File name: Pandora179s1_CornwallCT_20241205_L2Fit_fwvt1c40d20221201p1-8.txt File generation date: 20241206T052523.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c40p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 179 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora179_OF_v3d20220331.txt Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt Level 1 file used: Pandora179s1_CornwallCT_20241205_L1_smca1c40d20221201p1-8.txt Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005) Short location name: CornwallCT Country of location: United States Location latitude [deg]: 41.8213 Location longitude [deg]: -73.2973 Location altitude [m]: 505 Local noon date: 20241205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1622 1771 Nominal wavelengths inside fitting window [nm]: 492.0217 492.1431 492.2644 492.3857 492.5071 492.6283 492.7496 492.8709 492.9921 493.1133 493.2345 493.3557 493.4769 493.5981 493.7192 493.8403 493.9614 494.0825 494.2036 494.3246 494.4457 494.5667 494.6877 494.8087 494.9297 495.0506 495.1716 495.2925 495.4134 495.5343 495.6551 495.7760 495.8968 496.0176 496.1384 496.2592 496.3800 496.5007 496.6215 496.7422 496.8629 496.9836 497.1042 497.2249 497.3455 497.4661 497.5867 497.7073 497.8279 497.9484 498.0689 498.1895 498.3100 498.4304 498.5509 498.6713 498.7918 498.9122 499.0326 499.1529 499.2733 499.3936 499.5140 499.6343 499.7546 499.8748 499.9951 500.1153 500.2356 500.3558 500.4760 500.5961 500.7163 500.8364 500.9566 501.0767 501.1967 501.3168 501.4369 501.5569 501.6769 501.7969 501.9169 502.0369 502.1568 502.2768 502.3967 502.5166 502.6365 502.7563 502.8762 502.9960 503.1158 503.2356 503.3554 503.4752 503.5949 503.7146 503.8343 503.9540 504.0737 504.1934 504.3130 504.4326 504.5523 504.6718 504.7914 504.9110 505.0305 505.1500 505.2695 505.3890 505.5085 505.6280 505.7474 505.8668 505.9862 506.1056 506.2250 506.3443 506.4637 506.5830 506.7023 506.8216 506.9408 507.0601 507.1793 507.2985 507.4177 507.5369 507.6561 507.7752 507.8943 508.0135 508.1325 508.2516 508.3707 508.4897 508.6088 508.7278 508.8468 508.9657 509.0847 509.2036 509.3225 509.4414 509.5603 509.6792 509.7981 509.9169 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241205T151525.7Z 9105.635714 142 1 48.41 2 67.49 157.83 98.39 114.14 0.00 1 0.00 1 0 15 3.387e-03 3.390e-03 2.139e-03 2.128e-03 8.140599e+02 1.239950e+02 6.385304e+01 -6.000000e+00 1.890330e+02 274.47 -2.00 20.00 -2.00 505.28 0.00e+00 5.296536e-04 5.835743e-05 3.136579e-05 -6.000000e+00 9.468850e-05 274.47 -2.00 20.00 -2.00 500.29 0.00e+00 1.864346e-01 4.306778e-02 7.706521e-03 -6.000000e+00 6.835010e-02 222.54 -2.00 3.52 -2.00 501.93 0.00e+00 2.591 0.000 489.00 513.00 1 7.7524e+00 3.2923e-03 3.6224e-03 -6.0000e+00 5.2397e-03 7.2276e-03 8.4797e-04 2.4860e-04 -6.0000e+00 1.3447e-03 5.8276e-04 3.1030e-04 2.3655e-04 1.4716e-05 -6.0000e+00 3.8646e-04 1.0286e-02 -2.2301e-05 10 0 0 10 0 0 99.99 22.67 1.12 0.01029 0.01244 452 108 1 4 0 107.090 25.90 20.00 22.67 4.90 32.8 902.90 87 -298 255 114 71 31 340 546 -170 628 -257 383 -286 300 -298 5 -32 -219 144 -568 89 200 42 95 517 -136 166 479 -379 373 -440 492 -720 300 83 2 -490 -100 -6 -198 721 -477 427 -356 341 -249 85 27 -343 23 -589 333 -760 201 -455 -41 -435 138 -181 173 222 1 737 -300 280 -487 331 -429 -106 -309 -233 209 77 -102 -440 371 -647 432 -310 177 83 -101 57 -313 192 -660 225 -698 239 -156 242 12 578 65 259 98 -567 -86 -323 401 -930 -23 -136 -51 -494 -441 179 -294 172 -141 -45 -296 238 139 338 769 212 355 -156 138 -254 475 142 73 -97 399 -11 -412 270 210 192 151 400 -217 158 -135 -94 -218 101 57 -83 288 -417 500 -362 286 -116 57 282 -290 81 -282 246 114 73 32 362 586 -184 668 -272 397 -295 