File name: Pandora179s1_CornwallCT_20240722_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240723T050914.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240722_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240722T150618.2Z 8969.629377 5 1 48.40 2 32.34 123.50 136.11 285.23 0.00 1 0.00 1 0 17 8.126e-03 6.216e-03 3.130e-04 2.170e-04 1.702526e-01 1.126436e-04 2.065095e-03 -6.000000e+00 4.730109e-03 232.37 -2.00 3.52 -2.00 314.89 0.00e+00 2.114464e-04 9.506696e-06 1.732250e-05 -6.000000e+00 2.090520e-04 286.66 -2.00 20.00 -2.00 314.24 0.00e+00 1.183 0.000 302.00 328.00 3 1.8791e+00 2.9138e-04 1.4396e-02 -6.0000e+00 1.1867e-02 9.0439e-03 3.2277e-04 8.9053e-03 -6.0000e+00 1.2841e-02 -3.3713e-03 1.8413e-04 4.3237e-03 -6.0000e+00 7.6409e-03 -2.0172e-03 8.0029e-05 1.1867e-03 -6.0000e+00 3.2029e-03 2.2391e-02 -1.7789e-04 6.1506e-06 1.5743e-05 -6.0000e+00 2.2192e-04 8.8021e-03 0.0000e+00 10 0 0 10 0 0 99.93 22.78 0.31 0.00880 0.00747 710 170 1 5 0 68.150 25.90 19.99 22.78 33.26 33.5 1021.16 406 -359 -11 -1973 -3047 -1772 -934 670 1168 431 -1708 -1315 -363 -431 480 284 -329 450 526 988 936 208 1165 865 640 878 509 -237 -97 688 1440 1326 2015 199 -2254 -1508 -1773 -1219 -239 -430 -964 -866 -728 -897 -515 -363 -764 -571 -672 -196 789 636 809 1030 504 781 845 447 447 497 804 1124 1301 1281 221 -431 -113 -609 672 769 79 217 -46 348 -12 -143 -151 -564 -4 -507 -1020 -1190 -2008 -1603 -871 -792 -426 -188 218 142 272 417 172 745 732 333 608 690 -2 -217 -117 -623 -295 146 -580 -949 -633 -644 -275 212 103 37 76 118 125 460 430 251 315 -112 -395 95 150 258 716 680 586 1250 626 343 188 -164 -59 84 -91 -199 -97 97 -383 -247 -144 -489 -423 133 -130 -4 -700 -963 -556 -298 212 410 161 -643 -485 -142 -174 214 138 -166 229 274 527 474 105 629 453 351 496 289 -128 -51 345 731 710 1137 109 -1284 -815 -952 -748 -161 -318 -786 -692 -595 -740 -420 -294 -605 -462 -523 -149 615 526 660 876 442 693 760 402 395 436 723 1011 1258 1306 226 -406 -103 -529 601 729 78 225 -48 351 -12 -137 -129 -481 -3 -459 -979 -1254 -2149 -1786 -979 -955 -515 -234 272 171 318 464 183 751 767 362 690 861 -3 -270 -143 -708 -336 171 -709 -1174 -815 -863 -366 296 143 52 106 158 160 550 512 313 402 -148 -536 127 205 337 926 835 720 1523 769 447 243 -216 -79 116 -127 -293 -140 144 -573 -362 -212 -703 -597 SS 20240722T151126.1Z 8969.632941 8 1 48.42 2 31.55 125.22 136.97 286.33 0.00 1 0.00 1 0 17 8.111e-03 6.243e-03 3.696e-04 2.600e-04 1.686294e-01 1.357049e-04 2.049390e-03 -6.000000e+00 4.721485e-03 232.37 -2.00 3.52 -2.00 314.79 0.00e+00 2.258787e-04 1.116779e-05 1.654507e-05 -6.000000e+00 2.086696e-04 286.66 -2.00 20.00 -2.00 314.14 0.00e+00 1.173 0.000 302.00 328.00 3 2.2631e+00 3.5079e-04 1.4271e-02 -6.0000e+00 1.1845e-02 8.2585e-03 3.8872e-04 8.8285e-03 -6.0000e+00 1.2818e-02 -2.7991e-03 2.2178e-04 4.2873e-03 -6.0000e+00 7.6270e-03 -2.2839e-03 9.5677e-05 1.1787e-03 -6.0000e+00 3.1972e-03 1.5448e-02 -1.7585e-04 7.3743e-06 1.5810e-05 -6.0000e+00 2.2151e-04 8.6763e-03 0.0000e+00 10 0 0 10 0 0 99.70 22.81 0.32 0.00868 0.00735 435 104 1 5 0 111.290 26.00 19.98 22.81 33.35 33.4 1022.37 422 -302 103 -1954 -2981 -1769 -864 633 1214 431 -1697 -1172 -382 -429 579 300 -285 412 472 989 911 171 1149 860 621 974 431 -191 -189 712 1512 1298 2022 308 -2193 -1469 -1792 -1133 -230 -419 -1059 -922 -748 -913 -541 -314 -827 -598 -712 -187 735 629 780 1057 507 845 819 494 479 565 760 1188 1334 1279 244 -463 -90 -599 713 710 90 220 -34 353 -13 -94 -169 -559 -1 -472 -1029 -1192 -1997 -1655 -886 -791 -411 -173 214 143 331 409 251 740 746 335 605 690 -27 -241 -116 -634 -283 155 -578 -945 -648 -668 -283 213 100 7 60 130 89 433 434 233 333 -82 -363 80 176 276 748 651 580 1235 559 368 187 -162 -86 92 -75 -186 -100 106 -408 -231 -150 -456 -437 145 -114 40 -725 -984 -532 -264 210 445 169 -667 -450 -156 -180 269 152 -139 203 238 511 480 90 600 468 355 572 255 -107 -97 371 797 670 1101 175 -1204 -765 -999 -721 -161 -322 -844 -765 -635 -782 -459 -263 -680 -472 -575 -148 594 508 660 931 436 732 721 435 415 514 668 1107 1265 1279 245 -452 -80 -538 660 696 92 236 -35 369 -13 -88 -150 -464 -1 -442 -1020 -1229 -2098 -1810 -1028 -939 -513 -213 263 178 380 447 262 770 764 376 710 846 -33 -295 -139 -744 -316 179 -694 -1206 -822 -883 -372 293 144 9 82 172 112 535 533 286 419 -112 -486 111 237 356 951 786 698 1475 675 471 249 -211 -113 125 -103 -270 -143 155 -603 -333 -219 -646 -610 SS 20240722T151633.9Z 8969.636504 11 1 48.89 2 30.78 127.01 137.83 287.46 0.00 1 0.00 1 0 17 8.122e-03 6.292e-03 2.361e-04 1.671e-04 1.679055e-01 8.700172e-05 2.037997e-03 -6.000000e+00 4.727962e-03 232.37 -2.00 3.52 -2.00 314.78 0.00e+00 2.202803e-04 7.162480e-06 1.649196e-05 -6.000000e+00 2.089557e-04 286.66 -2.00 20.00 -2.00 314.13 0.00e+00 1.163 0.000 302.00 328.00 3 1.3962e+00 2.2482e-04 1.4172e-02 -6.0000e+00 1.1861e-02 7.8832e-03 2.4886e-04 8.7783e-03 -6.0000e+00 1.2835e-02 -3.7329e-03 1.4208e-04 4.2632e-03 -6.0000e+00 7.6374e-03 -1.6298e-03 6.1433e-05 1.1720e-03 -6.0000e+00 3.2016e-03 3.7151e-02 -2.2294e-04 4.7500e-06 1.5730e-05 -6.0000e+00 2.2181e-04 8.6404e-03 0.0000e+00 10 0 0 10 0 0 98.56 22.82 0.32 0.00864 0.00697 1014 243 1 5 0 47.740 26.00 20.00 22.82 33.51 33.4 1023.25 443 -280 118 -1909 -3076 -1674 -991 644 1191 454 -1662 -1151 -449 -300 470 273 -307 467 572 945 926 124 1205 860 625 897 533 -153 -165 768 1477 1325 1977 254 -2288 -1462 -1769 -1131 -254 -397 -988 -939 -768 -954 -505 -418 -757 -602 -692 -166 755 625 828 1058 491 805 798 460 447 548 808 1146 1285 1284 199 -440 -93 -593 706 711 98 233 -18 343 15 -95 -158 -506 -45 -523 -1045 -1192 -2006 -1619 -845 -822 -411 -215 177 128 303 431 210 781 760 328 628 701 -17 -229 -109 -595 -275 162 -607 -944 -655 -682 -288 216 104 44 67 116 129 449 448 256 329 -97 -405 77 116 268 740 699 608 1259 657 336 213 -161 -73 102 -70 -218 -102 106 -365 -255 -147 -476 -442 156 -100 43 -729 -1047 -518 -311 220 449 182 -672 -455 -174 -129 224 132 -154 236 296 501 501 67 645 481 366 505 301 -88 -87 381 741 701 1103 148 -1288 -779 -1008 -687 -170 -293 -804 -797 -630 -789 -413 -340 -637 -486 -538 -126 587 515 715 899 431 713 717 414 395 481 725 1091 1245 1311 203 -416 -84 -514 629 674 103 243 -19 348 15 -90 -143 -429 -39 -472 -1001 -1254 -2149 -1806 -952 -995 -500 -270 222 156 355 481 223 785 795 356 715 837 -22 -286 -133 -678 -313 190 -744 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