File name: Pandora179s1_CornwallCT_20240919_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20240920T051002.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20240919_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20240919 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240919T112951.3Z 9028.479066 240 1 22.61 2 81.21 96.34 81.12 270.93 0.00 1 0.00 1 0 17 5.087e-01 2.571e-02 2.457e-01 8.950e-03 7.299882e-01 4.972951e-03 8.476626e-03 -6.000000e+00 2.984964e-01 228.37 -2.00 3.52 -2.00 321.40 0.00e+00 1.449976e-02 2.522662e-03 1.114848e-03 -6.000000e+00 1.407715e-02 283.95 -2.00 20.00 -2.00 320.84 0.00e+00 6.186 0.004 302.00 328.00 3 2.4728e+00 1.7357e-02 7.0494e-02 -6.0000e+00 7.4639e-01 5.2959e-01 2.3246e-02 4.2498e-02 -6.0000e+00 8.1536e-01 -7.2353e-01 2.1186e-02 2.3492e-02 -6.0000e+00 4.8251e-01 3.0988e-01 9.9444e-03 1.6835e-02 -6.0000e+00 2.0168e-01 5.7871e-05 -1.2496e-03 2.4952e-04 1.8999e-04 -6.0000e+00 1.4294e-02 9.5599e-03 0.0000e+00 12 9 9 12 1 1 -56.19 22.89 0.52 0.00956 0.00017 10 6 1 5 0 2054.960 26.11 20.00 22.89 21.00 33.6 946.18 -137620 900000 -159346 900000 -122128 -110193 -123288 -221629 900000 -36171 -152966 -150880 -42437 -121153 900000 -9126 900000 77733 -6814 900000 -14649 900000 900000 105728 86558 900000 -47871 49269 -37648 -28738 42663 11446 109456 900000 171063 42403 -21454 51155 39057 111380 19023 72502 52956 52046 186 58117 1176 76949 34819 24529 11198 58359 9612 27203 20045 35358 34215 -12240 28347 8022 3029 9695 16070 26705 8415 -1445 9092 8828 2911 10040 9061 4460 6359 1149 -1558 -3745 9451 -4693 4135 -5873 -708 85 -428 -8432 353 2640 -158 -1683 -558 -4114 1582 -2173 -704 2802 -3762 -3132 -3438 -988 -414 -1955 -416 -1656 684 -2954 -12 -381 800 -2690 -2509 -534 422 -812 -2116 1492 -685 1344 -931 1664 140 13 831 -1298 2669 1759 1520 3505 856 723 2327 935 980 247 176 281 -1327 1401 -478 590 -694 -185 -237 -944 -1848 -3277 900000 -6108 900000 -2766 -1984 -2434 -11842 900000 -338 -4264 -4469 -581 -4573 900000 -193 900000 871 -191 900000 -456 900000 900000 921 916 900000 -1936 736 -1335 -1019 903 406 1703 900000 1490 1266 -1268 1655 1677 2703 1290 3068 2867 2947 18 3255 120 3830 2773 2305 1324 4793 1400 3572 2956 4554 4492 -2513 3739 1273 522 1725 3080 5251 2131 -400 2235 2236 853 3136 3152 1577 2171 415 -523 -1149 2370 -1384 1266 -2390 -302 41 -231 -5220 213 1654 -107 -1191 -391 -2881 978 -1305 -402 1606 -2608 -2539 -3081 -1002 -459 -2220 -437 -1578 616 -2743 -10 -367 808 -3038 -3132 -698 611 -1273 -3394 2243 -1002 1857 -1333 2438 220 21 1328 -2032 3862 2481 2196 4795 1172 1046 3563 1652 1807 492 371 595 -3052 3285 -1164 1438 -1699 -429 -514 -2036 -3890 SS 20240919T114231.5Z 9028.487865 245 1 47.84 2 78.87 98.51 83.36 273.01 0.00 1 0.00 1 0 25 2.995e-01 6.499e-03 5.379e-02 1.512e-03 6.139396e-01 7.886290e-04 6.953326e-03 -6.000000e+00 1.717434e-01 228.37 -2.00 3.52 -2.00 320.60 0.00e+00 2.305284e-03 3.237415e-04 3.976245e-04 -6.000000e+00 7.616187e-03 283.95 -2.00 20.00 -2.00 319.97 0.00e+00 5.000 0.002 302.00 328.00 3 1.2888e+00 2.4761e-03 5.7067e-02 -6.0000e+00 4.2707e-01 6.2909e-02 3.2062e-03 3.2670e-02 -6.0000e+00 4.6379e-01 -5.7190e-02 3.0598e-03 1.6647e-02 -6.0000e+00 2.7644e-01 1.2936e-02 1.5138e-03 