File name: Pandora120s1_Davos_20240822_L2Fit_fout2c5d20240814p1-8.txt File generation date: 20241127T222617.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v5d20240814.txt Level 1 file used: Pandora120s1_Davos_20240822_L1_smca1c5d20240814p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8129 Location longitude [deg]: 9.8437 Location altitude [m]: 1590 Local noon date: 20240822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1159 305.2573 305.3987 305.5401 305.6814 305.8228 305.9641 306.1054 306.2467 306.3880 306.5293 306.6706 306.8118 306.9531 307.0943 307.2356 307.3768 307.5180 307.6592 307.8004 307.9415 308.0827 308.2239 308.3650 308.5061 308.6473 308.7884 308.9295 309.0706 309.2116 309.3527 309.4938 309.6348 309.7758 309.9169 310.0579 310.1989 310.3399 310.4808 310.6218 310.7627 310.9037 311.0446 311.1855 311.3265 311.4674 311.6082 311.7491 311.8900 312.0308 312.1717 312.3125 312.4533 312.5941 312.7349 312.8757 313.0165 313.1573 313.2980 313.4388 313.5795 313.7202 313.8609 314.0016 314.1423 314.2830 314.4237 314.5643 314.7050 314.8456 314.9862 315.1268 315.2674 315.4080 315.5486 315.6891 315.8297 315.9702 316.1108 316.2513 316.3918 316.5323 316.6728 316.8133 316.9537 317.0942 317.2346 317.3750 317.5155 317.6559 317.7963 317.9366 318.0770 318.2174 318.3577 318.4981 318.6384 318.7787 318.9190 319.0593 319.1996 319.3399 319.4801 319.6204 319.7606 319.9008 320.0410 320.1813 320.3214 320.4616 320.6018 320.7420 320.8821 321.0222 321.1624 321.3025 321.4426 321.5827 321.7227 321.8628 322.0029 322.1429 322.2829 322.4230 322.5630 322.7030 322.8430 322.9829 323.1229 323.2629 323.4028 323.5427 323.6827 323.8226 323.9625 324.1023 324.2422 324.3821 324.5219 324.6618 324.8016 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240822T055347.1Z 9000.245684 543 1 8.91 2 76.42 87.44 73.32 252.47 0.00 1 0.00 1 0 17 4.647e-01 8.519e-03 2.734e-01 6.850e-03 5.665665e-01 3.476544e-03 6.606811e-03 -6.000000e+00 2.611232e-01 230.48 -2.00 3.62 -2.00 320.08 0.00e+00 4.903642e-04 1.016605e-03 3.388011e-04 -6.000000e+00 1.094264e-02 277.63 -2.00 20.00 -2.00 319.76 0.00e+00 4.160 0.001 302.00 328.00 3 3.9606e+00 9.7423e-03 4.6294e-02 -6.0000e+00 6.5862e-01 1.9549e-02 1.1923e-02 3.0573e-02 -6.0000e+00 7.1795e-01 -4.5528e-03 1.2310e-02 1.5868e-02 -6.0000e+00 4.2066e-01 -6.5773e-03 6.5358e-03 4.8397e-03 -6.0000e+00 1.7597e-01 1.6310e-04 -5.9603e-05 1.8196e-04 4.5838e-05 -6.0000e+00 1.1838e-02 1.5454e-02 0.0000e+00 12 9 1 12 9 1 -83.44 14.92 0.23 0.01545 0.01501 4 6 2 8 0 1780.520 15.00 14.92 17.38 20.35 20.77 28.1 830.49 98065 288353 -8513 282785 206437 170595 -27387 