File name: Pandora179s1_CornwallCT_20240626_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240627T161910.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240626_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240626T102416.2Z 8943.433521 198 1 49.70 2 80.27 67.31 59.84 205.33 0.00 1 0.00 1 0 17 6.035e-01 3.193e-02 2.103e-01 7.665e-03 8.149954e-01 4.424991e-03 8.979185e-03 -6.000000e+00 3.641315e-01 232.62 -2.00 3.52 -2.00 321.53 0.00e+00 3.068830e-03 2.289462e-03 7.249358e-04 -6.000000e+00 1.772885e-02 284.77 -2.00 20.00 -2.00 320.97 0.00e+00 5.648 0.003 302.00 328.00 3 3.3338e+00 1.5880e-02 6.9830e-02 -6.0000e+00 9.2645e-01 6.8016e-01 2.1993e-02 4.6003e-02 -6.0000e+00 1.0135e+00 -9.6347e-01 1.9494e-02 2.3275e-02 -6.0000e+00 5.9373e-01 4.1104e-01 8.8863e-03 8.4214e-03 -6.0000e+00 2.4435e-01 3.5006e-05 -1.4431e-03 2.1019e-04 9.7796e-05 -6.0000e+00 1.7370e-02 8.8233e-03 0.0000e+00 12 9 8 11 32 0 91.42 22.88 0.30 0.00882 -0.00202 15 4 1 5 0 3311.970 26.11 20.00 22.88 24.74 32.1 992.44 -109728 900000 -113233 900000 900000 -83476 -55968 -194382 900000 900000 -187589 -91772 -153697 -18188 900000 -25343 900000 900000 47910 900000 17282 900000 900000 19121 900000 243708 -43935 17591 -11175 21472 900000 -18354 183294 900000 113234 900000 -22017 79656 301492 157591 18621 39846 70745 106553 -21969 62074 18470 90567 48133 54662 33561 104799 35952 48095 31934 71460 28738 9404 40082 18709 -604 8961 37424 21612 15532 -2443 15378 6874 7240 9628 15704 12518 11514 -3668 -4517 -5072 12404 2413 3825 -839 -11690 717 273 -10804 1322 7337 -365 376 3334 -5005 4560 -2207 1412 3482 -2753 -1730 -4566 -1842 -2702 -3806 -1048 -3033 -806 -2737 819 860 -2175 -3941 -3892 1026 359 -1470 -2175 313 -610 247 -1436 2259 -92 -123 2599 717 2204 2640 -305 5649 1087 1166 1504 -21 1448 -28 588 2098 -2155 1491 344 784 -771 -136 -1086 -804 -3146 -2617 900000 -3376 900000 900000 -1466 -745 -10237 900000 900000 -10439 -2247 -7942 -329 900000 -729 900000 900000 842 900000 414 900000 900000 448 900000 1816 -2058 421 -339 492 900000 -889 1471 900000 1883 900000 -1301 2101 2247 2710 1338 2461 3314 3787 -2596 3172 1475 3894 3075 3492 2930 5407 3751 4813 3978 6201 3901 1527 4566 2530 -100 1455 5200 4004 3283 -614 3209 1621 1869 2788 4732 4058 3708 -1283 -1435 -1439 2747 603 1065 -294 -5414 339 134 -6313 728 4039 -227 238 2044 -3210 2481 -1207 777 1967 -1757 -1288 -4108 -1753 -2861 -4114 -1035 -2922 -686 -2348 725 806 -2225 -4158 -4561 1306 520 -2196 -3335 458 -916 355 -2119 3367 -140 -193 4122 1104 3207 3691 -422 7128 1399 1588 2343 -36 2702 -57 1196 4486 -5145 3597 809 1852 -1826 -320 -2396 -1643 -6332 SS 20240626T103210.2Z 8943.439007 203 1 47.21 2 78.91 68.53 60.45 207.37 0.00 1 0.00 1 0 17 5.797e-01 1.837e-02 2.886e-01 5.093e-03 7.345216e-01 2.786676e-03 8.141607e-03 -6.000000e+00 3.404420e-01 232.62 -2.00 3.52 -2.00 321.10 0.00e+00 5.452841e-03 1.324544e-03 6.831182e-04 -6.000000e+00 1.495014e-02 284.77 -2.00 20.00 -2.00 320.51 0.00e+00 5.013 0.002 302.00 328.00 3 3.3111e+00 9.3807e-03 6.2407e-02 -6.0000e+00 8.5677e-01 2.8731e-01 1.2928e-02 4.1684e-02 -6.0000e+00 9.2931e-01 -3.5847e-01 1.2669e-02 2.1265e-02 -6.0000e+00 5.5057e-01 1.4510e-01 