File name: Pandora179s1_CornwallCT_20240707_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240708T050917.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240707_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240707T104307.7Z 8954.446617 83 1 46.95 2 77.89 70.54 91.22 56.88 0.00 1 0.00 1 0 17 5.106e-01 2.805e-02 1.902e-01 7.945e-03 6.153111e-01 4.257756e-03 7.464597e-03 -6.000000e+00 2.991916e-01 232.64 -2.00 3.52 -2.00 320.73 0.00e+00 9.401444e-03 1.692680e-03 2.725531e-03 -6.000000e+00 1.322515e-02 285.81 -2.00 20.00 -2.00 320.07 0.00e+00 4.625 0.002 302.00 328.00 3 4.3429e+00 1.3463e-02 5.5197e-02 -6.0000e+00 7.5197e-01 4.2489e-01 1.6800e-02 3.3578e-02 -6.0000e+00 8.1452e-01 -5.4870e-01 1.3421e-02 2.0416e-02 -6.0000e+00 4.8457e-01 2.4125e-01 6.5656e-03 9.9631e-03 -6.0000e+00 2.0313e-01 3.9525e-05 -1.5340e-03 2.2293e-04 1.3140e-04 -6.0000e+00 1.3987e-02 1.1956e-02 0.0000e+00 12 8 8 10 0 0 99.80 22.86 0.18 0.01196 0.00043 15 4 1 5 0 3129.890 26.11 19.98 22.86 26.34 32.6 994.31 -42344 900000 -122493 201943 -15254 -60214 -112369 -132273 -58336 3879 -140621 -93896 -102731 -70774 -43833 -9907 900000 -14095 7312 114160 28837 149932 900000 -12557 64224 184572 -23484 24322 -21673 -9713 72583 -8184 53828 304484 46753 73466 -20925 20712 63883 65675 -1122 38901 24212 37687 3533 10925 1390 23666 19908 14195 23229 53441 6756 13519 7338 36668 10811 -2458 20208 3431 2537 -3441 9586 11792 6921 -7674 7278 2635 -4936 920 3408 1042 57 -3820 -6461 -2019 1333 -4789 -2108 -5940 2159 -1357 1321 815 -1123 1788 -1582 -1328 515 -3884 1018 -5722 1505 2529 -1597 108 -3997 242 -587 -1959 -1103 -2780 46 -3025 -1466 1289 2538 -2841 -2474 -1437 1556 -1175 -1128 959 932 2059 -2764 2419 365 562 1555 -555 2227 2383 55 5512 -6 1501 1903 872 876 -1500 444 145 -1579 1374 -340 453 -495 631 -1607 -592 -1668 -959 900000 -7182 1564 -282 -1578 -4886 -6804 -1633 60 -8556 -4083 -5936 -3794 -2246 -431 900000 -772 344 1904 1134 1838 900000 -726 1760 1668 -1567 971 -1330 -555 2119 -634 2565 2358 2451 2801 -2156 1604 3805 4499 -166 4102 3087 4310 574 1679 238 3313 2977 2351 3819 7163 1561 3125 1884 7165 2769 -710 4502 887 680 -1068 2947 3969 2577 -3218 2545 976 -2132 397 1582 517 28 -1855 -3167 -847 499 -1900 -899 -3103 1127 -835 865 567 -848 1397 -1344 -1159 442 -3358 780 -4358 1014 1715 -1252 96 -4289 266 -709 -2402 -1258 -3119 45 -3124 -1601 1451 2974 -3509 -3320 -2126 2461 -1885 -1924 1540 1408 2946 -4175 3636 594 953 2595 -913 3434 3529 80 7273 -8 2073 2930 1518 1556 -2891 876 303 -3586 3172 -767 1026 -1125 1441 -3529 -1210 -3342 SS 20240707T110641.6Z 8954.462982 92 1 48.85 2 73.71 74.13 87.64 60.66 0.00 1 0.00 1 0 17 7.116e-02 5.216e-03 1.097e-02 7.320e-04 4.690656e-01 3.781020e-04 5.422754e-03 -6.000000e+00 4.145913e-02 232.64 -2.00 3.52 -2.00 319.50 0.00e+00 1.304914e-03 1.048356e-04 1.976388e-04 -6.000000e+00 1.824058e-03 285.81 -2.00 20.00 -2.00 318.74 0.00e+00 3.507 0.001 302.00 328.00 3 1.4588e+00 1.0794e-03 4.1575e-02 -6.0000e+00 1.0411e-01 1.7981e-02 1.2720e-03 2.4952e-02 -6.0000e+00 1.1265e-01 -2.2061e-02 9.9375e-04 1.2125e-02 -6.0000e+00 6.6983e-02 1.5197e-03 5.1843e-04 3.5934e-03 -6.0000e+00 2.8038e-02 2.5597e-03 -5.5363e-04 