File name: Pandora179s1_CornwallCT_20241124_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20241125T044532.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20241124_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20241124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241124T131542.0Z 9094.552570 294 1 48.67 2 78.35 132.00 40.62 210.31 0.00 1 0.00 1 0 17 4.764e-01 1.050e-02 1.803e-01 3.625e-03 6.959930e-01 1.911303e-03 7.791940e-03 -6.000000e+00 2.674204e-01 222.68 -2.00 3.52 -2.00 321.00 0.00e+00 4.414609e-03 8.379110e-04 6.600863e-04 -6.000000e+00 1.179809e-02 275.71 -2.00 20.00 -2.00 320.51 0.00e+00 4.794 0.002 302.00 328.00 3 2.7989e+00 5.9915e-03 5.7722e-02 -6.0000e+00 6.5827e-01 1.8074e-01 8.2631e-03 3.7339e-02 -6.0000e+00 7.1903e-01 -1.4876e-01 8.8214e-03 1.9953e-02 -6.0000e+00 4.2884e-01 5.0877e-02 4.2932e-03 8.4723e-03 -6.0000e+00 1.8246e-01 1.5689e-04 -1.0814e-03 9.8928e-05 8.2900e-05 -6.0000e+00 1.3024e-02 1.2191e-02 0.0000e+00 12 8 8 10 0 0 99.83 22.72 0.39 0.01219 0.00407 78 19 1 5 0 623.900 25.90 19.99 22.72 7.86 33.0 907.42 -178875 900000 -156361 47156 -184957 195718 -135779 -161494 -89026 -84084 -194929 -148005 -74682 -131422 900000 -55829 94317 463 9827 13503 -22368 18770 26625 -34649 -29195 64217 -62510 605 -31262 -23836 -14998 -26427 16698 35322 30082 -476 1943 -4079 9924 19449 8119 3852 2299 12258 -9429 4027 -6578 11281 3911 6147 3903 18757 -3134 7859 3742 7222 2762 -3300 4850 1560 2682 340 5440 4231 3562 -3634 1588 1751 -1833 3268 1271 2375 902 74 -1477 -236 -525 -3635 350 -1820 -1090 -1561 -677 -3427 456 313 274 23 924 -775 -417 710 -564 1199 -6 302 -140 562 4 -33 -235 -973 -581 -1324 -686 -1016 268 -1286 -736 237 36 -157 -267 600 132 358 -196 614 288 -21 110 -279 128 478 525 1629 9 880 517 185 171 -579 -52 -124 -310 94 -173 390 -238 -37 -140 35 -411 -1844 900000 -1750 167 -2560 692 -1265 -2179 -658 -648 -4822 -2568 -792 -3251 900000 -1040 455 6 136 191 -467 259 351 -913 -788 722 -2571 13 -914 -697 -482 -1163 563 1089 957 -20 86 -225 583 1256 670 360 231 1154 -1121 430 -803 1200 473 780 564 2634 -554 1359 719 1395 574 -727 954 338 590 77 1341 1201 1089 -1182 485 551 -656 1279 562 1086 413 32 -594 -84 -174 -1262 131 -830 -581 -959 -454 -2505 341 249 211 18 724 -643 -321 505 -392 848 -5 260 -140 644 5 -41 -276 -1033 -558 -1276 -703 -1103 303 -1585 -992 330 56 -259 -443 952 199 517 -285 927 461 -34 178 -436 191 738 779 2299 13 1280 795 322 327 -1111 -104 -264 -708 224 -419 952 -579 -86 -303 71 -813 SS 20241124T132103.1Z 9094.556286 297 1 48.57 2 77.61 133.03 41.15 212.14 0.00 1 0.00 1 0 25 4.825e-01 8.017e-03 1.904e-01 3.406e-03 6.613006e-01 1.787781e-03 7.444050e-03 -6.000000e+00 2.707368e-01 222.68 -2.00 3.52 -2.00 320.93 0.00e+00 4.102685e-03 7.703397e-04 1.054046e-03 -6.000000e+00 1.195025e-02 275.71 -2.00 20.00 -2.00 320.44 0.00e+00 4.531 0.002 302.00 328.00 3 2.8394e+00 5.6043e-03 5.5055e-02 -6.0000e+00 6.6643e-01 1.1039e-01 7.6265e-03 3.6464e-02 -6.0000e+00 7.2782e-01 -5.0202e-02 8.1799e-03 1.8626e-02 -6.0000e+00 4.3387e-01 8.2815e-03 4.0089e-03 7.9903e-03 -6.0000e+00 1.8465e-01 1.9975e-04 -8.3138e-04 9.4447e-05 7.6909e-05 -6.0000e+00 1.3156e-02 1.2435e-02 0.0000e+00 11 8 0 10 0 0 99.96 22.72 0.24 0.01243 