File name: Pandora179s1_CornwallCT_20240616_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240618T224818.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240616_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240616 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240616T102042.8Z 8933.431051 107 1 48.77 2 80.48 67.07 137.35 311.88 0.00 1 0.00 1 0 17 7.186e-01 8.646e-03 1.188e-01 2.036e-03 8.155929e-01 1.121971e-03 8.964063e-03 -6.000000e+00 4.185259e-01 232.61 -2.00 3.52 -2.00 321.49 0.00e+00 4.659846e-03 5.934264e-04 8.172674e-04 -6.000000e+00 1.826571e-02 283.82 -2.00 20.00 -2.00 320.95 0.00e+00 5.762 0.003 302.00 328.00 3 7.7894e-01 4.0190e-03 7.0570e-02 -6.0000e+00 1.0516e+00 1.9132e-01 5.9603e-03 4.5916e-02 -6.0000e+00 1.1384e+00 -2.1864e-01 6.3203e-03 2.4484e-02 -6.0000e+00 6.7611e-01 7.8748e-02 2.9005e-03 1.0412e-02 -6.0000e+00 2.8239e-01 4.4470e-04 -8.3715e-04 5.3258e-05 1.1285e-04 -6.0000e+00 1.9627e-02 1.0806e-02 0.0000e+00 11 8 0 10 0 0 98.26 22.81 0.33 0.01081 0.00452 185 44 1 5 0 262.170 26.00 19.99 22.81 15.97 31.2 953.35 -283639 -136293 -249339 -245339 -226213 -220718 -225221 -263412 -165621 -208683 -189774 -184957 -177872 -147088 -76251 -85607 -83423 -57096 -71968 -42957 -59467 -47543 -30476 -67416 -50866 -30007 -78155 -59830 -53928 -61093 -17282 -44699 -5605 10911 -7325 -16143 -28171 -12247 -6264 12570 -4718 3140 4767 13438 -4986 3718 -9415 6235 2425 -815 7378 11250 5591 6839 6866 7822 6944 2000 5139 1282 3013 2486 5584 6063 5307 2901 3826 2556 1661 3950 3157 2013 1699 1020 43 -358 78 -2713 -449 -583 -396 -288 -1963 -2423 -509 247 -405 -184 438 497 61 -45 -791 -78 -81 -453 82 343 139 -381 -316 -1067 -645 -150 -796 -1165 -473 -1122 -519 -232 18 -12 -284 180 -77 333 398 282 246 -142 107 428 518 509 442 625 168 901 270 225 89 -104 5 -27 -387 -95 54 420 -241 -183 51 -183 -287 -2509 -344 -2205 -2126 -1511 -1490 -1699 -2996 -888 -1906 -1545 -1653 -1943 -1606 -545 -850 -961 -578 -943 -452 -768 -548 -309 -1084 -758 -387 -1692 -1069 -910 -1225 -278 -1189 -121 223 -177 -420 -901 -396 -236 479 -246 166 264 710 -324 229 -688 412 179 -68 645 1081 635 847 916 1087 1009 306 739 187 445 408 1029 1283 1116 628 826 588 430 1159 1039 703 588 334 13 -96 22 -727 -135 -212 -171 -144 -1110 -1469 -323 166 -287 -134 316 345 40 -28 -479 -50 -58 -355 76 364 163 -451 -351 -1065 -579 -133 -762 -1183 -505 -1303 -667 -314 28 -20 -470 290 -119 493 597 443 409 -244 179 679 788 746 624 851 225 1274 443 391 173 -218 10 -59 -925 -238 138 1077 -615 -444 116 -414 -629 SS 20240616T102949.6Z 8933.437380 112 1 48.45 2 78.91 68.47 138.56 314.56 0.00 1 0.00 1 0 17 4.886e-01 6.361e-03 5.014e-02 1.119e-03 7.250483e-01 6.028585e-04 8.077323e-03 -6.000000e+00 2.845586e-01 232.61 -2.00 3.52 -2.00 321.01 0.00e+00 2.867147e-03 2.792345e-04 6.450598e-04 -6.000000e+00 1.241887e-02 283.82 -2.00 20.00 -2.00 320.43 0.00e+00 5.016 0.002 302.00 328.00 3 4.7216e-01 1.9885e-03 6.1633e-02 -6.0000e+00 7.1500e-01 1.0562e-01 2.7323e-03 3.9648e-02 -6.0000e+00 7.7402e-01 -1.0181e-01 2.7951e-03 2.0588e-02 -6.0000e+00 4.5969e-01 2.9519e-02 1.3377e-03 7.5160e-03 -6.0000e+00 1.9200e-01 1.2995e-03 -6.4393e-04 2.9732e-05 7.9180e-05 -6.0000e+00 1.3344e-02 1.0600e-02 0.0000e+00 10 