2.0911e-05 3.7441e-05 -6.0000e+00 1.9434e-03 8.9416e-03 0.0000e+00 10 0 0 10 0 0 99.98 22.87 0.29 0.00894 0.00478 381 91 1 5 0 127.200 26.11 20.00 22.87 27.37 32.9 1002.71 -17596 -15377 -23351 -26050 -29031 -33809 -26846 -27062 -16773 -12956 -18610 -17690 -15657 -9218 -5558 -4121 -5725 -3427 -2911 922 -1084 -1190 1509 -2211 -29 -1717 -2356 -4869 -4070 -2631 -170 405 1589 1821 -2122 -1880 -3029 -1723 -623 33 -1527 -766 -511 -288 368 132 -461 14 -366 -413 1002 683 1146 1080 587 1008 766 394 207 519 529 1305 1743 1847 1065 209 555 -150 878 1120 453 344 94 227 -319 -421 -464 -935 -193 -674 -1012 -863 -1956 -1686 -735 -632 -166 108 607 582 632 462 368 670 699 145 474 719 -70 -291 -293 -756 -369 31 -745 -1062 -795 -830 -380 203 148 -58 110 201 172 489 429 223 229 -223 -521 98 156 214 485 477 356 1134 476 194 159 -250 -159 41 -151 -163 -79 277 -282 -104 9 -219 -196 -281 -282 -502 -569 -597 -695 -544 -622 -396 -322 -506 -506 -518 -350 -247 -212 -331 -210 -191 61 -76 -84 107 -175 -2 -155 -219 -449 -356 -231 -16 44 194 239 -280 -241 -425 -280 -111 7 -371 -198 -138 -79 102 37 -131 4 -106 -124 322 243 440 446 257 455 357 185 95 235 246 598 886 1033 622 118 298 -81 508 739 307 246 67 168 -219 -261 -264 -522 -115 -466 -747 -717 -1785 -1623 -696 -640 -176 119 663 614 619 451 338 611 692 152 562 895 -94 -392 -370 -935 -423 36 -880 -1333 -1046 -1157 -531 308 244 -93 172 319 254 684 603 329 359 -369 -872 159 246 323 697 700 502 1634 710 320 265 -436 -288 73 -289 -328 -164 549 -563 -210 16 -403 -374 SS 20240707T111325.0Z 8954.467651 96 1 49.03 2 72.50 75.15 86.59 61.72 0.00 1 0.00 1 0 25 4.639e-02 5.308e-03 6.143e-03 5.369e-04 4.416572e-01 2.760016e-04 5.122520e-03 -6.000000e+00 2.703100e-02 232.64 -2.00 3.52 -2.00 319.13 0.00e+00 9.343432e-04 6.826780e-05 1.944631e-04 -6.000000e+00 1.189255e-03 285.81 -2.00 20.00 -2.00 318.36 0.00e+00 3.279 0.001 302.00 328.00 3 1.1564e+00 7.7251e-04 3.8943e-02 -6.0000e+00 6.7880e-02 1.7719e-02 8.9648e-04 2.3386e-02 -6.0000e+00 7.3449e-02 -2.2298e-02 6.6049e-04 1.1382e-02 -6.0000e+00 4.3672e-02 1.7264e-03 3.4637e-04 3.2412e-03 -6.0000e+00 1.8281e-02 4.4032e-03 -5.3039e-04 1.5339e-05 3.3225e-05 -6.0000e+00 1.2670e-03 8.6429e-03 0.0000e+00 10 0 0 10 0 0 99.85 22.87 0.28 0.00864 0.00466 503 120 1 5 0 96.310 26.11 19.99 22.87 28.16 33.0 1007.13 -10440 -13290 -11128 -16735 -17670 -19282 -19774 -12694 -12963 -8179 -18392 -10783 -12325 -5612 -3352 -2372 -2056 -2048 941 -41 927 -2029 1521 -1465 192 -767 -513 -1748 -3145 -983 110 833 1045 1137 -3452 -1473 -3737 -1286 -730 -120 -966 -940 -265 -703 -104 -223 -438 -438 -299 -256 1230 884 615 1582 724 1135 592 269 80 574 652 1178 1797 1741 999 186 365 -406 1057 971 481 527 187 348 -106 -243 -568 -674 -351 -493 -1162 -999 -1981 -1547 -787 -659 -112 -28 480 340 681 520 337 640 644 375 470 700 -123 -319 -333 -724 -363 50 -816 -1139 -832 -715 -310 158 103 -4 65 151 144 434 575 320 193 -204 -472 134 103 259 518 539 401 1171 457 196 113 -226 -80 34 -171 -202 -42 226 -243 -205 30 -295 -210 -226 -344 -304 -476 -462 -487 -529 -358 -417 -273 -701 -401 -543 -281 -197 -161 -153 -164 78 -4 84 -190 141 -151 21 -89 -61 -202 -351 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