File name: Pandora120s1_Davos_20240817_L2Fit_fout2c1d20200806p1-8.txt File generation date: 20240817T233023.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v1d20200806.txt Level 1 file used: Pandora120s1_Davos_20240817_L1_smca1c1d20200806p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8129 Location longitude [deg]: 9.8437 Location altitude [m]: 1590 Local noon date: 20240817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1371 305.2785 305.4199 305.5613 305.7027 305.8441 305.9855 306.1268 306.2682 306.4095 306.5508 306.6922 306.8335 306.9748 307.1160 307.2573 307.3986 307.5398 307.6811 307.8223 307.9635 308.1047 308.2459 308.3871 308.5282 308.6694 308.8105 308.9517 309.0928 309.2339 309.3750 309.5161 309.6572 309.7982 309.9393 310.0803 310.2214 310.3624 310.5034 310.6444 310.7854 310.9264 311.0673 311.2083 311.3492 311.4902 311.6311 311.7720 311.9129 312.0538 312.1946 312.3355 312.4763 312.6172 312.7580 312.8988 313.0396 313.1804 313.3212 313.4620 313.6027 313.7435 313.8842 314.0249 314.1657 314.3064 314.4470 314.5877 314.7284 314.8690 315.0097 315.1503 315.2909 315.4316 315.5722 315.7127 315.8533 315.9939 316.1344 316.2750 316.4155 316.5560 316.6965 316.8370 316.9775 317.1180 317.2585 317.3989 317.5393 317.6798 317.8202 317.9606 318.1010 318.2414 318.3817 318.5221 318.6624 318.8028 318.9431 319.0834 319.2237 319.3640 319.5043 319.6446 319.7848 319.9251 320.0653 320.2055 320.3457 320.4859 320.6261 320.7663 320.9064 321.0466 321.1867 321.3269 321.4670 321.6071 321.7472 321.8873 322.0273 322.1674 322.3075 322.4475 322.5875 322.7275 322.8675 323.0075 323.1475 323.2875 323.4274 323.5674 323.7073 323.8472 323.9871 324.1270 324.2669 324.4068 324.5467 324.6865 324.8264 324.9662 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20240817T055940.4Z 8995.249774 441 1 49.68 2 74.44 87.10 138.64 281.40 0.00 1 0.00 1 0 17 1.809e-01 1.625e-02 5.025e-02 3.210e-03 4.579921e-01 1.591832e-03 5.490192e-03 -6.000000e+00 1.004146e-01 230.98 -2.00 3.62 -2.00 319.16 0.00e+00 3.479730e-03 3.849596e-04 5.502311e-04 -6.000000e+00 4.315938e-03 278.16 -2.00 20.00 -2.00 318.53 0.00e+00 3.662 0.001 302.00 328.00 3 4.9565e+00 4.4197e-03 3.9264e-02 -6.0000e+00 2.5212e-01 6.3473e-02 5.1176e-03 2.4665e-02 -6.0000e+00 2.7399e-01 -7.3260e-02 3.9004e-03 1.2664e-02 -6.0000e+00 1.6220e-01 3.2591e-02 2.0707e-03 4.7978e-03 -6.0000e+00 6.8965e-02 1.0056e-04 -5.8170e-04 8.2165e-05 3.9111e-05 -6.0000e+00 4.3646e-03 -6.5602e-03 0.0000e+00 12 9 9 12 32 32 83.02 15.57 0.12 -0.00656 -0.01093 13 3 1 8 0 3820.780 15.00 15.57 21.71 20.87 21.17 28.7 853.93 -44779 -11324 52390 -67641 41727 30223 -6190 -65723 114628 -74870 4637 -70986 6125 -32804 -12058 4598 -1412 -20218 1265 4418 -18957 3074 13441 -3634 -8832 -12756 3909 646 -6903 3170 3752 -11248 -1608 7249 -7010 -4123 7534 11545 5533 3839 -6911 11172 3954 6955 -2930 7481 6736 -2955 520 -222 11452 5680 4709 5235 1280 1179 -4865 3830 2198 -790 2857 1935 -5822 3901 -310 3170 -1589 1302 1920 -1931 -1301 -1302 -27 -920 -509 433 2360 -1567 -3460 -307 -1737 -1587 -2915 -2454 532 643 1187 1295 1336 -5442 11 566 -1680 822 -21 679 1337 -864 271 -680 -1110 -465 -444 -298 -1486 541 -473 -315 358 737 309 753 97 40 730 495 -599 -149 1135 -677 164 1316 959 1417 962 640 328 5 68 -1933 -758 279 208 174 376 -129 -473 420 375 160 -1677 -103 -1478 -293 804 -2810 575 473 -155 -3415 1076 -4758 134 -5044 251 -2444 -876 315 -110 -2050 109 386 -2077 267 1119 -386 -1042 -1613 406 65 -746 341 469 -1863 -270 1073 -1101 -662 1245 2241 1384 1009 -2161 3058 1200 2056 -974 2261 2051 -1003 174 -80 4077 2318 2084 2430 634 603 -2438 1866 1063 -399 1505 1056 -3836 2479 -195 1795 -925 778 1332 -1443 -1018 -1023 -20 -695 -341 259 1324 -968 -2553 -235 -1526 -1524 -2748 -2455 557 712 1357 1486 1488 -6017 11 536 -1589 825 -22 765 1701 -1159 360 -907 -1335 -540 -523 -361 -1927 718 -627 -445 552 1164 512 1216 149 61 1025 697 -893 -223 1786 -1093 254 2070 1460 2043 1337 895 467 8 106 -3302 -1330 469 367 330 710 -250 -937 829 712 305 -3070 -179 SU 20240817T060819.9Z 8995.255786 447 1 51.01 2 72.96 88.66 140.00 283.28 0.00 1 0.00 1 0 17 1.036e-01 1.160e-02 2.062e-02 2.452e-03 4.300172e-01 1.213496e-03 5.181383e-03 -6.000000e+00 5.754160e-02 230.98 -2.00 3.62 -2.00 318.77 0.00e+00 1.033907e-03 2.600337e-04 2.232636e-04 -6.000000e+00 2.472742e-03 278.16 -2.00 20.00 -2.00 318.14 0.00e+00 3.363 0.001 302.00 328.00 3 4.8041e+00 3.3260e-03 3.6401e-02 -6.0000e+00 1.4448e-01 3.9985e-02 3.8086e-03 2.3120e-02 -6.0000e+00 1.5699e-01 -5.8488e-02 2.7278e-03 1.1389e-02 -6.0000e+00 9.2942e-02 2.7860e-02 1.4461e-03 3.3364e-03 -6.0000e+00 3.9526e-02 1.5625e-04 -1.6685e-04 6.3033e-05 2.9236e-05 -6.0000e+00 2.5005e-03 -8.0261e-03 0.0000e+00 12 9 8 11 40 0 31.14 15.60 -0.03 -0.00803 -0.00928 18 4 1 8 0 2833.370 15.01 15.60 22.55 20.87 21.27 29.5 859.41 -39540 -9403 -7108 -22157 -14435 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-637 425 654 -1282 -294 -360 -243 -929 -213 -2754 196 -95 -1972 -1576 -1641 -1733 -2504 -1679 257 620 770 1147 843 990 239 -296 -924 538 398 413 1698 -645 443 -487 -1737 -2489 -328 -657 -1535 -143 -298 -379 576 205 1418 834 621 -63 877 344 -624 -169 439 -1159 40 1078 1176 1592 716 733 581 -469 -54 1394 -450 -523 470 -304 314 227 -515 502 -472 -129 -1243 -1106 SU 20240817T061130.7Z 8995.257994 450 1 51.13 2 72.41 89.24 140.49 283.99 0.00 1 0.00 1 0 17 1.031e-01 1.233e-02 1.694e-02 2.254e-03 4.181346e-01 1.113568e-03 5.041359e-03 -6.000000e+00 5.725657e-02 230.98 -2.00 3.62 -2.00 318.62 0.00e+00 4.555637e-04 2.263149e-04 1.787735e-04 -6.000000e+00 2.460583e-03 278.16 -2.00 20.00 -2.00 317.96 0.00e+00 3.265 0.001 302.00 328.00 3 4.7523e+00 3.0406e-03 3.5355e-02 -6.0000e+00 1.4376e-01 2.7157e-02 3.4767e-03 2.2461e-02 -6.0000e+00 1.5622e-01 -3.7002e-02 2.4574e-03 1.1047e-02 -6.0000e+00 9.2483e-02 1.5734e-02 1.2998e-03 3.1326e-03 -6.0000e+00 3.9329e-02 1.8130e-04 -4.9701e-05 5.7977e-05 2.6776e-05 -6.0000e+00 2.4882e-03 -7.7535e-03 0.0000e+00 12 9 8 11 40 0 47.91 15.62 0.19 -0.00775 -0.00813 20 4 1 8 0 2555.860 15.01 15.62 22.93 20.96 21.27 29.5 861.03 -28447 -8269 -18539 -38587 -19231 -2713 -46172 -37909 28500 -33115 -8993 -36956 -5432 -15379 8917 6012 -3077 -10430 -6159 1981 -10431 483 4278 12270 -12086 -5522 1176 -1830 -2914 -122 989 -6462 54032 7280 -7964 -4513 1349 3700 4128 1299 -3009 3821 2908 2890 -2586 3308 1514 -47 -664 658 4881 2757 2166 2176 668 1342 -1772 1701 1214 456 2326 1191 -2299 788 -80 1600 -1226 1130 1318 -1522 121 -742 444 -302 -64 -3231 -1925 -849 -2185 -3745 -1099 -1313 -2019 -1370 249 -138 655 830 429 920 1152 402 -1076 518 451 565 1485 27 113 -615 -1527 -1711 -232 -460 -1229 -203 -154 -209 88 286 803 578 250 -169 192 4 -463 30 591 -626 202 713 644 1065 148 332 499 110 105 721 -298 -155 -79 -5 115 -67 -284 270 -123 269 -1303 -247 -1193 -307 -770 -1750 -714 -88 -2608 -2291 983 -2161 -460 -2843 -370 -1392 747 569 -338 -1320 -784 243 -1444 60 547 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