20 496 20 -46 -793 -437 127 328 178 -174 253 389 -535 -108 -681 421 -402 -274 343 736 -205 674 560 646 375 -161 402 -17 411 98 882 413 967 -250 398 306 298 789 401 552 217 301 -104 -155 179 -386 3 -313 -885 -496 -672 -1855 -257 -12 161 300 613 23 523 448 -277 553 -266 258 -7 1105 88 -246 136 -896 41 -426 -844 -1780 -577 -1137 -397 273 278 -80 -128 160 -207 555 650 524 77 -255 -378 201 776 662 427 191 -97 847 526 337 512 -577 -402 -188 -646 -327 -150 1227 -716 -272 237 49 -305 SS 20240526T104143.1Z 8912.445637 215 1 14.13 2 77.55 72.51 84.49 222.49 0.00 1 0.00 1 0 17 5.057e-01 1.601e-02 2.358e-01 7.504e-03 7.171040e-01 4.049138e-03 8.244902e-03 -6.000000e+00 2.933747e-01 231.47 -2.00 3.52 -2.00 320.96 0.00e+00 8.223080e-03 1.786287e-03 1.851099e-03 -6.000000e+00 1.306248e-02 281.65 -2.00 20.00 -2.00 320.39 0.00e+00 4.509 0.002 302.00 328.00 3 3.2686e+00 1.3003e-02 5.7603e-02 -6.0000e+00 7.3564e-01 2.8721e-01 1.7190e-02 3.8670e-02 -6.0000e+00 7.9748e-01 -3.5006e-01 1.6612e-02 2.2736e-02 -6.0000e+00 4.7433e-01 1.3617e-01 8.0335e-03 1.1024e-02 -6.0000e+00 1.9991e-01 1.1807e-04 -1.1814e-03 2.0176e-04 1.2747e-04 -6.0000e+00 1.4009e-02 1.0860e-02 0.0000e+00 12 9 9 12 1 1 99.42 22.85 0.51 0.01086 0.00198 8 7 1 5 0 1569.490 26.00 20.01 22.85 23.46 31.7 1016.29 -211708 900000 -194974 900000 -179733 -103578 -177668 -176315 -120328 -8928 -171860 -83815 -145187 -36714 900000 -58600 -7546 -7838 -21309 119792 15953 18393 41729 -62874 52045 125126 -60224 25823 -51484 -38117 12647 -36376 5367 132799 45980 -5360 7068 -14045 34987 33471 9125 8112 21336 4650 -5167 10647 5354 19606 6867 12575 4202 16680 4678 11439 5587 12934 11075 -4077 7842 -2466 9704 3292 7129 5471 7820 -2124 6742 3566 -1294 4361 2853 5478 23 104 -2767 -892 -2729 1242 102 -2548 -3624 -793 -1016 -4072 440 -515 707 -3902 1538 -1302 946 -2206 -1945 -933 -1103 -1107 31 289 -825 -999 -496 -1412 717 -200 -411 -2193 512 -696 -348 521 1398 98 209 446 424 -675 2 456 -113 4 43 269 790 283 697 1475 184 628 947 -98 67 136 93 -25 -1029 -152 373 356 -53 714 -321 -468 -1200 -5068 900000 -5315 900000 -3824 -964 -3544 -3751 -1600 -65 -4228 -1042 -3861 -483 900000 -1403 -138 -161 -545 876 303 336 610 -2508 761 915 -2863 510 -2184 -1533 370 -2128 243 1845 1480 -278 346 -986 1817 2105 828 801 1951 520 -591 1176 642 2122 889 1646 603 2373 824 2046 1122 2494 2224 -946 1564 -535 1916 762 1815 1612 2407 -715 2049 1152 -481 1760 1294 2528 11 47 -1170 -331 -960 426 40 -1220 -2068 -505 -654 -2867 315 -396 564 -3349 1248 -1047 693 -1558 -1320 -647 -863 -1011 33 323 -1019 -1241 -575 -1480 723 -203 -447 -2369 568 -840 -461 771 2120 160 342 706 637 -984 3 693 -183 7 71 423 1187 443 1043 2109 259 925 1467 -174 122 264 190 -54 -2265 -347 864 834 -123 1578 -714 -976 -2446 SS 20240526T104622.5Z 8912.448871 218 1 48.36 2 76.72 73.23 85.06 223.31 0.00 1 0.00 1 0 17 3.403e-01 5.473e-03 7.111e-02 1.468e-03 6.730406e-01 7.830457e-04 7.504517e-03 -6.000000e+00 1.973785e-01 231.47 -2.00 3.52 -2.00 320.85 0.00e+00 3.295365e-03 3.386173e-04 6.632236e-04 -6.000000e+00 8.571640e-03 281.65 -2.00 20.00 -2.00 320.27 0.00e+00 4.246 0.001 302.00 328.00 3 1.7398e+00 2.4948e-03 5.4368e-02 -6.0000e+00 4.9491e-01 4.3497e-02 3.3375e-03 3.7110e-02 -6.0000e+00 5.3640e-01 -5.9180e-02 3.3830e-03 1.8743e-02 -6.0000e+00 3.1846e-01 1.3326e-02 1.6468e-03 7.3830e-03 -6.0000e+00 1.3308e-01 7.7724e-04 -7.5259e-04 4.0099e-05 7.1171e-05 -6.0000e+00 9.2897e-03 9.2660e-03 0.0000e+00 10 0 0 10 0 0 98.65 22.85 0.30 0.00927 0.00361 235 56 1 5 0 205.740 26.00 20.00 22.85 23.84 31.6 1017.97 -120315 -76903 -119285 -130173 -119017 -133517 -104962 -131862 -78396 -53806 -121781 -68729 -89637 -41389 -18898 -26282 -31754 -30060 -13548 -5808 -12095 -24831 -4049 -25667 -2437 -14799 -23877 -22757 -15197 -18294 -8411 -14752 -5218 6021 -5645 -2850 -11985 -4140 -3184 2587 -3024 -911 -665 879 -2156 -609 -1851 921 47 -1216 2397 2203 554 2559 1662 2753 1237 -30 852 346 1365 1618 2684 2893 1602 587 1228 745 1432 1712 1014 895 402 349 -147 -312 -756 -1108 -429 -581 -1147 -1079 -1784 -1870 -742 -283 -26 122 728 585 757 492 433 660 359 -149 469 592 10 -101 -170 -438 -352 -270 -1125 -1078 -923 -725 -379 62 84 94 -43 138 6 290 290 386 86 -317 -418 173 198 266 368 627 182 950 363 251 148 -253 -102 12 -277 -146 35 334 -306 -80 116 -197 -140 -672 -341 -905 -1118 -852 -1071 -676 -1265 -505 -300 -1430 -531 -1078 -403 -189 -350 -518 -542 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