File name: Pandora258s1_CorpusChristiTX_20240430_L2Fit_fwvt1c4d20240322p1-8.txt File generation date: 20241022T140316.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Joseph David Felix Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 258 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora258_OF_v2d20221212.txt Instrument calibration file used: Pandora258s1_CF_v4d20240322.txt Level 1 file used: Pandora258s1_CorpusChristiTX_20240430_L1_smca1c4d20240322p1-8.txt Full location name: Texas A&M University - Corpus Christi Short location name: CorpusChristiTX Country of location: United States Location latitude [deg]: 27.7150 Location longitude [deg]: -97.3287 Location altitude [m]: 14 Local noon date: 20240430 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New AnaFld, based on session 3. First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0664 492.1871 492.3079 492.4286 492.5494 492.6701 492.7907 492.9114 493.0321 493.1527 493.2733 493.3939 493.5145 493.6351 493.7556 493.8762 493.9967 494.1172 494.2377 494.3582 494.4786 494.5991 494.7195 494.8399 494.9603 495.0806 495.2010 495.3213 495.4416 495.5619 495.6822 495.8025 495.9227 496.0430 496.1632 496.2834 496.4036 496.5238 496.6439 496.7640 496.8842 497.0043 497.1243 497.2444 497.3645 497.4845 497.6045 497.7245 497.8445 497.9645 498.0844 498.2043 498.3243 498.4442 498.5640 498.6839 498.8037 498.9236 499.0434 499.1632 499.2830 499.4027 499.5225 499.6422 499.7619 499.8816 500.0013 500.1210 500.2406 500.3602 500.4798 500.5994 500.7190 500.8386 500.9581 501.0776 501.1972 501.3166 501.4361 501.5556 501.6750 501.7945 501.9139 502.0333 502.1526 502.2720 502.3913 502.5106 502.6300 502.7492 502.8685 502.9878 503.1070 503.2262 503.3454 503.4646 503.5838 503.7029 503.8221 503.9412 504.0603 504.1794 504.2985 504.4175 504.5365 504.6556 504.7746 504.8936 505.0125 505.1315 505.2504 505.3693 505.4882 505.6071 505.7260 505.8448 505.9636 506.0825 506.2012 506.3200 506.4388 506.5575 506.6763 506.7950 506.9137 507.0323 507.1510 507.2696 507.3883 507.5069 507.6255 507.7440 507.8626 507.9811 508.0997 508.2182 508.3367 508.4551 508.5736 508.6920 508.8104 508.9288 509.0472 509.1656 509.2840 509.4023 509.5206 509.6389 509.7572 509.8755 509.9937 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240430T181454.1Z 8886.760348 2 1 5.94 2 12.91 167.40 102.52 248.04 0.00 1 0.00 1 0 15 2.172e-03 2.177e-03 1.565e-04 1.563e-04 2.546131e+03 9.450101e+00 1.782606e+02 -6.000000e+00 1.222538e+02 290.24 -2.00 20.00 -2.00 505.28 0.00e+00 3.578862e-04 4.337571e-06 2.378874e-05 -6.000000e+00 6.156496e-05 290.24 -2.00 20.00 -2.00 500.52 0.00e+00 -6.170337e-02 3.030835e-03 1.747068e-02 -6.000000e+00 4.240437e-02 230.23 -2.00 3.19 -2.00 502.11 0.00e+00 1.026 0.000 489.00 513.00 1 2.6862e+00 2.3280e-04 2.1571e-03 -6.0000e+00 3.2598e-03 4.0374e-03 5.9956e-05 4.2032e-04 -6.0000e+00 8.4217e-04 1.1496e-01 6.9612e-04 1.4509e-05 1.9881e-05 -6.0000e+00 2.0720e-04 -3.0841e-03 -2.0750e-05 10 0 0 10 0 0 99.94 26.63 1.37 -0.00308 0.00174 567 60 1 4 0 10.470 34.75 20.00 26.63 33.47 3.8 998.99 -283 -332 -141 -116 105 457 442 348 269 208 397 109 -201 -142 -168 -162 -34 100 -116 -253 148 144 77 242 166 157 347 44 -538 -153 50 -167 -80 235 -244 -154 153 68 -97 -103 14 -73 85 132 171 131 225 266 135 -275 -317 -348 -406 -189 -177 -317 -300 -131 -11 156 209 269 166 182 126 114 243 115 -178 -387 -89 -12 -94 9 -207 -369 -146 67 -195 -300 -179 -268 -377 -38 45 -159 -148 -73 -30 -51 83 275 129 -63 117 351 121 -99 -251 -306 -284 -176 -113 -149 -512 -309 -70 -56 53 155 -53 -124 83 110 203 439 423 290 96 229 131 163 314 294 -122 44 184 105 286 271 -205 -143 66 -116 -193 125 -168 -319 -51 69 3 195 308 255 197 58 -256 -272 -65 -63 -148 -275 -323 -140 -117 