File name: Pandora179s1_CornwallCT_20241201_L2Fit_fout2c40d20221201p1-8.txt File generation date: 20241202T045140.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20241201_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20241201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 205 347 Nominal wavelengths inside fitting window [nm]: 305.0173 305.1585 305.2997 305.4409 305.5821 305.7232 305.8644 306.0055 306.1467 306.2878 306.4289 306.5700 306.7111 306.8521 306.9932 307.1343 307.2753 307.4163 307.5573 307.6983 307.8393 307.9803 308.1213 308.2623 308.4032 308.5442 308.6851 308.8260 308.9669 309.1078 309.2487 309.3896 309.5304 309.6713 309.8121 309.9529 310.0938 310.2346 310.3754 310.5161 310.6569 310.7977 310.9384 311.0792 311.2199 311.3606 311.5013 311.6420 311.7827 311.9234 312.0640 312.2047 312.3453 312.4859 312.6265 312.7672 312.9077 313.0483 313.1889 313.3295 313.4700 313.6105 313.7511 313.8916 314.0321 314.1726 314.3131 314.4535 314.5940 314.7344 314.8749 315.0153 315.1557 315.2961 315.4365 315.5769 315.7173 315.8576 315.9980 316.1383 316.2786 316.4189 316.5592 316.6995 316.8398 316.9801 317.1203 317.2606 317.4008 317.5410 317.6812 317.8214 317.9616 318.1018 318.2420 318.3821 318.5223 318.6624 318.8025 318.9426 319.0827 319.2228 319.3629 319.5029 319.6430 319.7830 319.9231 320.0631 320.2031 320.3431 320.4831 320.6230 320.7630 320.9029 321.0429 321.1828 321.3227 321.4626 321.6025 321.7424 321.8823 322.0221 322.1620 322.3018 322.4416 322.5814 322.7212 322.8610 323.0008 323.1406 323.2803 323.4201 323.5598 323.6995 323.8392 323.9789 324.1186 324.2583 324.3980 324.5376 324.6773 324.8169 324.9565 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241201T131852.8Z 9101.554778 77 1 47.67 2 79.22 132.88 85.83 133.81 0.00 1 0.00 1 0 25 6.945e-01 2.085e-02 2.201e-01 4.868e-03 8.538294e-01 2.657509e-03 9.384183e-03 -6.000000e+00 3.957815e-01 222.59 -2.00 3.52 -2.00 321.43 0.00e+00 5.862028e-03 1.301259e-03 1.768743e-03 -6.000000e+00 1.799947e-02 274.92 -2.00 20.00 -2.00 320.97 0.00e+00 5.150 0.002 302.00 328.00 3 3.0651e+00 8.8246e-03 6.7145e-02 -6.0000e+00 9.7943e-01 4.3591e-01 1.2896e-02 4.9649e-02 -6.0000e+00 1.0741e+00 -5.8282e-01 1.4002e-02 2.5218e-02 -6.0000e+00 6.3678e-01 2.4015e-01 6.5915e-03 1.0372e-02 -6.0000e+00 2.6886e-01 7.2435e-05 -1.3855e-03 1.2558e-04 1.0569e-04 -6.0000e+00 1.9334e-02 1.2470e-02 0.0000e+00 12 8 8 10 0 0 99.50 22.76 0.36 0.01247 0.00206 24 6 1 5 0 1986.070 26.00 20.00 22.76 -1.15 31.9 862.24 -135228 900000 -162903 900000 -152626 -190327 -118888 -281942 -137096 900000 -274086 -153068 -174118 -102073 900000 -40046 900000 1011 30089 30360 