5.7161e-03 -6.0000e+00 1.1651e-01 6.8168e-04 -7.2461e-04 4.1760e-05 5.8307e-05 -6.0000e+00 8.1705e-03 1.0097e-02 0.0000e+00 11 8 0 10 0 0 73.83 22.90 0.38 0.01010 0.00465 163 39 1 5 0 293.460 26.11 20.00 22.90 21.79 33.9 951.62 -61646 -98193 -91304 -104018 -107462 -106530 -114012 -114503 -76167 -39334 -118982 -46103 -86067 -39673 -40594 -23463 -31117 -24901 -16975 -16987 -10713 -19338 13657 -24444 -2016 -14259 -17137 -19880 -16223 -12485 -10144 -9165 -6257 13872 -4909 -1258 -12791 -140 -5568 3689 126 -301 2816 1412 561 345 1249 -52 1562 -1621 2109 3648 530 3977 1507 3736 1637 314 619 1127 814 1796 3485 2134 2696 -53 1733 -201 1206 833 1289 663 287 62 -392 -496 -960 -622 -1097 -775 -1658 -749 -1886 -1657 -833 -172 0 -52 817 -179 826 295 537 145 342 -205 335 592 81 8 -391 -574 -631 41 -1135 -1059 -894 -848 -429 250 268 76 239 27 247 364 475 159 111 -361 -509 113 213 312 222 843 106 1181 402 336 190 -181 -143 -117 -261 -282 -46 218 -193 -141 171 -166 -163 -318 -883 -848 -1104 -1094 -1037 -1278 -1469 -764 -302 -2141 -442 -1523 -568 -742 -439 -720 -602 -416 -443 -273 -542 286 -818 -59 -503 -642 -751 -577 -451 -419 -449 -347 689 -288 -70 -866 -10 -510 373 15 -39 376 198 80 51 186 -8 249 -284 394 685 113 893 370 937 434 85 162 289 215 515 1114 778 1035 -21 644 -78 505 403 690 376 162 33 -194 -221 -399 -258 -506 -421 -974 -498 -1392 -1297 -692 -151 0 -46 773 -165 704 235 409 113 297 -191 357 718 100 10 -487 -647 -655 43 -1283 -1266 -1126 -1060 -583 377 414 123 388 42 388 549 719 252 175 -595 -834 178 346 489 333 1212 148 1713 660 576 357 -338 -279 -243 -546 -620 -104 495 -438 -308 372 -342 -329 SS 20240919T114809.9Z 9028.491781 248 1 48.12 2 77.84 99.48 84.35 273.93 0.00 1 0.00 1 0 25 2.165e-01 5.703e-03 4.831e-02 1.335e-03 5.718001e-01 6.926647e-04 6.516427e-03 -6.000000e+00 1.241775e-01 228.37 -2.00 3.52 -2.00 320.37 0.00e+00 1.658079e-03 2.602207e-04 3.231185e-04 -6.000000e+00 5.506757e-03 283.95 -2.00 20.00 -2.00 319.71 0.00e+00 4.606 0.002 302.00 328.00 3 1.4869e+00 2.1082e-03 5.2712e-02 -6.0000e+00 3.0879e-01 3.9477e-02 2.6638e-03 3.0239e-02 -6.0000e+00 3.3534e-01 -3.1155e-02 2.4578e-03 1.5128e-02 -6.0000e+00 1.9987e-01 3.7187e-03 1.2359e-03 4.8962e-03 -6.0000e+00 8.4244e-02 8.3436e-04 -6.6347e-04 3.7494e-05 5.2721e-05 -6.0000e+00 5.9074e-03 9.8993e-03 0.0000e+00 10 0 0 10 0 0 21.69 22.91 0.30 0.00990 0.00491 177 42 1 5 0 270.210 26.11 19.98 22.91 22.31 34.0 954.35 -98073 27631 -100617 -28433 -82737 -65219 -83124 -75266 -21433 -51554 -65120 -71258 -36283 -54549 4831 -23256 -8533 -16318 -12767 293 -8266 2810 -8323 -7219 -10607 964 -13731 -3959 -13227 -4832 -3174 -5059 2742 3025 243 -6835 -4694 -5704 -671 464 -1314 835 882 1198 -1851 1632 -2484 2281 -1528 983 995 3312 1199 2770 2282 1675 1840 -1096 1127 358 1265 370 2644 2107 1328 -72 856 32 563 1609 319 799 244 166 -457 -349 -225 -1515 -28 -1225 -881 -1328 -1692 -2163 -464 -517 -223 152 478 514 488 632 -85 840 226 385 457 642 66 -145 81 -797 -92 -319 -809 -1212 -429 -718 -339 233 211 84 59 85 -37 520 203 342 75 -184 -404 6 192 186 376 421 384 933 371 20 148 -315 -139 39 -348 -17 -91 330 -250 -42 -10 -136 -81 -1086 104 -1507 -207 -959 -612 -996 -951 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