File name: Pandora120s1_Davos_20240901_L2Fit_fwvt1c5d20240814p1-8.txt File generation date: 20241127T223133.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v5d20240814.txt Level 1 file used: Pandora120s1_Davos_20240901_L1_smca1c5d20240814p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8129 Location longitude [deg]: 9.8437 Location altitude [m]: 1590 Local noon date: 20240901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1788 Nominal wavelengths inside fitting window [nm]: 492.0841 492.2060 492.3279 492.4497 492.5716 492.6935 492.8153 492.9371 493.0589 493.1807 493.3024 493.4242 493.5459 493.6676 493.7893 493.9110 494.0327 494.1543 494.2759 494.3975 494.5191 494.6407 494.7623 494.8838 495.0054 495.1269 495.2484 495.3698 495.4913 495.6127 495.7342 495.8556 495.9770 496.0984 496.2197 496.3411 496.4624 496.5837 496.7050 496.8263 496.9476 497.0688 497.1900 497.3112 497.4324 497.5536 497.6748 497.7959 497.9171 498.0382 498.1593 498.2804 498.4014 498.5225 498.6435 498.7645 498.8855 499.0065 499.1274 499.2484 499.3693 499.4902 499.6111 499.7320 499.8529 499.9737 500.0945 500.2153 500.3361 500.4569 500.5777 500.6984 500.8191 500.9399 501.0606 501.1812 501.3019 501.4225 501.5432 501.6638 501.7844 501.9049 502.0255 502.1460 502.2666 502.3871 502.5076 502.6280 502.7485 502.8689 502.9894 503.1098 503.2302 503.3505 503.4709 503.5912 503.7115 503.8318 503.9521 504.0724 504.1927 504.3129 504.4331 504.5533 504.6735 504.7937 504.9138 505.0340 505.1541 505.2742 505.3943 505.5143 505.6344 505.7544 505.8744 505.9944 506.1144 506.2344 506.3543 506.4743 506.5942 506.7141 506.8340 506.9538 507.0737 507.1935 507.3133 507.4331 507.5529 507.6727 507.7924 507.9121 508.0318 508.1515 508.2712 508.3909 508.5105 508.6301 508.7497 508.8693 508.9889 509.1085 509.2280 509.3475 509.4670 509.5865 509.7060 509.8254 509.9449 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240901T062242.4Z 9010.265769 134 1 8.88 2 73.51 95.82 54.40 101.59 0.00 1 0.00 1 0 15 2.081e-03 2.064e-03 1.496e-04 1.493e-04 3.199479e+03 8.808086e+00 2.370687e+02 -6.000000e+00 1.110921e+02 276.59 -2.00 20.00 -2.00 505.26 0.00e+00 5.837329e-04 4.016883e-06 3.699404e-05 -6.000000e+00 5.716846e-05 276.59 -2.00 20.00 -2.00 500.46 0.00e+00 2.917568e-01 2.944364e-03 2.396936e-02 -6.000000e+00 4.120725e-02 229.48 -2.00 3.62 -2.00 502.05 0.00e+00 3.469 0.001 489.00 513.00 1 2.0935e+00 2.2484e-04 4.6661e-03 -6.0000e+00 3.1482e-03 -8.5810e-03 5.8438e-05 6.2328e-04 -6.0000e+00 8.2361e-04 1.5516e-01 2.2125e-04 1.3606e-05 3.3405e-05 -6.0000e+00 1.9586e-04 1.7582e-02 -1.5219e-04 10 0 0 10 0 0 22.27 15.18 0.37 0.01758 0.01912 521 