File name: Pandora179s1_CornwallCT_20241111_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20241113T122018.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20241111_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20241111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241111T143246.9Z 9081.606098 188 1 0.55 2 66.08 147.39 137.93 37.35 0.00 1 0.00 1 0 17 1.583e-02 6.993e-03 1.229e-02 4.193e-03 2.935110e-01 2.078828e-03 3.589616e-03 -6.000000e+00 8.888151e-03 223.07 -2.00 3.52 -2.00 317.05 0.00e+00 3.068074e-04 2.825398e-04 6.623515e-05 -6.000000e+00 3.912497e-04 277.20 -2.00 20.00 -2.00 316.43 0.00e+00 2.448 0.000 302.00 328.00 3 1.6630e+00 5.4233e-03 2.7298e-02 -6.0000e+00 2.1886e-02 4.0650e-02 6.1156e-03 1.4865e-02 -6.0000e+00 2.3895e-02 -1.2100e-02 3.6534e-03 7.3990e-03 -6.0000e+00 1.4243e-02 -6.6420e-04 1.7959e-03 2.1138e-03 -6.0000e+00 6.0242e-03 7.0416e-03 -1.2764e-03 1.1944e-04 2.4753e-05 -6.0000e+00 4.3123e-04 1.7685e-02 0.0000e+00 12 9 1 12 1 1 98.26 22.70 0.34 0.01769 0.00809 3 85 1 5 0 136.060 25.90 20.00 22.70 16.26 33.7 945.25 -156 1082 -6534 -2226 -4608 -6867 -8457 -1381 625 850 -3160 -2845 -1500 -1586 3525 -1347 -255 103 1658 3118 189 -947 521 2700 53 -981 -1142 -262 -2771 -708 2679 43 3238 -1073 -990 -577 -785 -1661 -250 -1315 -553 -521 -626 820 521 238 -392 -175 -969 984 775 262 1184 1033 291 910 1202 720 535 406 810 553 1843 1405 55 -877 -259 -231 803 1687 -25 587 -1102 -79 -75 -582 -415 -359 -763 -1061 -1147 -1189 -2206 -2149 -1243 -960 -587 304 427 408 114 866 626 1709 806 506 264 446 -96 -139 -87 -918 -164 56 130 -1226 -595 -921 -299 185 351 522 158 376 -160 240 651 26 489 244 -459 -554 32 678 486 731 102 900 596 327 -77 -350 -298 57 238 -123 -409 286 -303 -78 -543 -169 -36 -16 127 -862 -271 -563 -803 -1044 -177 80 117 -455 -415 -240 -295 719 -323 -64 27 447 860 55 -277 152 749 16 -313 -368 -80 -804 -215 830 14 1090 -395 -346 -193 -283 -700 -115 -723 -311 -309 -383 501 319 146 -239 -104 -573 574 478 175 777 718 211 672 903 543 395 297 606 445 1497 1231 49 -741 -202 -187 639 1507 -24 575 -1098 -75 -66 -494 -339 -279 -622 -919 -1056 -1215 -2307 -2358 -1369 -1129 -690 365 514 497 129 940 663 1742 830 579 320 570 -125 -187 -110 -1127 -188 66 158 -1598 -806 -1252 -427 268 538 811 238 552 -217 321 865 35 695 352 -679 -808 47 954 684 977 131 1160 828 467 -116 -522 -453 89 382 -208 -680 483 -515 -129 -901 -269 -56 SS 20241111T143537.7Z 9081.608075 191 1 14.19 2 65.79 148.06 137.61 38.23 0.00 1 0.00 1 0 17 1.408e-01 2.517e-02 8.464e-02 1.426e-02 3.088347e-01 7.011467e-03 3.770600e-03 -6.000000e+00 7.915933e-02 223.07 -2.00 3.52 -2.00 318.13 0.00e+00 7.475416e-04 1.262981e-03 6.370503e-04 -6.000000e+00 3.482616e-03 277.20 -2.00 20.00 -2.00 317.49 0.00e+00 2.422 0.000 302.00 328.00 3 6.4364e+00 1.8645e-02 2.7656e-02 -6.0000e+00 1.9492e-01 1.6693e-01 2.1275e-02 1.6163e-02 -6.0000e+00 2.1275e-01 -1.8500e-02 1.3765e-02 7.8177e-03 -6.0000e+00 1.2682e-01 -1.0423e-02 7.0953e-03 2.3545e-03 -6.0000e+00 5.3688e-02 5.5724e-05 -8.7910e-04 4.1620e-04 2.6513e-05 -6.0000e+00 3.8375e-03 1.1834e-02 0.0000e+00 12 9 9 12 1 1 99.98 22.70 -0.27 0.01183 0.00523 6 6 1 5 0 2026.970 25.90 20.00 22.70 16.37 33.8 946.64 67784 96249 -281 -11437 