File name: Pandora229s1_Daegu_20250304_L2Fit_fwvt1c4d20221031p1-8.txt File generation date: 20250305T075027.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Sunyoung Park Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 229 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora229_OF_v3d20220728.txt Instrument calibration file used: Pandora229s1_CF_v4d20221031.txt Level 1 file used: Pandora229s1_Daegu_20250304_L1_smca1c4d20221031p1-8.txt Full location name: Kyungpook National University Short location name: Daegu Country of location: Korea, Republic of Location latitude [deg]: 35.8869 Location longitude [deg]: 128.6061 Location altitude [m]: 44 Local noon date: 20250304 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 3 adding wavelength change parameters to OoB First and last pixel inside fitting window: 1615 1764 Nominal wavelengths inside fitting window [nm]: 492.0542 492.1755 492.2967 492.4180 492.5392 492.6604 492.7816 492.9027 493.0239 493.1450 493.2661 493.3872 493.5083 493.6294 493.7504 493.8715 493.9925 494.1135 494.2345 494.3554 494.4764 494.5973 494.7182 494.8391 494.9600 495.0809 495.2017 495.3225 495.4434 495.5642 495.6849 495.8057 495.9264 496.0472 496.1679 496.2886 496.4093 496.5299 496.6506 496.7712 496.8918 497.0124 497.1330 497.2536 497.3741 497.4946 497.6152 497.7356 497.8561 497.9766 498.0970 498.2175 498.3379 498.4583 498.5786 498.6990 498.8193 498.9397 499.0600 499.1803 499.3006 499.4208 499.5411 499.6613 499.7815 499.9017 500.0219 500.1420 500.2622 500.3823 500.5024 500.6225 500.7426 500.8626 500.9827 501.1027 501.2227 501.3427 501.4626 501.5826 501.7025 501.8225 501.9424 502.0623 502.1821 502.3020 502.4218 502.5416 502.6614 502.7812 502.9010 503.0207 503.1405 503.2602 503.3799 503.4996 503.6192 503.7389 503.8585 503.9781 504.0977 504.2173 504.3369 504.4564 504.5760 504.6955 504.8150 504.9344 505.0539 505.1733 505.2928 505.4122 505.5316 505.6510 505.7703 505.8897 506.0090 506.1283 506.2476 506.3669 506.4861 506.6054 506.7246 506.8438 506.9630 507.0821 507.2013 507.3204 507.4395 507.5586 507.6777 507.7968 507.9159 508.0349 508.1539 508.2729 508.3919 508.5108 508.6298 508.7487 508.8676 508.9865 509.1054 509.2243 509.3431 509.4619 509.5808 509.6996 509.8183 509.9371 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250304T062433.4Z 9194.267053 342 1 51.58 2 57.62 231.70 20.02 146.28 0.00 1 0.00 1 0 22 3.847e-03 3.806e-03 1.466e-04 1.463e-04 1.427674e+03 8.009545e+00 1.071227e+02 -6.000000e+00 1.998928e+02 280.18 -2.00 20.00 -2.00 505.26 0.00e+00 5.853382e-04 3.898970e-06 3.404619e-05 -6.000000e+00 1.049166e-04 280.18 -2.00 20.00 -2.00 500.43 0.00e+00 1.406220e-01 2.800379e-03 1.158543e-02 -6.000000e+00 7.390757e-02 226.12 -2.00 3.41 -2.00 502.03 0.00e+00 1.861 0.000 489.00 513.00 1 3.8799e+00 2.1400e-04 2.9388e-03 -6.0000e+00 5.6493e-03 1.5081e-03 5.6166e-05 2.9917e-04 -6.0000e+00 1.4852e-03 3.0478e-02 1.5489e-03 1.1563e-05 1.6135e-05 -6.0000e+00 3.1092e-04 2.6080e-02 6.5893e-05 11 9 0 11 16 0 99.98 22.80 1.46 0.02608 0.03682 694 113 1 2 0 74.320 25.58 20.29 22.80 8.67 4.5 898.68 -972 -576 -142 229 420 459 699 628 423 301 116 -84 -296 -526 -403 -294 -120 120 258 322 218 177 266 200 326 371 434 -63 -297 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76 242 377 484 578 665 662 546 429 256 71 104 98 216 296 224 214 308 316 208 52 -134 -345 -405 -389 -154 81 161 162 233 239 228 318 425 293 -3 -315 -572 -622 -573 SQ 20250304T062854.6Z 9194.270076 345 1 8.41 2 58.31 232.68 19.54 148.90 0.00 1 0.00 1 0 22 3.845e-03 3.814e-03 1.467e-04 1.464e-04 1.418746e+03 7.940932e+00 1.065275e+02 -6.000000e+00 1.998069e+02 280.18 -2.00 20.00 -2.00 505.25 