File name: Pandora179s1_CornwallCT_20241231_L2Fit_fwvt1c40d20221201p1-8.txt
File generation date: 20250109T020330.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c40p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 179
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora179_OF_v3d20220331.txt
Instrument calibration file used: Pandora179s1_CF_v40d20221201.txt
Level 1 file used: Pandora179s1_CornwallCT_20241231_L1_smca1c40d20221201p1-8.txt
Full location name: Cornwall - Mohawk Mt CTDEEP (USEPA AQS Site ID 09-005-0005)
Short location name: CornwallCT
Country of location: United States
Location latitude [deg]: 41.8213
Location longitude [deg]: -73.2973
Location altitude [m]: 505
Local noon date: 20241231
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1622 1771
Nominal wavelengths inside fitting window [nm]: 492.0217 492.1431 492.2644 492.3857 492.5071 492.6283 492.7496 492.8709 492.9921 493.1133 493.2345 493.3557 493.4769 493.5981 493.7192 493.8403 493.9614 494.0825 494.2036 494.3246 494.4457 494.5667 494.6877 494.8087 494.9297 495.0506 495.1716 495.2925 495.4134 495.5343 495.6551 495.7760 495.8968 496.0176 496.1384 496.2592 496.3800 496.5007 496.6215 496.7422 496.8629 496.9836 497.1042 497.2249 497.3455 497.4661 497.5867 497.7073 497.8279 497.9484 498.0689 498.1895 498.3100 498.4304 498.5509 498.6713 498.7918 498.9122 499.0326 499.1529 499.2733 499.3936 499.5140 499.6343 499.7546 499.8748 499.9951 500.1153 500.2356 500.3558 500.4760 500.5961 500.7163 500.8364 500.9566 501.0767 501.1967 501.3168 501.4369 501.5569 501.6769 501.7969 501.9169 502.0369 502.1568 502.2768 502.3967 502.5166 502.6365 502.7563 502.8762 502.9960 503.1158 503.2356 503.3554 503.4752 503.5949 503.7146 503.8343 503.9540 504.0737 504.1934 504.3130 504.4326 504.5523 504.6718 504.7914 504.9110 505.0305 505.1500 505.2695 505.3890 505.5085 505.6280 505.7474 505.8668 505.9862 506.1056 506.2250 506.3443 506.4637 506.5830 506.7023 506.8216 506.9408 507.0601 507.1793 507.2985 507.4177 507.5369 507.6561 507.7752 507.8943 508.0135 508.1325 508.2516 508.3707 508.4897 508.6088 508.7278 508.8468 508.9657 509.0847 509.2036 509.3225 509.4414 509.5603 509.6792 509.7981 509.9169
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20241231T122858.8Z 9131.520125 34 1 20.83 2 89.51 122.19 98.68 119.63 0.00 1 0.00 1 0 22 7.540e-03 7.461e-03 6.728e-04 6.702e-04 8.725865e+03 4.407836e+01 5.821747e+02 -6.000000e+00 4.175351e+02 272.40 -2.00 20.00 -2.00 505.41 0.00e+00 2.307504e-03 1.847628e-05 1.302614e-04 -6.000000e+00 2.097301e-04 272.40 -2.00 20.00 -2.00 501.07 0.00e+00 1.078467e+00 1.314288e-02 7.838958e-02 -6.000000e+00 1.524223e-01 222.98 -2.00 3.52 -2.00 502.57 0.00e+00 20.016 0.149 489.00 513.00 1 3.4833e+00 1.0033e-03 3.4355e-02 -6.0000e+00 1.1676e-02 -3.7943e-02 2.5039e-04 2.5526e-03 -6.0000e+00 2.9974e-03 3.6640e-03 1.0523e-03 7.2054e-05 9.1079e-05 -6.0000e+00 8.6034e-04 7.3660e-03 2.2439e-05 12 9 9 12 1 1 96.94 22.65 4.66 0.00737 0.01467 24 14 1 4 0 832.980 25.79 19.99 22.65 5.65 34.4 936.52 -1833 -1527 -914 -248 183 851 1368 1213 1255 868 363 -9 -560 -728 -751 -837 -369 -66 375 228 497 606 567 885 976 701 540 361 -254 -759 -950 -800 -644 175 351 188 36 165 -6 -182 104 336 497 773 816 910 745 372 59 -498 -883 -1198 -1507 -1112 -547 -92 45 479 504 704 779 961 