62069 -46616 900000 -20046 170971 -26901 -5845 -17928 16973 17167 35512 31349 -16270 -24640 -8513 6904 -14574 20317 -25900 24860 -4764 18275 4811 23226 8236 9086 -6964 4624 -13059 -644 3032 -6684 -4034 -3862 -2136 -1878 -830 -6714 4251 -5654 4516 -1714 972 -2311 859 2241 -210 1145 701 1447 950 713 450 2377 580 3441 -1153 227 333 909 164 1063 -704 720 -443 1152 1119 1439 884 -1651 -1091 -1541 2 -1898 -1314 -1565 22 -723 1333 -672 1023 -28 963 -222 -222 433 392 -77 1310 593 471 262 -649 -594 405 870 -2160 -1380 -2743 -181 492 478 462 223 -448 -73 336 -43 673 412 259 8 -181 -408 202 -572 848 170 1000 905 550 -57 51 -236 -483 291 -700 -150 -482 471 -50 -13 337 -132 -32 655 1926 -60 1888 1379 1139 -241 415 -655 900000 -240 1142 -520 -115 -485 370 410 774 760 -669 -1109 -332 252 -733 778 -1639 926 -228 700 238 1143 550 674 -595 333 -1193 -61 344 -975 -661 -686 -394 -356 -157 -1370 789 -1178 876 -370 223 -616 244 682 -70 393 252 520 334 245 157 879 235 1528 -574 108 151 411 80 576 -435 464 -289 707 633 759 427 -798 -567 -906 1 -1430 -1083 -1365 19 -685 1308 -696 1044 -28 885 -199 -187 361 361 -79 1447 723 632 354 -827 -704 431 929 -2590 -1673 -3529 -240 677 704 749 367 -739 -118 507 -64 992 616 414 13 -294 -661 313 -863 1251 242 1396 1254 830 -93 90 -427 -910 558 -1406 -314 -1036 987 -105 -27 681 -251 -62 SS 20240822T055421.9Z 9000.246086 544 1 9.73 2 76.32 87.55 73.41 252.59 0.00 1 0.00 1 0 25 1.668e-01 6.205e-03 1.571e-01 3.575e-03 5.610088e-01 1.804866e-03 6.555204e-03 -6.000000e+00 9.372438e-02 230.48 -2.00 3.62 -2.00 319.99 0.00e+00 1.583846e-03 5.145251e-04 3.255071e-04 -6.000000e+00 3.742783e-03 277.63 -2.00 20.00 -2.00 319.68 0.00e+00 4.132 0.001 302.00 328.00 3 2.9516e+00 5.0364e-03 4.5888e-02 -6.0000e+00 2.3627e-01 3.6867e-02 6.0954e-03 3.0222e-02 -6.0000e+00 2.5752e-01 -2.4285e-02 6.1323e-03 1.5649e-02 -6.0000e+00 1.5099e-01 2.3891e-03 3.2702e-03 4.7564e-03 -6.0000e+00 6.3060e-02 4.5713e-04 -2.9030e-05 9.4286e-05 4.4103e-05 -6.0000e+00 4.2203e-03 1.5824e-02 0.0000e+00 12 1 1 12 1 1 -6.19 14.92 0.22 0.01582 0.01561 14 16 2 8 0 647.600 15.00 14.92 17.39 20.46 20.77 28.1 830.40 123727 -39551 48561 28931 -33674 -9599 -67613 1735 -61220 26998 -33830 5835 -43765 13184 -21911 40343 -10794 22455 -16172 8065 -9570 9100 -3685 1080 -4327 -8071 2991 -7748 3088 -10949 5051 -8371 3740 -11041 6122 -3373 262 -5674 475 -2583 417 391 -244 -1471 430 2810 -2978 -507 -2055 2448 778 2721 -777 2232 -244 1904 -491 -91 129 2075 932 1656 2352 795 1412 520 1541 -207 1043 -1004 555 -822 1258 -306 76 -1312 -1376 -641 18 -1347 -834 -1636 -1404 -518 -562 22 -1067 527 57 1110 538 1037 