File name: Pandora179s1_CornwallCT_20241028_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20241029T044435.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20241028_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20241028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241028T135725.6Z 9067.581547 245 1 48.70 2 66.32 137.07 38.44 179.19 0.00 1 0.00 1 0 17 2.676e-02 6.249e-03 7.650e-03 1.562e-03 3.412005e-01 7.765286e-04 4.094763e-03 -6.000000e+00 1.511041e-02 224.31 -2.00 3.52 -2.00 318.01 0.00e+00 6.128391e-04 1.361697e-04 9.705822e-05 -6.000000e+00 6.666285e-04 279.01 -2.00 20.00 -2.00 317.34 0.00e+00 2.471 0.000 302.00 328.00 3 4.1327e+00 2.0657e-03 2.8988e-02 -6.0000e+00 3.7287e-02 5.3724e-02 2.3481e-03 1.7358e-02 -6.0000e+00 4.0652e-02 -1.2297e-02 1.5107e-03 8.6323e-03 -6.0000e+00 2.4235e-02 -1.6967e-03 7.7700e-04 2.5149e-03 -6.0000e+00 1.0249e-02 5.3152e-04 -2.8169e-04 4.4801e-05 2.7535e-05 -6.0000e+00 7.2940e-04 1.2555e-02 0.0000e+00 10 0 0 10 0 0 99.98 22.73 0.33 0.01255 0.01044 57 14 1 5 0 854.220 25.90 20.01 22.73 13.06 33.1 919.73 -5361 9943 -10205 -4546 -10113 -2783 -12021 -8553 1265 1713 -9780 -8545 -3136 -6838 4245 -3030 -81 -2714 -161 2803 480 946 3334 1053 390 1023 -2227 -623 -2002 222 1277 -863 2906 2948 -1204 -2122 -3011 -3069 439 278 -404 -1181 -91 -23 -952 352 -1312 1192 -806 275 142 1704 598 1268 719 1638 1249 -181 967 178 970 222 2055 1569 517 -1160 -10 -555 263 1223 185 508 -197 365 -195 -643 -380 -967 66 -1191 -1308 -1183 -1961 -2093 -254 -337 -232 -41 524 140 324 474 -11 918 457 340 464 856 -26 -197 48 -1036 -263 -47 -752 -836 -290 -865 -314 322 293 181 65 160 9 320 113 288 9 -139 -461 37 183 412 435 905 323 1003 601 201 158 -134 -8 -5 -257 -180 30 275 -439 -139 -19 -233 -417 -327 591 -780 -317 -670 -161 -798 -614 93 134 -870 -773 -305 -811 527 -459 -13 -462 -28 495 89 174 609 209 83 227 -515 -135 -413 44 271 -207 739 724 -293 -550 -777 -921 154 115 -187 -538 -43 -11 -455 166 -625 592 -406 139 70 900 341 762 452 1047 818 -120 620 114 631 157 1448 1199 405 -867 -8 -408 190 991 167 445 -174 329 -164 -487 -280 -689 49 -947 -1182 -1108 -1989 -2233 -285 -379 -274 -50 634 163 373 499 -10 873 466 387 554 1134 -35 -260 63 -1255 -317 -54 -949 -1115 -380 -1197 -459 475 459 290 100 246 13 427 152 401 14 -208 -700 58 279 599 602 1261 432 1359 832 302 251 -209 -12 -9 -432 -317 54 503 -809 -246 -33 -401 -706 SS 20241028T140133.7Z 9067.584418 248 1 8.48 2 65.80 138.01 38.46 180.83 0.00 1 0.00 1 0 17 1.427e-02 5.791e-03 4.755e-03 1.240e-03 3.301886e-01 6.167458e-04 3.970164e-03 -6.000000e+00 8.055177e-03 224.31 -2.00 3.52 -2.00 317.54 0.00e+00 6.372814e-04 9.578181e-05 1.151765e-04 -6.000000e+00 3.553697e-04 279.01 -2.00 20.00 -2.00 316.88 0.00e+00 2.422 0.000 302.00 328.00 3 2.1693e+00 1.6263e-03 2.8243e-02 -6.0000e+00 1.9877e-02 2.5012e-02 1.8387e-03 1.6716e-02 -6.0000e+00 2.1671e-02 -8.5807e-03 1.1393e-03 8.3129e-03 -6.0000e+00 1.2919e-02 -1.4013e-03 5.7511e-04 2.4054e-03 -6.0000e+00 5.4637e-03 4.0841e-03 -3.5462e-04 3.5379e-05 2.6846e-05 -6.0000e+00 3.8883e-04 1.2495e-02 0.0000e+00 12 1 1 12 1 1 99.78 22.74 0.33 0.01249 0.00983 40 56 1 5 0 206.650 25.90 20.01 22.74 13.19 33.1 920.61 -1781 -2562 -2693 -5261 -2079 -4798 -3553 -3725 -1590 -2860 -6939 -4994 -4148 -1800 4 1310 -358 491 -709 1334 -9 -100 849 -438 443 571 -102 -913 -938 113 1075 884 1803 588 -2541 -2155 -2643 -1149 -610 285 -583 -30 -143 -485 -41 -137 -460 -267 -84 -29 1314 945 1024 1270 312 788 861 493 395 568 715 1402 1392 1655 317 -296 -12 -434 771 707 413 238 -36 305 -40 -250 -240 -885 -300 -788 -1074 -1263 -2270 -1793 -864 -731 -351 -133 137 195 272 356 117 619 640 305 597 589 -126 -256 -28 -801 -429 16 -858 -963 -757 -545 -229 395 347 185 103 178 119 238 596 174 290 -25 -164 222 131 260 592 547 506 1153 528 246 156 -241 -55 3 -225 -107 -12 88 -482 -190 -62 -310 -331 -140 -230 -255 -494 -169 -378 -288 -339 -159 -312 -796 -577 -537 -267 1 226 -67 96 -148 284 -2 -22 189 -105 112 150 -27 -236 -227 27 270 245 545 189 -803 -656 -869 -397 -253 128 -293 -16 -78 -270 -23 -76 -254 -145 -45 -16 750 586 628 825 213 548 611 351 276 391 505 1056 1074 1373 270 -238 -9 -320 599 623 377 227 -34 279 -34 -205 -178 -680 -225 -675 -981 -1209 -2359 -1948 -939 -849 -429 -158 163 235 304 385 117 642 666 335 733 763 -166 -333 -35 -997 -501 19 -1061 -1261 -1036 -743 -330 579 541 280 159 257 166 329 822 239 426 -37 -247 328 197 375 809 751 664 1530 723 365 233 -374 -88 4 -379 -180 -20 154 -853 -325 -107 -511 -536 SS 20241028T141743.1Z 9067.595638 256 1 13.41 2 63.86 141.79 38.73 187.18 0.00 1 0.00 1 0 25 4.135e-02 1.006e-02 1.893e-02 4.993e-03 3.132069e-01 2.486773e-03 3.739236e-03 -6.000000e+00 2.336056e-02 224.31 -2.00 3.52 -2.00 317.48 0.00e+00 -4.121821e-04 3.786603e-04 1.346193e-04 -6.000000e+00 1.030322e-03 279.00 -2.00 20.00 -2.00 316.80 0.00e+00 2.257 0.000 302.00 328.00 3 5.1860e+00 6.5389e-03 2.6449e-02 -6.0000e+00 5.7647e-02 5.9817e-02 7.3981e-03 1.5780e-02 -6.0000e+00 6.2834e-02 -6.2527e-03 4.5725e-03 7.8556e-03 -6.0000e+00 3.7459e-02 -5.5374e-03 2.2977e-03 2.2385e-03 -6.0000e+00 1.5854e-02 2.3494e-04 3.8891e-04 1.4289e-04 2.4823e-05 -6.0000e+00 1.1268e-03 7.5812e-03 0.0000e+00 12 9 9 12 41 1 99.97 22.76 0.48 0.00758 0.01050 3 3 1 5 0 3351.700 26.00 20.00 22.76 13.83 33.2 924.09 -5323 24099 -9162 -4888 2631 11874 9392 -6782 738 4576 -20688 -13781 -11254 -6607 5752 -4173 2796 -638 -708 6593 262 5660 8685 -1294 -1651 812 -996 -465 -1328 -4222 347 1794 4574 7084 -533 -382 -6949 -4721 1257 2567 -431 492 474 1824 -3792 -467 -2432 269 -1366 -2410 1577 4391 1376 1092 -490 1691 893 246 1157 -128 962 1253 806 2984 -145 -3120 -425 -1259 -1205 324 -555 1297 335 120 -373 -155 323 -859 881 -1397 -2475 -1362 -1384 -2188 -960 14 603 523 379 125 571 198 250 1433 420 924 877 515 383 32 -145 -1231 -391 -925 26 43 85 -1117 -498 423 493 82 401 259 769 227 -743 327 25 -641 -931 -84 295 38 200 -310 1100 1017 835 87 170 -727 -426 361 -719 151 18 274 439 -148 -77 -338 -280 -444 1814 -934 -459 221 854 725 -691 79 506 -2756 -1750 -1558 -1013 902 -811 540 -133 -155 1392 60 1230 1867 -327 -446 224 -283 -125 -334 -1072 89 499 1352 2141 -165 -114 -2385 -1720 520 1238 -223 266 264 1016 -2226 -265 -1389 147 -747 -1345 894 2611 845 712 -337 1168 635 175 800 -89 674 938 626 2434 -123 -2553 -334 -975 -936 281 -504 1211 315 109 -333 -124 247 -634 670 -1160 -2348 -1343 -1463 -2326 -1077 17 716 639 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