File name: Pandora179s1_CornwallCT_20240705_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240706T050543.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240705_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240705T152947.1Z 8952.645684 293 1 2.85 2 26.55 129.24 20.70 126.78 0.00 1 0.00 1 0 17 8.326e-03 6.628e-03 2.665e-03 1.977e-03 1.586908e-01 1.034605e-03 1.926448e-03 -6.000000e+00 4.852676e-03 232.64 -2.00 3.52 -2.00 314.47 0.00e+00 1.889436e-04 8.055866e-05 1.418375e-05 -6.000000e+00 2.133110e-04 285.64 -2.00 20.00 -2.00 313.88 0.00e+00 1.118 0.000 302.00 328.00 3 3.4153e+00 2.6693e-03 1.3527e-02 -6.0000e+00 1.2187e-02 4.2392e-02 2.9510e-03 8.3062e-03 -6.0000e+00 1.3185e-02 -4.8920e-03 1.6859e-03 4.0306e-03 -6.0000e+00 7.8392e-03 -1.8562e-03 7.2394e-04 1.1039e-03 -6.0000e+00 3.2824e-03 5.1934e-03 -2.2536e-04 5.5648e-05 1.5264e-05 -6.0000e+00 2.2738e-04 5.9947e-03 0.0000e+00 12 9 1 12 1 1 99.93 22.86 0.32 0.00599 0.00430 7 33 1 5 0 356.000 26.11 20.01 22.86 32.20 32.9 1031.29 853 -458 -442 -1047 -2869 -471 -1878 1292 824 495 -2224 -1062 -1022 -962 732 19 130 88 486 632 915 112 1253 110 645 1382 333 -137 -540 1560 1436 1634 1798 815 -1797 -1746 -1475 -973 -80 -69 -1119 -972 -476 -1110 -132 -695 -631 -858 -708 -491 357 776 669 1396 395 767 557 193 467 791 1166 912 1638 987 212 -424 -143 -656 348 844 43 352 -340 185 52 38 -286 -494 -208 -842 -1147 -1003 -1986 -1519 -662 -739 -336 -170 520 60 566 392 490 723 907 321 366 784 -76 -240 -424 -687 -361 53 -507 -1185 -706 -769 -183 -170 356 -86 284 110 329 310 439 542 407 -100 -483 255 -11 411 621 853 479 880 903 565 293 -340 -180 341 -13 -578 -100 210 -230 -195 -393 -446 -492 331 -181 -179 -403 -1071 -158 -650 477 340 200 -907 -454 -429 -448 373 10 69 47 267 356 523 64 707 65 396 870 198 -82 -299 863 806 891 1036 488 -1037 -959 -859 -603 -58 -55 -930 -840 -419 -990 -116 -608 -537 -702 -590 -400 297 640 578 1249 346 677 500 173 434 728 1035 862 1650 998 214 -416 -135 -590 322 822 44 376 -368 193 54 36 -253 -432 -184 -779 -1119 -1014 -2154 -1712 -751 -858 -410 -215 655 74 668 441 525 733 950 348 415 926 -95 -297 -518 -779 -409 62 -614 -1458 -903 -977 -240 -235 486 -118 387 144 414 364 511 659 508 -135 -641 335 -14 526 787 1023 574 1046 1073 712 367 -435 -232 454 -18 -822 -139 298 -331 -274 -560 -616 -668 SS 20240705T162722.6Z 8952.685678 330 1 4.60 2 20.18 159.15 14.57 163.52 0.00 1 0.00 1 0 17 8.238e-03 6.648e-03 2.224e-03 1.660e-03 1.485747e-01 8.683742e-04 1.801353e-03 -6.000000e+00 4.801854e-03 232.64 -2.00 3.52 -2.00 314.44 0.00e+00 1.951108e-04 6.715820e-05 1.586947e-05 -6.000000e+00 2.110741e-04 285.64 -2.00 20.00 -2.00 313.85 0.00e+00 1.065 0.000 302.00 328.00 3 3.6486e+00 2.2368e-03 1.2798e-02 -6.0000e+00 1.2059e-02 2.7110e-02 2.4719e-03 7.7740e-03 -6.0000e+00 1.3047e-02 -8.7033e-04 1.4132e-03 3.7710e-03 -6.0000e+00 7.7569e-03 -2.6819e-03 6.0542e-04 1.0362e-03 -6.0000e+00 3.2482e-03 4.4325e-03 -2.1682e-04 4.7032e-05 1.4093e-05 -6.0000e+00 2.2499e-04 5.5032e-03 0.0000e+00 12 9 1 12 1 1 99.95 22.86 0.34 0.00550 0.00387 12 33 1 5 0 353.800 26.11 20.01 22.86 33.70 32.7 1038.38 1092 -226 79 -1941 -2007 -1902 -539 1220 1194 678 -1792 -1162 -654 -109 353 646 -488 615 473 819 899 -279 1046 333 459 735 772 -260 -388 223 1747 1309 1851 164 -2455 -1532 -2000 -949 -209 -471 -994 -676 -982 -834 -630 -559 -434 -410 -690 -410 1244 455 1012 964 576 1027 868 753 359 728 858 1210 1102 1265 -8 -684 -96 -664 568 656 -74 297 61 295 255 -234 -168 -511 348 -369 -1327 -995 -2034 -1780 -975 -840 -310 -112 239 -51 373 321 359 864 905 421 566 808 -26 -218 28 -523 -258 346 -965 -1054 -582 -541 -306 222 -8 -25 -82 150 269 458 401 314 371 83 -568 33 -4 294 744 826 719 1189 580 224 215 -463 -32 -78 -117 -251 79 100 -317 -179 120 -497 -551 419 -96 34 -806 -733 -637 -181 443 482 291 -775 -488 -290 -49 176 346 -272 343 271 479 497 -155 615 190 273 449 471 -151 -222 120 937 738 1096 101 -1465 -862 -1201 -600 -145 -359 -834 -589 -877 -749 -561 -493 -372 -337 -545 -336 1033 377 874 868 534 901 774 671 335 671 762 1138 1113 1267 -8 -670 -90 -594 521 634 -75 313 65 304 261 -217 -148 -447 305 -337 -1282 -1048 -2172 -1979 -1089 -1006 -372 -138 296 -61 433 357 381 863 933 448 661 979 -32 -276 33 -610 -287 396 -1151 -1334 -726 -702 -412 297 -12 -34 -109 192 330 553 480 373 473 109 -771 44 -6 386 921 1022 844 1381 713 277 275 -607 -42 -102 -160 -344 111 144 -462 -255 165 -701 -765 SS 20240705T164844.0Z 8952.700510 346 1 19.09 2 19.23 173.53 14.09 182.12 0.00 1 0.00 1 0 17 8.405e-03 6.420e-03 1.239e-03 8.947e-04 1.480011e-01 4.665936e-04 1.797827e-03 -6.000000e+00 4.899648e-03 232.64 -2.00 3.52 -2.00 314.64 0.00e+00 2.278556e-04 3.758863e-05 1.422485e-05 -6.000000e+00 2.153662e-04 285.64 -2.00 20.00 -2.00 314.03 0.00e+00 1.059 0.000 302.00 328.00 3 3.8429e+00 1.2046e-03 1.2742e-02 -6.0000e+00 1.2305e-02 1.9793e-02 1.3326e-03 7.7608e-03 -6.0000e+00 1.3312e-02 -3.8071e-04 7.6085e-04 3.7639e-03 -6.0000e+00 7.9147e-03 -2.1848e-03 3.2783e-04 1.0356e-03 -6.0000e+00 3.3147e-03 3.6823e-03 -1.4610e-04 2.5312e-05 1.4233e-05 -6.0000e+00 2.2955e-04 4.7670e-03 0.0000e+00 12 9 1 12 1 1 99.99 22.86 0.25 0.00477 0.00367 63 39 1 5 0 298.160 26.00 20.01 22.86 35.07 32.8 1046.64 619 -267 95 -1737 -3395 -1601 -1354 1048 1156 679 -1932 -967 -751 -220 678 57 -329 339 620 968 971 170 1266 856 592 1040 375 -10 -281 1199 1320 1339 2195 696 -2069 -1485 -1771 -1357 -263 -412 -1069 -1017 -896 -1075 -540 -472 -751 -621 -585 -194 674 692 516 1156 448 943 738 461 473 549 761 1026 1252 1119 342 -567 -53 -662 823 787 84 347 -80 431 -11 -3 -194 -574 174 -566 -1117 -1187 -1851 -1669 -754 -715 -385 -209 284 115 298 423 226 784 726 313 539 733 -48 -366 -179 -670 -106 220 -549 -970 -624 -901 -189 175 268 -15 33 231 110 462 388 298 258 -52 -389 133 142 286 700 826 516 1213 571 369 110 -348 -38 94 4 -136 -173 133 -403 -157 -33 -481 -518 214 -101 37 -646 -1231 -523 -449 373 457 261 -750 -396 -298 -97 327 30 -178 184 344 507 518 91 722 469 339 612 222 -6 -156 622 691 733 1259 417 -1196 -812 -1032 -833 -190 -322 -860 -851 -766 -928 -460 -399 -619 -525 -474 -153 542 588 429 996 399 844 671 420 423 487 690 985 1207 1137 347 -566 -48 -569 723 775 86 370 -86 450 -10 -3 -176 -485 148 -498 -1099 -1200 -2001 -1881 -846 -863 -462 -260 353 138 350 477 230 802 767 338 602 897 -59 -469 -215 -797 -120 256 -659 -1239 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