224 1401 801 1048 581 -134 -175 -402 -159 308 -124 -1060 -1443 -1386 -133 -133 426 -10 140 259 282 26 261 623 176 -196 -445 -477 -424 290 -134 640 2 939 783 504 -131 179 -92 31 -68 -452 -168 251 0 -234 -97 30 -105 96 431 -424 221 147 -298 -70 -997 15 -1100 227 -508 70 -1103 237 -682 768 -376 614 -694 285 -405 325 -162 50 -226 -455 148 -407 147 -681 320 -707 313 -1048 463 -298 26 -742 71 -461 78 77 -50 -309 90 585 -668 -114 -491 610 205 773 -248 737 -86 682 -181 -33 45 719 354 705 1121 411 704 249 731 -108 583 -642 369 -554 793 -181 43 -680 -697 -349 11 -950 -626 -1360 -1227 -478 -557 22 -1094 533 56 1066 480 862 188 1276 794 1188 713 -181 -238 -513 -192 335 -137 -1287 -1759 -1768 -178 -182 642 -16 233 426 442 39 380 905 270 -305 -729 -781 -667 459 -205 932 3 1312 1130 777 -216 320 -165 57 -133 -909 -355 537 -1 -489 -204 58 -204 181 SS 20240822T055530.4Z 9000.246879 546 1 33.17 2 76.12 87.75 73.59 252.81 0.00 1 0.00 1 0 25 9.255e-02 4.942e-03 4.393e-02 1.288e-03 5.581237e-01 6.577187e-04 6.498898e-03 -6.000000e+00 5.199763e-02 230.48 -2.00 3.62 -2.00 320.25 0.00e+00 7.308956e-04 1.973918e-04 3.431039e-04 -6.000000e+00 2.076623e-03 277.63 -2.00 20.00 -2.00 319.93 0.00e+00 4.077 0.001 302.00 328.00 3 1.9472e+00 1.8497e-03 4.5477e-02 -6.0000e+00 1.3108e-01 3.2014e-02 2.2793e-03 3.0108e-02 -6.0000e+00 1.4287e-01 -9.3747e-03 2.3712e-03 1.5717e-02 -6.0000e+00 8.3770e-02 -6.5928e-03 1.2519e-03 4.8505e-03 -6.0000e+00 3.4983e-02 1.3081e-03 -1.0773e-04 3.4790e-05 4.7063e-05 -6.0000e+00 2.3416e-03 1.6446e-02 0.0000e+00 12 1 1 12 1 1 86.33 14.92 0.24 0.01645 0.01564 138 43 2 8 0 236.880 15.00 14.92 17.38 20.35 20.77 28.1 830.35 -27524 -32499 -23911 -35427 -36347 -45409 -33031 -19982 -21223 -26586 -24757 -20039 -14117 -10294 -6599 -8217 -6642 -4819 -4679 -3323 -9891 -5397 -5160 -6366 -4177 -1734 -6140 -3485 -1496 -1792 -1318 1375 1625 -2822 -3053 -3425 -1199 -2215 -978 -1273 -742 -905 -507 -1344 -555 -843 -650 -508 -258 1138 934 357 894 825 468 739 192 834 610 1158 1066 1070 1812 817 377 1141 288 884 97 193 -9 -307 203 409 -15 414 -315 387 -229 -730 -971 -1897 -1389 -1023 -667 -418 -28 392 532 994 989 1041 1269 1064 414 710 488 -25 -160 -153 -107 147 49 -1210 -1193 -833 -637 -1 -154 -119 -319 258 154 197 506 551 140 -49 -521 -692 -175 85 -233 415 284 861 1178 321 259 164 14 112 124 -144 -174 59 52 -208 -371 -126 -133 269 -200 -278 -192 -294 -283 -405 -299 -186 -224 -311 -298 -274 -230 -203 -152 -220 -192 -149 -155 -114 -364 -193 -201 -277 -192 -81 -292 -154 -65 -89 -77 92 121 -214 -220 -263 -106 -245 -131 -197 -124 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