File name: Pandora258s1_CorpusChristiTX_20240901_L2Fit_fout2c4d20240322p1-8.txt File generation date: 20241022T142953.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Joseph David Felix Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 258 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora258_OF_v2d20221212.txt Instrument calibration file used: Pandora258s1_CF_v4d20240322.txt Level 1 file used: Pandora258s1_CorpusChristiTX_20240901_L1_smca1c4d20240322p1-8.txt Full location name: Texas A&M University - Corpus Christi Short location name: CorpusChristiTX Country of location: United States Location latitude [deg]: 27.7150 Location longitude [deg]: -97.3287 Location altitude [m]: 14 Local noon date: 20240901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: New AnaFld, based on session 3. First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.1235 305.2641 305.4047 305.5453 305.6859 305.8265 305.9670 306.1076 306.2481 306.3886 306.5292 306.6697 306.8102 306.9506 307.0911 307.2316 307.3720 307.5124 307.6529 307.7933 307.9337 308.0741 308.2145 308.3548 308.4952 308.6355 308.7759 308.9162 309.0565 309.1968 309.3371 309.4774 309.6176 309.7579 309.8981 310.0384 310.1786 310.3188 310.4590 310.5992 310.7394 310.8795 311.0197 311.1598 311.3000 311.4401 311.5802 311.7203 311.8604 312.0004 312.1405 312.2806 312.4206 312.5606 312.7006 312.8407 312.9806 313.1206 313.2606 313.4006 313.5405 313.6805 313.8204 313.9603 314.1002 314.2401 314.3800 314.5199 314.6597 314.7996 314.9394 315.0792 315.2190 315.3588 315.4986 315.6384 315.7782 315.9179 316.0577 316.1974 316.3371 316.4768 316.6165 316.7562 316.8959 317.0356 317.1752 317.3149 317.4545 317.5941 317.7337 317.8733 318.0129 318.1525 318.2921 318.4316 318.5711 318.7107 318.8502 318.9897 319.1292 319.2687 319.4081 319.5476 319.6871 319.8265 319.9659 320.1053 320.2447 320.3841 320.5235 320.6629 320.8022 320.9416 321.0809 321.2202 321.3595 321.4988 321.6381 321.7774 321.9167 322.0559 322.1952 322.3344 322.4736 322.6128 322.7520 322.8912 323.0304 323.1695 323.3087 323.4478 323.5870 323.7261 323.8652 324.0043 324.1433 324.2824 324.4215 324.5605 324.6996 324.8386 324.9776 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240901T131320.2Z 9010.550928 101 1 15.32 2 76.56 87.97 60.21 85.29 0.00 1 0.00 1 0 25 1.984e-01 1.228e-02 1.067e-01 6.608e-03 5.019434e-01 3.316425e-03 5.305094e-03 -6.000000e+00 1.112721e-01 228.41 -2.00 3.19 -2.00 319.72 0.00e+00 1.830525e-03 1.033965e-03 7.687270e-04 -6.000000e+00 5.187829e-03 294.41 -2.00 20.00 -2.00 318.84 0.00e+00 4.197 0.001 302.00 328.00 3 4.4021e+00 9.7479e-03 4.7950e-02 -6.0000e+00 2.7583e-01 9.5410e-02 1.1828e-02 2.3908e-02 -6.0000e+00 2.9945e-01 -5.9521e-02 9.3309e-03 1.1936e-02 -6.0000e+00 1.7948e-01 1.7422e-02 4.8635e-03 3.7109e-03 -6.0000e+00 7.7076e-02 5.5766e-05 