0 0 10 0 0 47.38 22.81 0.31 0.01060 0.00576 379 91 1 5 0 127.810 26.00 19.99 22.81 16.80 31.5 959.03 -172592 -148246 -154664 -184757 -153771 -186313 -174093 -165447 -124576 -119876 -132515 -110002 -108845 -75430 -62580 -42776 -57179 -40560 -36599 -23909 -27987 -25640 -16946 -39021 -19438 -24762 -27499 -33869 -26956 -32638 -17030 -14990 -6044 1639 -11739 -7425 -13777 -5683 -6300 -493 -3076 509 1598 1127 380 136 -466 626 2150 -1018 3022 3534 2977 3764 2826 4051 2026 2234 801 1731 976 2615 3297 3696 2786 990 1498 350 1576 1778 1412 1095 1097 86 -59 -756 -407 -806 -621 -217 -867 -761 -1824 -1747 -847 -719 -256 79 619 415 370 -55 -24 198 109 -206 318 738 -31 -158 -185 -856 -384 64 -1046 -984 -818 -833 -492 194 128 48 65 47 -3 306 523 242 206 -195 -216 289 331 331 280 440 364 997 271 46 81 -182 -107 -97 -326 -123 68 282 -212 -53 73 -194 -147 -1092 -906 -1131 -1855 -1057 -1728 -1539 -1535 -884 -903 -1215 -912 -1140 -749 -710 -495 -892 -606 -583 -360 -458 -414 -263 -830 -373 -538 -636 -824 -606 -841 -453 -481 -210 58 -471 -281 -607 -275 -380 -34 -251 44 144 106 37 14 -48 67 240 -127 407 537 505 633 515 766 406 448 159 333 194 563 809 1029 839 301 451 111 546 710 630 514 511 38 -24 -277 -139 -281 -243 -101 -481 -444 -1189 -1212 -622 -562 -210 66 515 333 278 -39 -17 140 87 -192 318 845 -39 -200 -219 -917 -372 67 -1097 -1090 -956 -1046 -678 279 205 76 104 77 -5 460 794 385 348 -318 -372 473 522 502 409 617 497 1428 445 79 155 -374 -217 -209 -755 -281 159 663 -497 -119 163 -404 -298 SS 20240616T103531.0Z 8933.441331 115 1 48.54 2 77.92 69.34 139.30 316.29 0.00 1 0.00 1 0 25 3.480e-01 5.619e-03 3.684e-02 8.531e-04 6.757394e-01 4.551739e-04 7.574018e-03 -6.000000e+00 2.027129e-01 232.61 -2.00 3.52 -2.00 320.74 0.00e+00 2.193017e-03 1.928019e-04 5.008618e-04 -6.000000e+00 8.846820e-03 283.83 -2.00 20.00 -2.00 320.12 0.00e+00 4.636 0.002 302.00 328.00 3 3.9723e-01 1.4413e-03 5.7041e-02 -6.0000e+00 5.0935e-01 7.7712e-02 1.9039e-03 3.6573e-02 -6.0000e+00 5.5139e-01 -6.3063e-02 1.8810e-03 1.8631e-02 -6.0000e+00 3.2747e-01 1.3062e-02 9.1952e-04 6.3029e-03 -6.0000e+00 1.3678e-01 2.0734e-03 -6.4686e-04 2.2970e-05 6.7365e-05 -6.0000e+00 9.5055e-03 1.0369e-02 0.0000e+00 10 0 0 10 0 0 16.50 22.81 0.31 0.01037 0.00551 492 118 1 5 0 98.450 26.00 20.00 22.81 17.36 31.5 961.99 -137700 -88877 -131796 -97959 -130882 -107783 -132920 -105385 -101273 -87713 -99209 -93463 -64882 -62446 -19812 -43993 -24805 -30329 -17354 -24713 -18443 -20898 -15667 -19560 -19939 -11435 -23810 -14166 -21134 -13345 -12584 -10521 -3381 -2212 -8013 -9361 -7724 -7561 -418 -1594 -1126 -713 182 279 -268 579 -2114 1385 -32 772 1068 3164 1772 2862 1393 2481 1691 394 1318 336 1156 1367 2982 2820 1758 430 1211 461 1111 1875 904 1208 149 626 -438 -232 -724 -901 -420 -784 -980 -1086 -1675 -1867 -562 -453 -64 28 527 517 552 490 -34 402 185 202 380 709 18 -103 -49 -740 -318 -112 -1020 -1271 -800 -752 -244 160 84 -17 -27 127 -15 447 395 384 175 -164 -290 243 263 169 472 360 320 957 421 42 50 -375 -124 -66 -194 -155 -21 328 -254 -36 31 -101 -138 -962 -466 -1184 -636 -1100 -699 -1194 -824 -876 -737 -999 -995 -653 -800 -213 -739 -398 -578 -321 -526 -385 -452 -336 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