107 471 457 363 280 214 408 111 -205 -142 -168 -163 -35 102 -121 -266 155 151 81 254 172 163 364 46 -556 -155 49 -167 -80 239 -253 -161 158 70 -99 -104 14 -75 87 137 177 136 232 275 137 -278 -315 -343 -395 -185 -175 -318 -303 -134 -11 158 212 274 170 187 128 115 243 114 -177 -380 -87 -12 -93 8 -206 -365 -144 65 -187 -287 -172 -260 -369 -38 44 -157 -147 -73 -30 -51 82 273 131 -63 118 347 120 -97 -239 -292 -269 -166 -109 -146 -509 -308 -70 -55 52 151 -52 -123 83 111 206 447 426 294 97 230 130 162 308 290 -121 44 182 104 282 267 -201 -139 64 -111 -184 119 -162 -314 -50 69 3 196 306 254 196 58 -255 -268 -62 -60 -142 SQ 20240430T181500.2Z 8886.760419 2 2 5.94 2 12.90 167.51 102.54 248.05 0.00 1 0.00 1 0 15 2.173e-03 2.180e-03 1.640e-04 1.638e-04 2.542710e+03 9.910804e+00 1.775468e+02 -6.000000e+00 1.223219e+02 290.24 -2.00 20.00 -2.00 505.28 0.00e+00 3.543698e-04 4.550993e-06 2.401290e-05 -6.000000e+00 6.159927e-05 290.24 -2.00 20.00 -2.00 500.52 0.00e+00 -5.936553e-02 3.174773e-03 1.760328e-02 -6.000000e+00 4.242757e-02 230.23 -2.00 3.19 -2.00 502.11 0.00e+00 1.026 0.000 489.00 513.00 1 2.7799e+00 2.4395e-04 2.1654e-03 -6.0000e+00 3.2616e-03 4.5081e-03 6.2778e-05 4.2202e-04 -6.0000e+00 8.4262e-04 1.0465e-01 6.7482e-04 1.5220e-05 1.9928e-05 -6.0000e+00 2.0732e-04 -3.1713e-03 -1.9435e-05 10 0 0 10 0 0 99.55 26.63 1.36 -0.00317 0.00151 567 60 1 4 0 10.470 34.50 20.00 26.63 33.47 3.8 998.99 -250 -358 -118 -142 114 482 424 326 295 197 392 132 -189 -150 -163 -167 -28 58 -140 -241 169 143 86 262 119 162 350 49 -570 -145 27 -158 -75 259 -233 -169 167 49 -109 -83 14 -100 88 145 165 126 244 277 179 -218 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-175 122 -121 -307 -60 73 -35 187 323 274 190 -4 -258 -243 -38 -90 -133 SQ 20240430T181505.5Z 8886.760480 2 3 4.52 2 12.90 167.60 102.55 248.05 0.00 1 0.00 1 0 15 2.181e-03 2.184e-03 1.389e-04 1.387e-04 2.551279e+03 8.393038e+00 1.777444e+02 -6.000000e+00 1.227556e+02 290.24 -2.00 20.00 -2.00 505.28 0.00e+00 3.636016e-04 3.851492e-06 2.435247e-05 -6.000000e+00 6.181765e-05 290.24 -2.00 20.00 -2.00 500.52 0.00e+00 -6.428764e-02 2.688411e-03 1.770827e-02 -6.000000e+00 4.257834e-02 230.23 -2.00 3.19 -2.00 502.11 0.00e+00 1.026 0.000 489.00 513.00 1 2.1757e+00 2.0651e-04 2.1726e-03 -6.0000e+00 3.2732e-03 2.2384e-03 5.3176e-05 4.2361e-04 -6.0000e+00 8.4562e-04 1.9155e-01 7.0910e-04 1.2886e-05 1.9828e-05 -6.0000e+00 2.0806e-04 -3.1137e-03 -2.0423e-05 12 1 1 12 1 1 99.90 26.63 1.36 -0.00311 0.00180 430 60 1 4 0 10.470 34.50 20.00 26.63 33.47 3.8 998.99 -290 -350 -131 -124 110 504 439 347 290 213 371 124 -182 -149 -152 -121 -21 59 -109 -236 130 151 72 262 128 119 327 60 -542 -153 44 -144 -74 236 -266 -172 162 73 -77 -96 -12 -64 99 131 172 128 238 278 120 -236 -347 -350 -383 -191 -188 -361 -313 -104 -22 151 192 268 141 219 158 81 234 107 -200 -365 -112 -38 -104 16 -220 -361 -122 55 -184 -314 -200 -247 -341 -44 10 -164 -132 -84 -33 -37 63 269 164 -84 102 363 87 -110 -253 -323 -279 -161 -96 -148 -500 -344 -64 -104 76 134 -70 -119 83 124 223 431 470 303 115 225 167 146 321 296 -116 26 185 118 271 271 -208 -165 75 -133 -195 112 -129 -289 -57 93 -22 210 322 255 189 29 -218 -256 -68 -113 -161 -282 -340 -130 -126 112 517 453 361 301 222 379 127 -184 -151 -152 -122 -22 60 -112 -248 137 158 76 275 133 124 338 63 -557 -153 44 -142 -75 242 -275 -180 167 76 -79 -97 -13 -65 101 135 178 133 245 287 122 -237 -343 -342 -374 -185 -184 -361 -317 -107 -22 153 195 273 145 224 161 81 233 106 -197 -356 -110 -37 -102 16 -218 -356 -120 54 -178 -303 -193 -239 -332 -43 10 -162 -131 -83 -33 -37 63 268 164 -84 103 359 86 -107 -243 -305 -263 -154 -93 -145 -499 -344 -64 -102 75 133 -69 -119 84 125 224 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