66186 248128 900000 -77374 371857 76300 -30521 21965 -37723 -56984 -29428 -33635 24281 900000 62706 62944 -38757 34718 59411 103134 9760 31625 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-241 -1167 -692 -1141 82 -1650 -1890 -1767 -130 422 -1887 -1645 -976 636 -892 -1196 700 758 344 -403 70 637 -23 719 -228 1440 1786 595 5000 428 2444 1821 1497 1647 -1005 653 -410 -682 450 127 194 -568 706 -915 -1407 -3118 SS 20241201T132413.9Z 9101.558494 80 1 14.56 2 78.49 133.91 85.15 134.73 0.00 1 0.00 1 0 25 6.593e-01 1.457e-02 2.924e-01 6.609e-03 8.066163e-01 3.577307e-03 8.941455e-03 -6.000000e+00 3.739813e-01 222.59 -2.00 3.52 -2.00 321.20 0.00e+00 3.682392e-03 1.677566e-03 1.328385e-03 -6.000000e+00 1.720199e-02 274.92 -2.00 20.00 -2.00 320.73 0.00e+00 4.852 0.002 302.00 328.00 3 2.8762e+00 1.1529e-02 6.2498e-02 -6.0000e+00 9.2257e-01 2.0674e-01 1.6823e-02 4.4569e-02 -6.0000e+00 1.0101e+00 -2.7700e-01 1.8821e-02 2.3246e-02 -6.0000e+00 5.9733e-01 1.1277e-01 8.9500e-03 8.6998e-03 -6.0000e+00 2.5558e-01 1.2548e-04 -1.2370e-03 1.7323e-04 9.0172e-05 -6.0000e+00 1.8393e-02 1.3277e-02 0.0000e+00 12 9 9 12 1 1 96.17 22.76 0.37 0.01328 0.00398 9 8 1 5 0 1455.890 26.00 19.99 22.76 -0.99 31.8 863.12 900000 900000 -188543 -193626 -196092 -257118 900000 -296897 -127201 900000 -207659 -157245 -192622 -157265 900000 -94949 -53249 57201 -26913 900000 24305 900000 900000 -22480 154784 102180 -58014 -68004 8841 -1826 57675 -40071 143578 207820 82729 21872 -31381 5947 29845 59526 -11614 18142 2795 36019 754 12382 -1966 12168 17628 366 13517 13080 13658 3915 12804 12125 8271 -1669 5458 3788 -1415 526 6244 12959 4946 -297 3148 3916 2110 3522 1268 3531 4637 -2656 124 -2934 3878 -3099 1495 -2788 -3203 -1026 -2199 -3678 -1642 421 -163 674 935 -1081 877 -652 -318 308 -714 -776 -444 644 406 -760 -95 -657 -1091 -773 -2136 63 51 -1154 -766 -367 211 -181 -220 660 604 111 -333 -546 342 -260 957 218 365 938 -244 1636 -624 1555 722 1217 141 -596 -173 -341 103 186 -165 80 237 -318 -3 -513 -560 900000 900000 -1719 -1869 -1788 -4137 900000 -8439 -819 900000 -3230 -1687 -3822 -2952 900000 -1579 -685 368 -362 900000 213 900000 900000 -355 996 658 -1561 -1989 119 -30 641 -1477 1008 1337 1162 550 -1450 223 1083 1950 -816 1125 196 2044 57 927 -161 997 1464 36 1319 1459 1685 586 1882 1879 1375 -305 896 613 -247 99 1283 2870 1286 -82 841 1088 662 1258 514 1460 1868 -1075 44 -960 1113 -984 518 -1217 -1541 -559 -1345 -2429 -1130 301 -122 515 708 -802 595 -423 -201 204 -546 -649 -434 721 466 -887 -110 -683 -1024 -715 -2138 66 55 -1380 -947 -516 311 -287 -354 1028 897 170 -484 -832 543 -425 1506 327 560 1381 -349 2222 -846 