113 2 2 0 16.650 15.00 15.18 18.65 20.67 20.96 28.9 835.21 -400 -293 -49 60 177 477 386 280 321 152 184 15 -148 -78 -185 -89 4 54 39 -21 118 168 149 241 121 127 36 -33 -267 -231 -250 -325 -28 94 -106 18 109 24 -13 53 34 89 157 222 182 187 142 71 -63 -337 -321 -419 -481 -237 -225 -170 -32 96 159 163 268 178 208 148 74 69 -95 -204 -309 -292 -232 -325 -124 -86 -190 -203 -148 -188 -270 -221 -187 -258 -118 34 -106 -2 137 50 51 85 206 166 96 120 213 -2 -165 -180 -377 -430 -344 -360 -161 -323 -239 -141 -212 -117 -19 -79 -54 100 235 343 432 405 348 176 219 165 77 227 306 89 168 252 111 116 268 58 46 13 -157 -119 64 -52 -57 158 212 128 178 160 51 43 5 -150 -267 -333 -398 -389 -291 -48 62 179 492 405 296 338 158 188 15 -152 -80 -188 -91 5 56 42 -22 126 180 160 249 126 133 37 -35 -273 -229 -245 -323 -29 97 -111 18 112 25 -14 55 36 91 162 231 190 195 147 73 -65 -338 -312 -401 -460 -232 -228 -171 -33 98 162 165 273 182 213 151 74 68 -96 -204 -306 -285 -227 -321 -124 -85 -185 -202 -144 -181 -259 -212 -182 -253 -116 33 -103 -2 134 49 50 84 206 168 98 121 211 -2 -156 -171 -353 -401 -326 -342 -159 -318 -235 -142 -209 -115 -19 -79 -53 100 235 346 438 413 355 179 218 162 75 219 297 87 164 245 108 112 260 56 45 13 -150 -114 62 -50 -56 158 213 129 180 158 51 43 5 -149 -259 -318 -381 SQ 20240901T062251.8Z 9010.265877 134 2 9.36 2 73.48 95.85 54.38 101.62 0.00 1 0.00 1 0 15 2.062e-03 2.054e-03 1.648e-04 1.645e-04 3.200240e+03 9.716044e+00 2.369605e+02 -6.000000e+00 1.100325e+02 276.59 -2.00 20.00 -2.00 505.26 0.00e+00 5.659732e-04 4.431264e-06 3.615927e-05 -6.000000e+00 5.662359e-05 276.59 -2.00 20.00 -2.00 500.46 0.00e+00 2.914012e-01 3.250518e-03 2.412162e-02 -6.000000e+00 4.081523e-02 229.48 -2.00 3.62 -2.00 502.05 0.00e+00 3.463 0.001 489.00 513.00 1 2.2571e+00 2.4824e-04 4.6608e-03 -6.0000e+00 3.1183e-03 -8.4756e-03 6.4495e-05 6.2614e-04 -6.0000e+00 8.1580e-04 1.3187e-01 1.9810e-04 1.4987e-05 3.3628e-05 -6.0000e+00 1.9400e-04 1.8395e-02 -1.5881e-04 10 0 0 10 0 0 27.40 15.18 0.37 0.01839 0.01977 521 113 2 2 0 16.650 15.00 15.18 18.65 20.67 20.96 28.9 835.21 -434 -293 -81 25 128 470 397 318 286 130 192 19 -100 -43 -171 -78 13 66 69 -2 137 167 145 211 134 139 65 -79 -289 -256 -249 -344 -54 101 -119 -10 130 28 24 53 -5 57 130 168 181 219 179 52 -97 -291 -367 -409 -447 -233 -171 -121 -30 78 180 137 279 203 201 183 64 31 -95 -181 -336 -332 -277 -291 -175 -104 -216 -186 -161 -124 -250 -222 -221 -261 -103 68 -98 2 121 12 66 86 186 146 89 107 240 -26 -154 -169 -357 -383 -346 -360 -180 -319 -218 -101 -194 -123 -29 -96 -85 81 217 314 448 450 324 184 219 156 96 165 250 102 173 251 104 141 266 13 35 -23 -174 -105 92 -14 -44 163 217 126 172 166 74 35 -21 -139 -237 -349 -370 -414 -285 -82 25 131 491 422 340 304 137 199 19 -101 -43 -170 -79 13 69 71 -2 143 174 152 221 141 146 68 -81 -298 -256 -248 -347 -56 105 -126 -11 135 29 24 53 -5 59 135 177 191 230 187 54 -97 -295 -362 -396 -433 -231 -169 -123 -31 80 184 140 287 210 207 188 65 31 -93 -177 -324 -329 -274 -280 -171 -102 -213 -180 -153 -121 -243 -216 -209 -250 -100 66 -96 2 120 12 66 85 188 145 89 105 239 -25 -147 -157 -338 -362 -320 -346 -180 -316 -217 -99 -187 -122 -28 -94 -85 81 220 319 457 462 334 189 220 154 94 160 244 100 170 246 102 138 259 13 33 -22 -168 -98 87 -14 -44 164 212 124 170 165 74 35 -21 -138 -232 -336 -357 SQ 20240901T062301.3Z 9010.265987 134 3 9.20 2 73.46 95.88 54.35 101.65 0.00 1 0.00 1 0 15 2.094e-03 2.078e-03 1.916e-04 1.912e-04 3.200250e+03 1.127039e+01 2.387974e+02 -6.000000e+00 1.117743e+02 276.59 -2.00 20.00 -2.00 505.26 0.00e+00 5.698585e-04 5.134915e-06 3.628355e-05 -6.000000e+00 5.752232e-05 276.59 -2.00 20.00 -2.00 500.46 0.00e+00 2.936281e-01 3.769162e-03 2.371203e-02 -6.000000e+00 4.146623e-02 229.48 -2.00 3.62 -2.00 502.05 0.00e+00 3.458 0.001 489.00 513.00 1 2.5017e+00 2.8771e-04 4.6443e-03 -6.0000e+00 3.1679e-03 -8.0482e-03 7.4762e-05 6.2215e-04 -6.0000e+00 8.2890e-04 1.0329e-01 1.8309e-04 1.7384e-05 3.3880e-05 -6.0000e+00 1.9710e-04 1.9172e-02 -1.7120e-04 10 0 0 10 0 0 27.69 15.18 0.37 0.01917 0.02044 521 113 2 2 0 16.650 15.00 15.18 18.65 20.67 20.96 28.9 835.21 -457 -333 -73 20 169 453 371 309 300 137 211 9 -116 -68 -174 -56 9 111 57 -11 155 164 130 229 109 119 50 -63 -333 -316 -335 -383 -67 139 -104 54 125 40 52 74 -10 47 148 180 203 209 191 81 -33 -290 -366 -448 -478 -256 -176 -143 -14 118 173 197 237 148 212 185 98 61 -91 -166 -330 -321 -282 -282 -139 -109 -196 -176 -147 -193 -227 -205 -205 -255 -102 54 -88 -6 100 22 84 82 201 148 126 134 271 6 -145 -184 -371 -431 -342 -340 -160 -298 -239 -46 -200 -140 -51 -117 -44 118 240 331 440 427 307 178 179 132 84 159 218 121 179 240 132 148 205 -16 9 -17 -165 -70 120 -20 -45 151 217 153 152 112 82 40 -15 -146 -222 -358 -377 -434 -323 -73 20 172 471 392 329 317 143 217 9 -116 -67 -172 -56 10 116 60 -12 166 176 140 238 113 124 51 -66 -342 -315 -330 -383 -69 143 -109 56 129 41 55 78 -10 48 152 187 212 218 197 83 -34 -293 -358 -431 -460 -252 -179 -144 -14 120 176 200 242 151 217 189 99 61 -89 -167 -328 -316 -278 -280 -135 -106 -191 -169 -144 -186 -219 -198 -201 -241 -98 52 -85 -6 98 22 82 81 201 150 129 136 268 6 -137 -176 -349 -404 -326 -324 -158 -302 -235 -46 -197 -137 -51 -118 -43 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