5.9841e-03 1.0125e-02 -6.0000e+00 2.3012e-01 7.1755e-05 -7.4937e-04 1.3702e-04 9.2681e-05 -6.0000e+00 1.5951e-02 8.0021e-03 0.0000e+00 12 8 8 10 0 0 62.87 22.88 0.41 0.00800 0.00237 19 5 1 5 0 2484.540 26.11 19.98 22.88 24.95 32.3 993.64 -57854 900000 -138809 -136083 40306 -44269 -156347 -245536 -98484 -12836 -211720 -83999 -181302 9510 900000 25446 133629 -18572 -23912 69382 219990 171953 900000 -74747 285463 -4274 -43350 -23553 -38718 -36293 74446 -21176 8310 900000 1712 81110 -37029 53603 22738 49377 -4119 11440 17767 21368 -10836 2227 -341 15689 29221 4299 12528 31357 2018 15417 9596 21560 3759 2420 11541 11159 -4688 5451 8824 10026 5188 -5474 6091 -760 3977 2527 5840 2630 2051 -2515 -3002 -2753 -2088 2948 -3162 411 -6599 1141 -2396 -4863 11 2684 408 282 1917 -3594 3403 -2416 1529 1804 -365 -1678 -2185 417 -938 -70 -955 -709 -950 -1363 -1673 1063 554 -1151 -1413 -499 876 -510 79 275 -166 -242 58 315 -91 -970 771 -119 842 1303 -716 3779 -312 1418 426 123 747 -86 421 304 -775 326 -21 294 222 154 -605 -598 -1262 -287 900000 -1749 -1662 200 -220 -2089 -8811 -902 -64 -6789 -834 -6022 62 900000 223 663 -326 -484 583 1092 853 900000 -2939 1417 -93 -1423 -620 -1168 -1150 1016 -849 292 900000 69 1543 -2276 1685 1094 2187 -354 908 1397 1672 -1187 219 -35 1443 2477 502 1502 3507 334 2431 1707 3539 758 492 2075 1968 -993 1145 2048 2618 1523 -1772 1739 -241 1321 981 2432 1099 853 -1030 -1209 -989 -694 948 -1217 182 -3446 634 -1523 -3368 8 1957 320 228 1518 -2896 2385 -1680 987 1205 -281 -1428 -2182 468 -1094 -81 -1120 -744 -908 -1304 -1719 1124 622 -1415 -1800 -711 1374 -812 126 424 -260 -366 88 499 -144 -1602 1232 -195 1312 1949 -1050 5100 -427 2008 692 215 1423 -166 857 661 -1725 753 -51 701 525 347 -1353 -1253 -2579 SS 20240626T103755.2Z 8943.443000 206 1 38.85 2 77.91 69.41 60.91 208.84 0.00 1 0.00 1 0 17 4.726e-01 1.316e-02 2.078e-01 4.600e-03 6.860377e-01 2.483959e-03 7.636862e-03 -6.000000e+00 2.757043e-01 232.62 -2.00 3.52 -2.00 320.85 0.00e+00 4.365645e-03 1.083232e-03 6.535000e-04 -6.000000e+00 1.248206e-02 284.77 -2.00 20.00 -2.00 320.23 0.00e+00 4.630 0.002 302.00 328.00 3 3.3642e+00 8.0045e-03 5.7718e-02 -6.0000e+00 6.9390e-01 1.7223e-01 1.0749e-02 3.8323e-02 -6.0000e+00 7.5159e-01 -1.9219e-01 1.0489e-02 1.9341e-02 -6.0000e+00 4.4577e-01 7.2088e-02 5.0717e-03 8.6617e-03 -6.0000e+00 1.8735e-01 1.0274e-04 -7.7869e-04 1.2539e-04 7.6561e-05 -6.0000e+00 1.2955e-02 8.5287e-03 0.0000e+00 12 9 9 12 1 1 95.16 22.87 0.40 0.00853 0.00268 17 5 1 5 0 2157.900 26.11 20.01 22.87 25.04 32.2 993.89 -165848 900000 -171501 220246 -97042 -48944 -145682 -191980 -58448 900000 -178975 -72680 -167651 -82854 900000 -51810 99498 -26342 19335 18393 5088 53608 125863 -33409 25272 18043 -51075 -15689 -48565 14148 39827 -5696 9514 13838 13283 18659 -19185 -2458 21950 14641 -3459 144 19835 21285 -14476 3792 -5433 11840 4730 -627 3485 23960 1537 4400 610 12124 939 -1728 3881 873 -225 -60 7306 5311 4256 -4414 3301 1075 -269 2458 2926 2930 2937 -812 -2840 -269 -2186 -79 -2415 -505 -4411 -931 -1828 -4524 -288 1125 525 36 1393 -1354 1441 -371 303 1651 -27 293 -1222 797 -396 -159 -267 -957 -332 -1084 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