2197 1110 2130 260 -1193 -365 -727 233 439 -378 184 567 -724 -6 -1069 -1131 SS 20241201T132835.7Z 9101.561524 83 1 48.31 2 77.91 134.76 84.60 135.50 0.00 1 0.00 1 0 25 5.532e-01 8.320e-03 1.047e-01 1.754e-03 7.760198e-01 9.202709e-04 8.657030e-03 -6.000000e+00 3.102183e-01 222.59 -2.00 3.52 -2.00 321.07 0.00e+00 4.564217e-03 4.164812e-04 1.123664e-03 -6.000000e+00 1.354877e-02 274.92 -2.00 20.00 -2.00 320.61 0.00e+00 4.636 0.002 302.00 328.00 3 1.7137e+00 2.9108e-03 5.9795e-02 -6.0000e+00 7.6366e-01 1.1264e-01 4.1680e-03 4.2515e-02 -6.0000e+00 8.3419e-01 -1.2530e-01 4.6665e-03 2.2183e-02 -6.0000e+00 4.9674e-01 4.1315e-02 2.2453e-03 9.1818e-03 -6.0000e+00 2.1003e-01 5.0697e-04 -1.0100e-03 4.4947e-05 8.8885e-05 -6.0000e+00 1.5069e-02 1.3427e-02 0.0000e+00 11 8 0 10 0 0 99.36 22.76 0.34 0.01343 0.00584 154 37 1 5 0 313.630 26.00 20.00 22.76 -0.87 31.9 864.34 -135492 -135963 -148614 -149899 -230674 -136214 -221475 -192529 -188109 -114952 -213172 -102514 -160669 -93669 -59942 -69481 -47254 -77037 -10120 -46115 1761 -57791 38808 -55600 -9029 -31775 -49444 -29030 -50198 -21005 -33398 -691 -22221 30112 -13552 3671 -18972 -5885 1485 2968 -104 -1979 9459 986 2644 -1873 691 4645 4548 1712 2818 8849 2225 6877 1805 7632 2633 2179 2184 1767 1448 1328 5040 3060 4501 269 4062 159 1591 1665 1389 1254 511 567 -945 846 -2199 -1211 -1588 -510 -1958 -503 -1770 -1933 -751 -615 76 -178 610 5 955 6 231 418 -260 220 -133 820 -221 217 -343 -555 -630 -130 -1556 -1277 -679 -1161 -290 1 394 -108 487 224 337 205 245 194 -92 -276 -401 173 119 616 188 942 228 1142 483 248 332 -294 58 -277 -296 -360 -2 297 -193 -19 -38 -159 -77 -421 -529 -739 -846 -2475 -606 -2462 -1811 -1930 -629 -3354 -614 -2253 -913 -554 -891 -574 -1436 -107 -749 18 -1097 292 -1179 -131 -620 -1192 -566 -1211 -417 -925 -17 -825 737 -505 113 -795 -256 74 177 -7 -156 709 83 225 -172 64 439 461 194 357 1202 327 1061 314 1314 492 408 396 314 265 269 1137 811 1271 79 1156 49 538 650 603 569 230 239 -367 288 -726 -408 -611 -234 -1082 -290 -1143 -1330 -543 -471 61 -145 493 4 689 4 153 291 -208 206 -134 949 -283 277 -411 -594 -608 -134 -1607 -1388 -775 -1437 -394 1 631 -173 785 377 537 316 379 314 -157 -453 -687 280 186 920 270 1299 310 1631 797 436 646 -579 120 -615 -661 -840 -4 708 -457 -43 -84 -329 -155 SS 20241201T133405.5Z 9101.565341 86 1 48.36 2 77.19 135.83 83.92 136.47 0.00 1 0.00 1 0 25 4.794e-01 6.443e-03 5.923e-02 1.221e-03 7.460040e-01 6.368917e-04 8.372310e-03 -6.000000e+00 2.688610e-01 222.59 -2.00 3.52 -2.00 320.89 0.00e+00 3.094758e-03 2.754628e-04 7.404202e-04 -6.000000e+00 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