0.00e+00 5.692411e-04 3.903010e-06 3.301332e-05 -6.000000e+00 1.048525e-04 280.18 -2.00 20.00 -2.00 500.47 0.00e+00 1.455596e-01 2.794150e-03 1.150215e-02 -6.000000e+00 7.384196e-02 226.12 -2.00 3.41 -2.00 502.05 0.00e+00 1.897 0.000 489.00 513.00 1 2.1123e+00 2.1343e-04 2.9772e-03 -6.0000e+00 5.6446e-03 -1.9582e-04 5.6109e-05 2.9975e-04 -6.0000e+00 1.4833e-03 1.7756e-01 1.1332e-03 1.1562e-05 1.6164e-05 -6.0000e+00 3.1067e-04 2.4054e-02 9.9709e-05 11 9 0 11 16 0 65.70 22.80 1.45 0.02405 0.03191 507 83 1 2 0 16.510 25.58 20.07 22.80 9.03 4.6 900.92 -958 -576 -163 226 425 470 670 631 389 312 121 -44 -302 -467 -386 -290 -127 116 256 323 224 182 262 189 354 370 407 -58 -326 -763 -651 -541 -162 122 454 301 44 -52 -228 -220 -173 68 192 395 446 465 347 272 -61 -357 -763 -948 -835 -619 -220 69 255 250 250 137 260 359 424 325 219 105 6 -196 -415 -513 -463 -283 -51 22 57 -75 -331 -482 -609 -478 -399 -324 -240 -272 -20 -34 -140 -236 -140 -140 97 326 449 435 301 206 32 -455 -704 -821 -748 -462 -79 102 259 -59 -359 -473 -450 -223 42 251 397 479 586 674 672 552 403 257 89 93 91 219 305 249 188 312 331 209 68 -164 -388 -396 -413 -196 74 189 166 246 236 236 330 437 313 -11 -344 -631 -630 -586 -929 -571 -163 234 435 491 712 674 412 325 124 -44 -310 -474 -393 -298 -129 121 267 337 234 191 273 198 373 388 425 -60 -332 -755 -642 -538 -165 127 482 317 46 -53 -232 -228 -175 69 199 413 470 489 361 279 -61 -358 -743 -931 -816 -601 -222 69 261 256 254 139 265 369 436 333 221 104 6 -196 -409 -497 -450 -277 -50 22 56 -75 -323 -464 -582 -457 -386 -317 -234 -263 -20 -34 -137 -232 -138 -139 97 323 451 433 302 204 31 -440 -665 -770 -707 -436 -78 101 258 -59 -357 -463 -441 -222 41 251 401 487 596 673 675 550 406 255 87 90 88 215 299 244 184 304 323 204 65 -158 -371 -374 -393 -187 73 186 162 241 232 233 328 435 311 -11 -335 -600 -594 -558 SQ 20250304T062903.1Z 9194.270175 345 2 8.39 2 58.34 232.71 19.53 148.99 0.00 1 0.00 1 0 22 3.841e-03 3.811e-03 1.477e-04 1.474e-04 1.429662e+03 8.010927e+00 1.083884e+02 -6.000000e+00 1.996124e+02 280.18 -2.00 20.00 -2.00 505.25 0.00e+00 5.593071e-04 3.935650e-06 3.259458e-05 -6.000000e+00 1.047508e-04 280.18 -2.00 20.00 -2.00 500.46 0.00e+00 1.490960e-01 2.817059e-03 1.133578e-02 -6.000000e+00 7.377085e-02 226.12 -2.00 3.41 -2.00 502.05 0.00e+00 1.898 0.000 489.00 513.00 1 2.1231e+00 2.1527e-04 2.9728e-03 -6.0000e+00 5.6392e-03 -3.3344e-04 5.6576e-05 2.9868e-04 -6.0000e+00 1.4819e-03 1.7560e-01 1.1276e-03 1.1643e-05 1.6312e-05 -6.0000e+00 3.1037e-04 2.4259e-02 9.7896e-05 11 9 0 11 16 0 52.57 22.80 1.45 0.02426 0.03208 507 83 1 2 0 16.510 25.58 20.07 22.80 9.03 4.6 900.92 -961 -575 -166 225 452 463 674 639 401 303 144 -63 -265 -490 -365 -301 -116 133 246 346 219 184 265 216 324 373 443 -45 -322 -752 -712 -548 -153 116 435 292 46 -87 -228 -243 -163 68 214 382 437 450 351 266 -57 -335 -783 -929 -828 -615 -232 88 281 240 227 135 255 349 423 344 214 109 -22 -195 -400 -540 -448 -277 -42 -11 59 -56 -303 -464 -605 -474 -425 -340 -224 -274 -44 -47 -149 -242 -129 -149 91 289 449 437 323 234 49 -467 -723 -833 -770 -456 -42 113 254 -67 -367 -472 -444 -208 76 248 390 475 574 667 666 526 402 256 63 89 93 192 305 206 211 296 335 188 71 -160 -386 -413 -400 -200 105 189 144 222 249 232 357 422 321 -4 -336 -582 -625 -577 -928 -567 -166 232 474 482 714 680 423 314 148 -66 -271 -497 -369 -307 -117 138 263 370 228 192 275 226 340 391 461 -48 -327 -762 -720 -544 -156 121 460 306 47 -89 -237 -251 -169 69 220 398 459 471 364 272 -59 -335 -760 -909 -807 -595 -233 89 286 245 230 137 259 357 433 351 216 108 -22 -194 -393 -522 -434 -271 -41 -11 58 -56 -294 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