5.6368e-04 1.7741e-04 3.7103e-05 -6.0000e+00 5.1372e-03 -2.0320e-04 0.0000e+00 12 9 9 12 9 1 30.70 26.83 0.35 -0.00020 0.00403 5 2 1 5 0 2551.600 35.00 19.99 26.83 33.30 4.0 992.12 -27348 -70798 -37437 4578 -88114 -86676 -58221 -55785 -65119 -29877 -72632 -19624 -37856 -34753 31355 -9096 -9991 -3141 -24107 70556 -3910 -8661 -22902 -14979 -13959 -11718 39320 13347 -15256 -1068 3390 20501 2379 -4749 -10047 -6892 8754 -1297 8568 -6740 2382 3520 1381 -5131 11486 913 3447 -4124 -98 4163 -584 4978 151 2461 3071 3338 132 1667 -708 4886 2592 1657 1577 -580 1121 958 2684 5792 -6459 694 635 2056 -1004 1480 -345 2488 -243 -2503 530 -740 -2258 -2018 -2686 -1800 -943 -1115 -404 1145 -152 1429 950 1755 -1146 -200 -652 259 -85 992 428 -799 -1107 -1312 -1555 -376 -1550 -1251 -1385 45 -83 561 990 1099 135 -427 -202 919 -810 364 381 -493 -364 366 793 749 359 62 -19 1392 758 68 984 211 -395 -279 -262 -128 663 182 114 -755 108 -979 -454 -385 -1700 -658 53 -2385 -2402 -1351 -1438 -2056 -693 -2668 -493 -1415 -1545 869 -428 -515 -164 -1647 1955 -229 -536 -1756 -1149 -1124 -967 1926 800 -1199 -81 284 1651 259 -557 -1159 -804 998 -196 1441 -1542 540 832 347 -1263 2664 239 884 -1161 -27 1180 -175 1545 53 910 1173 1314 55 669 -283 1849 1061 760 813 -334 628 507 1374 2955 -3843 441 436 1427 -700 947 -203 1395 -132 -1414 329 -500 -1773 -1637 -2339 -1639 -919 -1158 -435 1242 -166 1449 891 1520 -973 -174 -641 288 -100 1308 557 -1015 -1401 -1501 -1673 -423 -1915 -1609 -1886 61 -120 836 1586 1799 217 -651 -305 1316 -1206 564 593 -805 -587 567 1268 1144 527 88 -26 1969 1209 112 1729 367 -717 -534 -507 -258 1352 382 238 -1510 215 -1876 -849 SS 20240901T132222.5Z 9010.557205 104 1 6.74 2 74.57 89.01 58.27 86.26 0.00 1 0.00 1 0 25 5.044e-02 6.709e-03 2.162e-02 2.500e-03 4.535590e-01 1.245253e-03 4.841227e-03 -6.000000e+00 2.827108e-02 228.41 -2.00 3.19 -2.00 318.73 0.00e+00 6.369551e-04 2.830953e-04 3.752329e-04 -6.000000e+00 1.318375e-03 294.41 -2.00 20.00 -2.00 317.79 0.00e+00 3.687 0.000 302.00 328.00 3 2.6484e+00 3.4421e-03 4.2408e-02 -6.0000e+00 7.0082e-02 2.9848e-02 3.9934e-03 2.1466e-02 -6.0000e+00 7.6094e-02 -2.8780e-02 2.7540e-03 1.0368e-02 -6.0000e+00 4.5609e-02 7.9317e-03 1.4605e-03 2.8350e-03 -6.0000e+00 1.9576e-02 5.7019e-04 -4.2848e-04 6.6453e-05 2.8624e-05 -6.0000e+00 1.3060e-03 3.0413e-03 0.0000e+00 12 9 1 12 1 1 77.73 26.83 0.38 0.00304 -0.00018 21 19 1 5 0 306.080 35.00 20.00 26.83 33.55 4.0 993.88 -13176 -15252 -6261 -14664 -26705 -11792 -18419 -14634 -23171 -2428 -18505 -14381 -6992 -5223 -2212 -1298 -43 2173 -2282 303 -5501 -3815 1179 -1859 -1390 902 -2420 -3292 -2171 -3661 -1210 -1207 -547 -5686 -2259 -1566 -516 -2488 1839 -1318 -1299 594 -26 703 182 494 467 -444 1287 1803 1222 1153 1397 1191 2089 1012 -133 794 642 490 1612 1218 2629 1561 -251 368 -141 235 -178 416 