4840 53784 -25114 -5606 7208 30177 -27710 30818 -24195 3925 8349 -8439 14822 -2646 -1597 7246 15789 4641 27678 -12520 12796 8955 -15420 6460 -4137 5430 1543 1782 6944 49880 -1554 -989 -20381 1368 -1626 10502 -170 -3904 7510 1608 -1188 -2647 -1532 2641 -4655 -3894 -5034 12235 -2734 2898 -309 7306 -1162 -1688 -1538 337 -1908 -4493 2369 -2465 4569 -10517 2373 -2832 415 -633 4203 3839 -217 -2068 -4102 1859 -2574 751 -1976 -1003 -5963 1915 -1310 -4411 1568 2751 2658 262 4804 -1663 3568 -1275 718 583 -685 1213 -1899 3567 638 189 1603 657 -1804 -1021 -1198 1988 1690 -2410 -771 134 3019 573 559 1022 -1489 -2176 -2440 244 -1862 -1694 1012 -305 -118 1254 -3136 4094 -2308 -358 -217 725 -725 -2561 1552 -833 1542 -153 -280 758 -70 743 330 30 192 2393 2883 -21 -943 326 2072 -2203 -450 571 2034 -3350 2110 -3210 458 1081 -1350 2157 -444 -299 1287 2635 859 4116 -2724 2464 1868 -3845 1327 -881 1028 322 406 1642 8059 -399 -242 -6477 404 -593 3714 -74 -1862 3298 759 -575 -1299 -733 1189 -2220 -1853 -2551 5616 -1548 1638 -187 4181 -736 -1071 -952 202 -1196 -3094 1662 -1950 3404 -8516 1568 -1919 287 -500 3474 3330 -196 -1824 -3427 1313 -1848 496 -1400 -736 -5195 1708 -1293 -4707 1680 3114 3169 330 5775 -2052 3864 -1323 671 529 -667 1283 -2313 4564 893 262 2049 776 -2049 -1179 -1498 2542 2265 -3527 -1171 202 4670 922 869 1582 -2171 -3003 -3360 341 -2840 -2732 1612 -485 -181 1820 -4512 5214 -2985 -459 -299 1063 -1139 -4218 2506 -1434 2567 -271 -509 1392 -130 1325 567 53 333 SS 20241111T143929.5Z 9081.610758 194 1 25.82 2 65.42 148.99 137.16 39.42 0.00 1 0.00 1 0 17 1.429e-02 5.403e-03 5.030e-03 1.111e-03 2.854731e-01 5.507504e-04 3.418182e-03 -6.000000e+00 8.035110e-03 223.07 -2.00 3.52 -2.00 318.19 0.00e+00 4.211652e-04 9.875122e-05 9.022710e-05 -6.000000e+00 3.534550e-04 277.20 -2.00 20.00 -2.00 317.55 0.00e+00 2.388 0.000 302.00 328.00 3 2.4936e+00 1.4704e-03 2.6564e-02 -6.0000e+00 1.9786e-02 2.4899e-02 1.6717e-03 1.4392e-02 -6.0000e+00 2.1593e-02 4.5503e-03 1.0677e-03 7.1881e-03 -6.0000e+00 1.2871e-02 -8.5392e-03 5.4651e-04 2.1053e-03 -6.0000e+00 5.4513e-03 3.2906e-03 -2.1781e-04 3.2871e-05 2.3232e-05 -6.0000e+00 3.8937e-04 9.1621e-03 0.0000e+00 12 1 1 12 1 1 100.00 22.70 0.39 0.00916 0.00753 694 314 1 5 0 36.940 25.90 20.01 22.70 16.56 33.9 948.32 344 -5492 709 -5653 -2363 -4299 -2871 -2559 -2869 -2243 -8056 -1395 -4101 977 -525 636 -866 428 -201 433 578 -947 1613 -269 1318 -136 1031 -954 376 338 1788 1201 1271 1153 -3297 -708 -2203 -375 -324 302 -1320 -972 -816 -1359 -202 -469 -339 -517 81 -396 1316 865 642 1173 436 910 539 524 455 901 752 1378 1374 1565 375 -580 -59 -725 1055 764 635 161 239 303 147 2 -185 -549 -163 -292 -1107 -924 -2168 -1504 -1065 -778 -420 -218 364 102 500 351 360 717 858 419 738 806 21 -223 -271 -712 -476 216 -838 -808 -662 -617 -317 255 229 107 113 42 105 259 432 126 354 -89 -356 73 85 248 416 596 246 1225 340 205 35 -362 -210 -71 -112 -182 139 207 -134 -120 88 -409 -286 23 -441 56 -458 -165 -287 -196 -195 -246 -205 -785 -129 -434 114 -72 96 -142 72 -36 79 108 -179 301 -54 277 -30 229 -206 75 66 361 266 307 292 -829 -167 -567 -110 -114 124 -557 -431 -373 -634 -93 -217 -154 -254 39 -192 662 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