303 -302 5 -33 -229 154 -617 97 218 46 104 564 -149 181 513 -401 382 -446 493 -743 315 90 2 -536 -108 -6 -210 757 -509 456 -386 371 -273 92 29 -363 24 -595 326 -744 196 -455 -42 -456 137 -181 173 222 1 737 -302 279 -483 321 -413 -100 -291 -217 194 72 -97 -422 351 -611 398 -285 161 76 -93 53 -295 182 -635 215 -676 230 -151 236 11 575 65 258 96 -549 -81 -299 363 -851 -22 -129 -50 -491 -439 176 -286 166 -137 -44 -296 240 142 346 787 219 365 -160 139 -253 466 139 72 -96 392 -11 -407 265 205 185 144 375 -204 147 -128 -91 -214 100 58 -84 276 -404 482 -351 273 -109 52 269 -278 SQ 20241205T153553.8Z 9105.649928 152 1 0.64 2 66.21 162.78 95.04 117.23 0.00 1 0.00 1 0 15 1.801e-03 1.802e-03 3.726e-04 3.722e-04 7.492974e+02 2.099187e+01 5.203149e+01 -6.000000e+00 1.005329e+02 274.47 -2.00 20.00 -2.00 505.26 0.00e+00 4.270891e-04 1.018366e-05 2.455343e-05 -6.000000e+00 5.035325e-05 274.47 -2.00 20.00 -2.00 500.48 0.00e+00 1.350309e-01 7.427843e-03 8.065904e-03 -6.000000e+00 3.634223e-02 222.54 -2.00 3.52 -2.00 502.07 0.00e+00 2.461 0.000 489.00 513.00 1 1.2857e+00 5.6929e-04 3.4291e-03 -6.0000e+00 2.7861e-03 -2.0913e-03 1.4608e-04 2.4421e-04 -6.0000e+00 7.1482e-04 3.8361e-01 -1.9322e-04 4.1541e-05 1.1764e-05 -6.0000e+00 2.0553e-04 1.1459e-02 -1.1455e-05 12 1 1 12 1 1 85.08 22.67 1.63 0.01146 0.01012 50 130 1 4 0 11.980 25.90 20.00 22.67 5.92 33.1 909.65 -230 -281 -115 22 33 184 444 279 288 187 30 16 -113 -73 -60 -202 -121 -61 135 -37 -15 169 217 238 311 186 26 100 -2 -244 -74 -68 -112 172 60 -193 -113 9 19 -17 20 38 12 156 193 147 59 106 -40 -185 -364 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-101 -270 -170 SQ 20241205T154009.6Z 9105.652889 155 1 49.46 2 65.98 163.83 94.36 117.89 0.00 1 0.00 1 0 15 4.497e-03 4.505e-03 1.758e-03 1.753e-03 9.895292e+02 1.012956e+02 6.979283e+01 -6.000000e+00 2.510311e+02 274.47 -2.00 20.00 -2.00 505.25 0.00e+00 4.494845e-04 4.790963e-05 2.718144e-05 -6.000000e+00 1.257185e-04 274.47 -2.00 20.00 -2.00 500.36 0.00e+00 1.395246e-01 3.532585e-02 1.002970e-02 -6.000000e+00 9.071759e-02 222.54 -2.00 3.52 -2.00 501.96 0.00e+00 2.440 0.000 489.00 513.00 1 8.5371e+00 2.7075e-03 3.4465e-03 -6.0000e+00 6.9551e-03 1.0017e-02 6.9487e-04 2.7660e-04 -6.0000e+00 1.7836e-03 2.7251e-04 -7.8639e-04 1.9525e-04 1.3839e-05 -6.0000e+00 5.1321e-04 8.7271e-03 3.3253e-05 11 8 0 10 0 0 99.79 22.68 1.29 0.00873 0.00327 17 4 1 4 0 2909.010 25.90 20.00 22.68 6.22 33.0 911.03 -835 -109 -638 -396 31 320 1228 377 212 1058 -259 6 -323 94 -385 120 -48 92 614 -648 201 556 -965 197 430 -66 -161 254 -362 146 255 252 -364 80 79 -121 -530 -214 -189 118 1408 131 -33 601 192 196 -498 -148 -485 484 -116 310 -834 147 -23 277 -408 -157 -350 -149 415 335 480 -212 -230 -513 558 -491 -525 -202 -591 400 226 -639 -622 119 -539 -79 40 -4 949 -523 482 -581 192 -595 -706 -229 -14 419 -157 417 504 140 364 345 -495 -661 -162 470 -708 -791 401 -631 -546 -777 -164 87 -239 166 -253 74 253 487 193 1165 441 -146 770 691 360 571 311 -398 -30 246 -11 -234 47 -19 314 681 -127 126 -24 109 -577 -319 236 -291 404 227 -747 -129 -85 190 53 112 76 -629 -829 -108 -629 -402 32 339 1266 396 223 1096 -269 6 -337 97 -394 122 -49 94 636 -688 213 588 -1039 210 459 -70 -171 266 -374 146 260 256 -366 82 83 -129 -566 -226 -197 122 1432 135 -34 630 204 209 -513 -155 -502 484 -114 306 -824 145 -23 276 -418 -162 -363 -154 428 347 496 -214 -237 -525 556 -488 -516 -195 -571 383 218 -630 -616 116 -525 -75 38 -3 888 -500 460 -566 188 -590 -704 -227 -14 416 -153 409 499 139 359 336 -477 -644 -154 437 -664 -753 388 -613 -540 -772 -160 84 -230 160 -248 73 253 492 197 1181 451 -145 777 689 354 556 302 -390 -29 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