0.00619 125 30 1 5 0 388.490 25.90 20.01 22.72 8.16 33.2 910.45 -155084 900000 -155858 -6637 -191646 -64760 -150377 -150040 -86005 -35780 -151832 -72664 -35067 -69113 347759 -42275 43457 -26889 21750 8451 23439 56643 17854 -3426 -13668 9698 -40516 -13180 -33287 -25208 -15828 -15833 5859 39658 9912 -3037 -12058 -6740 7529 6477 419 876 2292 3259 -4865 3658 -7721 8425 -1474 142 -269 10826 -819 5887 2239 6129 2184 -3668 2277 -230 897 -1337 3964 2402 3190 -2943 3701 993 -1996 3072 99 999 19 789 -1191 409 -622 -2054 1607 -1618 -910 -1540 -1103 -2919 236 -131 109 -260 1101 -220 89 791 97 1463 65 422 -274 867 192 303 -58 -882 -196 -386 -973 -1442 -205 -1301 -292 13 562 -55 -28 301 -8 393 -176 296 -232 -244 -187 -59 340 48 142 1299 942 372 537 144 143 -657 34 -23 -186 220 -108 374 -508 -139 -58 172 -211 -1268 900000 -1752 -22 -2888 -287 -1537 -1725 -643 -178 -2366 -623 -262 -956 1155 -714 361 -506 277 131 324 564 272 -70 -337 201 -1435 -350 -1069 -802 -548 -666 233 1240 409 -139 -657 -379 450 473 37 84 230 335 -552 392 -953 919 -187 19 -40 1626 -152 1117 470 1289 492 -875 497 -51 201 -336 1078 752 1054 -1019 1182 335 -762 1282 47 493 9 364 -511 155 -221 -749 632 -780 -511 -924 -724 -2067 172 -102 89 -218 911 -177 66 548 65 998 50 377 -286 1022 231 363 -70 -961 -193 -381 -1036 -1629 -241 -1658 -377 19 891 -93 -48 485 -12 571 -259 453 -376 -410 -309 -94 516 70 199 1856 1311 511 830 252 273 -1261 69 -49 -422 521 -260 911 -1236 -322 -125 349 -419 SS 20241124T135411.1Z 9094.579295 319 1 1.24 2 73.36 139.72 44.97 222.66 0.00 1 0.00 1 0 17 9.411e-02 6.105e-03 5.548e-02 3.560e-03 5.118656e-01 1.777566e-03 5.997609e-03 -6.000000e+00 5.280564e-02 222.68 -2.00 3.52 -2.00 319.32 0.00e+00 1.348424e-03 4.697825e-04 2.355905e-04 -6.000000e+00 2.312533e-03 275.70 -2.00 20.00 -2.00 318.75 0.00e+00 3.438 0.001 302.00 328.00 3 1.0472e+00 4.9210e-03 4.1363e-02 -6.0000e+00 1.2998e-01 5.2172e-02 5.7911e-03 2.6007e-02 -6.0000e+00 1.4195e-01 -2.2638e-02 4.7517e-03 1.3135e-02 -6.0000e+00 8.4563e-02 1.6882e-03 2.5243e-03 4.1508e-03 -6.0000e+00 3.5779e-02 3.8820e-03 -3.3702e-04 9.8561e-05 4.4444e-05 -6.0000e+00 2.5637e-03 1.2218e-02 0.0000e+00 12 1 1 12 1 1 87.04 22.74 0.22 0.01222 0.00969 9 94 1 5 0 123.510 25.90 19.99 22.74 8.59 32.8 910.77 -55013 -13077 -41373 -12313 -44052 -21712 -45565 871 -15339 -3169 -11528 -30576 -11294 -17735 383 -14448 1501 -8529 1033 7379 3250 877 -716 -1365 -3300 -1652 -8653 -2167 -5003 -7548 4541 48 3115 -3118 -1246 -8555 -3533 -3777 989 -1394 990 236 1783 -145 413 1740 -1236 465 -939 835 -165 3003 1006 1562 1937 129 619 -442 283 188 1375 22 2225 1215 1337 52 -106 519 785 1034 -173 750 -512 586 -215 -434 -348 -1300 580 -857 -1527 -1162 -1336 -2249 -657 -765 -160 145 128 497 519 829 322 414 619 438 331 923 86 -374 -246 -833 317 -333 -703 -1310 -462 -725 -68 311 67 72 116 711 -232 315 -8 328 41 -91 -433 -114 103 -5 997 500 473 638 308 236 161 -382 20 96 190 -334 -171 29 -252 195 -284 -197 -36 -1184 -218 -991 -218 -979 -369 -1044 14 -336 -67 -276 -955 -349 -727 16 -833 82 -563 67 471 223 62 -53 -110 -293 -153 -880 -200 -457 -729 440 6 369 -423 -160 -1156 -492 -619 189 -327 256 66 513 -43 124 525 -388 145 -304 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