774 993 674 425 -442 -80 -1017 -906 -841 -743 -1429 -1886 -2104 -1341 -730 -332 9 234 673 423 318 -250 195 347 -415 -325 932 503 -370 -907 -627 -382 -215 -470 -1606 -962 -963 -273 11 814 567 308 482 448 90 328 -134 -19 166 -231 -177 219 430 584 581 185 607 960 293 159 56 278 -223 132 -49 -338 408 200 -153 -421 -417 -536 -203 -418 -543 -208 -483 -911 -359 -669 -585 -1130 -101 -920 -782 -429 -381 -187 -122 -4 228 -265 36 -633 -477 151 -241 -191 127 -348 -448 -312 -526 -194 -219 -110 -1213 -434 -310 -115 -624 542 -468 -462 218 -10 269 71 194 183 -177 513 756 529 544 708 648 1093 553 -75 437 346 264 904 757 1685 1098 -178 243 -91 154 -124 330 625 823 548 347 -331 -57 -680 -609 -634 -613 -1278 -1798 -2035 -1357 -755 -365 10 262 744 465 338 -248 192 349 -444 -359 1103 645 -504 -1199 -801 -461 -244 -564 -2030 -1211 -1279 -367 16 1230 890 476 748 680 132 460 -192 -28 258 -363 -276 331 655 849 838 256 836 1327 437 249 91 467 -375 234 -90 -629 768 386 -295 -778 -759 -964 -356 SS 20240901T133047.4Z 9010.563049 107 1 54.23 2 72.70 89.98 56.46 87.17 0.00 1 0.00 1 0 25 2.587e-02 5.943e-03 1.645e-03 2.961e-04 4.086224e-01 1.471989e-04 4.383588e-03 -6.000000e+00 1.449912e-02 228.41 -2.00 3.19 -2.00 318.18 0.00e+00 5.869026e-04 2.816996e-05 1.969307e-04 -6.000000e+00 6.761210e-04 294.41 -2.00 20.00 -2.00 317.20 0.00e+00 3.313 0.000 302.00 328.00 3 9.8008e-01 3.9914e-04 3.8114e-02 -6.0000e+00 3.5942e-02 3.4418e-03 4.5675e-04 1.9260e-02 -6.0000e+00 3.9024e-02 -1.5079e-02 2.9309e-04 9.3279e-03 -6.0000e+00 2.3390e-02 4.5049e-03 1.5288e-04 2.5828e-03 -6.0000e+00 1.0040e-02 4.6100e-03 -2.5747e-04 7.9434e-06 2.6019e-05 -6.0000e+00 6.6973e-04 2.4966e-03 0.0000e+00 10 0 0 10 0 0 77.81 26.83 0.33 0.00250 0.00056 1373 146 1 5 0 39.490 35.00 20.00 26.83 33.92 4.0 996.88 -5934 -6793 -7391 -11462 -11011 -9240 -7895 -7448 -6274 -8143 -8135 -6246 -4506 -2479 -1034 -1426 -47 480 469 226 -689 25 716 572 -336 349 -675 -1292 -1593 891 598 1079 378 -2623 -2786 -1981 -1331 -912 -84 -254 -354 -123 -37 64 362 -13 -189 -123 -425 830 1197 886 1403 1027 1029 1055 452 147 225 574 1278 1553 2172 1394 -180 265 -315 329 762 228 401 164 214 271 -227 -135 -795 -726 -483 -1121 -1193 -1575 -2145 -1323 -888 -549 -310 130 733 316 607 197 471 530 154 -61 511 614 -234 -552 -518 -586 -442 -91 -1349 -974 -939 -507 1 276 325 197 353 288 150 550 206 295 90 -153 -334 152 540 321 670 125 757 1092 446 171 25 224 -282 82 -35 -278 151 114 -225 -363 -253 -318 -335 -308 -388 -430 -631 -553 -471 -441 -472 -439 -603 -610 -517 -440 -258 -125 -192 -7 73 75 38 -117 4 128 111 -70 69 -132 -260 -310 181 126 253 100 -712 -703 -515 -392 -295 -31 -108 -151 -55 -17 30 169 -6 -89 -58 -203 411 609 490 779 612 635 671 279 95 141 360 792 1056 1543 1022 -139 189 -219 231 594 185 351 142 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