1027 974 687 277 10 -305 -385 -792 -802 -611 -549 -541 -425 -627 -1034 -981 -1246 -1178 -894 -938 -726 -634 -484 -529 -636 -512 -349 -201 32 588 814 694 701 588 -8 -541 -735 -1279 -1572 -1369 -768 -390 -478 -495 -593 -560 -259 -58 129 358 834 1172 1418 1690 1877 1569 1115 786 575 386 483 626 571 660 527 468 344 316 39 -250 -486 -703 -632 -343 -164 -67 58 307 113 361 242 328 125 -122 -397 -746 -1071 -1059 -1616 -1360 -832 -226 171 791 1290 1160 1203 830 345 -9 -524 -677 -695 -781 -348 -62 359 222 487 581 546 855 948 685 527 350 -243 -732 -904 -762 -611 170 349 185 36 162 -6 -177 101 328 492 774 825 904 739 376 59 -489 -851 -1165 -1459 -1083 -531 -92 45 480 507 709 787 975 1045 993 699 280 10 -302 -378 -774 -781 -596 -540 -539 -426 -627 -1026 -960 -1214 -1144 -869 -919 -717 -633 -476 -525 -634 -510 -347 -201 32 595 829 707 704 578 -8 -523 -699 -1209 -1495 -1327 -749 -394 -487 -510 -611 -573 -265 -59 131 370 866 1226 1491 1750 1960 1652 1177 823 595 405 504 655 590 685 549 490 360 331 41 -259 -499 -722 -654 -360 -172 -72 63 330 123 395 266 362 138 -134 -432 -803 -1146 -1136
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SQ 20241231T123514.4Z 9131.524473 42 1 48.49 2 88.53 123.24 97.71 120.56 0.00 1 0.00 1 0 22 4.602e-03 4.580e-03 2.954e-04 2.948e-04 6.435933e+03 1.885344e+01 4.419712e+02 -6.000000e+00 2.548850e+02 272.40 -2.00 20.00 -2.00 505.38 0.00e+00 1.684850e-03 8.110166e-06 9.769589e-05 -6.000000e+00 1.280265e-04 272.40 -2.00 20.00 -2.00 500.91 0.00e+00 1.201339e+00 5.826610e-03 5.731155e-02 -6.000000e+00 9.303463e-02 222.98 -2.00 3.52 -2.00 502.44 0.00e+00 17.669 0.103 489.00 513.00 1 3.0592e+00 4.4531e-04 2.7989e-02 -6.0000e+00 7.1269e-03 -2.0028e-02 1.1177e-04 1.9879e-03 -6.0000e+00 1.8292e-03 7.6752e-03 5.5551e-04 3.2080e-05 6.9407e-05 -6.0000e+00 5.2515e-04 -9.4228e-03 1.3483e-04 11 8 0 10 0 0 97.22 22.64 2.93 -0.00942 -0.00557 118 28 1 4 0 410.870 25.79 20.00 22.64 5.77 34.4 936.87 -895 -770 -470 -14 163 582 868 849 748 584 220 114 -159 -279 -267 -458 -328 -50 209 70 184 397 419 459 642 413 242 189 -65 -405 -476 -487 -363 59 127 -90 -66 113 -65 -77 63 70 296 415 503 496 345 210 -33 -357 -677 -777 -807 -736 -383 -79 -17 118 259 402 469 565 538 546 388 181 -11 -239 -269 -442 -478 -427 -452 -278 -289 -323 -610 -631 -654 -704 -630 -637 -583 -419 -318 -384 -415 -288 -253 -48 -2 369 445 405 335 288 -28 -286 -458 -707 -956 -827 -636 -389 -497 -489 -357 -297 -157 61 91 180 470 767 951 1088 1202 995 768 520 409 327 381 420 384 335 456 240 253 279 39 -237 -153 -323 -304 -47 -94 -165 58 234 181 256 231 234 33 -84 -309 -499 -644 -666 -806 -700 -427 -13 154 560 829 821 726 564 211 111 -153 -265 -253 -437 -318 -48 206 69 182 393 416 458 643 415 243 188 -64 -397 -460 -472 -351 58 126 -91 -66 113 -64 -76 63 70 298 423 506 501 348 210 -34 -353 -656 -755 -778 -716 -372 -79 -17 119 262 407 476 575 550 558 394 182 -11 -236 -263 -438 -471 -422 -441 -274 -288 -320 -598 -610 -641 -689 -618 -616 -569 -413 -317 -386 -409 -284 -250 -47 -2 371 452 411 336 283 -27 -275 -443 -677 -919 -793 -629 -389 -500 -497 -361 -299 -158 62 93 182 482 792 988 1137 1241 1032 796 534 424 336 389 430 396 348 473 250 258 289 40 -243 -155 -327 -310 -48 -97 -174 61 249 194 271 247 250 36 -89 -325 -526 -674 -698
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