File name: Pandora120s1_Davos_20240906_L2Fit_fout2c5d20240814p1-8.txt File generation date: 20241127T222610.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Julian Groebner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 120 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora120_OF_v5d20190819.txt Instrument calibration file used: Pandora120s1_CF_v5d20240814.txt Level 1 file used: Pandora120s1_Davos_20240906_L1_smca1c5d20240814p1-8.txt Full location name: PMOD/WRC-Davos Short location name: Davos Country of location: Switzerland Location latitude [deg]: 46.8129 Location longitude [deg]: 9.8437 Location altitude [m]: 1590 Local noon date: 20240906 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 227 368 Nominal wavelengths inside fitting window [nm]: 305.1159 305.2573 305.3987 305.5401 305.6814 305.8228 305.9641 306.1054 306.2467 306.3880 306.5293 306.6706 306.8118 306.9531 307.0943 307.2356 307.3768 307.5180 307.6592 307.8004 307.9415 308.0827 308.2239 308.3650 308.5061 308.6473 308.7884 308.9295 309.0706 309.2116 309.3527 309.4938 309.6348 309.7758 309.9169 310.0579 310.1989 310.3399 310.4808 310.6218 310.7627 310.9037 311.0446 311.1855 311.3265 311.4674 311.6082 311.7491 311.8900 312.0308 312.1717 312.3125 312.4533 312.5941 312.7349 312.8757 313.0165 313.1573 313.2980 313.4388 313.5795 313.7202 313.8609 314.0016 314.1423 314.2830 314.4237 314.5643 314.7050 314.8456 314.9862 315.1268 315.2674 315.4080 315.5486 315.6891 315.8297 315.9702 316.1108 316.2513 316.3918 316.5323 316.6728 316.8133 316.9537 317.0942 317.2346 317.3750 317.5155 317.6559 317.7963 317.9366 318.0770 318.2174 318.3577 318.4981 318.6384 318.7787 318.9190 319.0593 319.1996 319.3399 319.4801 319.6204 319.7606 319.9008 320.0410 320.1813 320.3214 320.4616 320.6018 320.7420 320.8821 321.0222 321.1624 321.3025 321.4426 321.5827 321.7227 321.8628 322.0029 322.1429 322.2829 322.4230 322.5630 322.7030 322.8430 322.9829 323.1229 323.2629 323.4028 323.5427 323.6827 323.8226 323.9625 324.1023 324.2422 324.3821 324.5219 324.6618 324.8016 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240906T061039.3Z 9015.257399 79 1 48.34 2 76.62 95.18 109.48 82.17 0.00 1 0.00 1 0 25 1.800e-01 6.253e-03 2.151e-01 4.846e-03 5.436953e-01 2.472353e-03 6.346311e-03 -6.000000e+00 1.006825e-01 228.98 -2.00 3.62 -2.00 320.34 0.00e+00 2.878341e-04 7.618055e-04 3.485111e-04 -6.000000e+00 4.038812e-03 276.06 -2.00 20.00 -2.00 320.02 0.00e+00 4.220 0.001 302.00 328.00 3 4.4725e+00 6.9935e-03 4.5634e-02 -6.0000e+00 2.5293e-01 8.2949e-02 8.6834e-03 2.9265e-02 -6.0000e+00 2.7587e-01 -7.3862e-03 9.1142e-03 1.5403e-02 -6.0000e+00 1.6193e-01 -9.6921e-03 4.8001e-03 4.8069e-03 -6.0000e+00 6.7934e-02 9.2977e-05 -4.6500e-04 1.3301e-04 4.7233e-05 -6.0000e+00 4.5507e-03 7.3713e-03 0.0000e+00 11 1 0 11 8 0 91.90 15.02 0.21 0.00737 0.00388 13 3 1 8 0 3718.070 15.00 15.02 18.26 20.56 20.87 28.9 833.00 89583 9114 103832 -17370 69474 -4402 -71325 -60377 -15789 -65205 42354 4765 -33896 -5625 -8486 -6695 -18692 -3186 3152 37820 -9378 4892 1912 19652 -11460 15801 -7431 -7603 -6998 -5907 -7108 -2511 -6449 -5478 -1459 -7050 193 -4324 3374 -7699 576 -3759 -1338 -3504 853 -6228 -674 245 2761 5026 2922 1114 -115 -307 -63 3085 -2619 1560 -424 1559 2923 2489 2271 1509 1292 2062 -111 712 1029 -272 163 14 382 379 1006 -1736 127 586 -161 -1356 912 -1085 -1165 -1768 -446 -551 -283 507 87 431 1110 913 147 1572 419 421 334 -139 -122 -463 -746 43 -593 -1097 -1098 -1055 -466 -118 131 -34 -380 239 594 458 107 740 355 -108 -584 -313 -135 166 189 124 399 1041 1265 135 -43 295 -304 306 -187 -160 -11 -56 402 -397 -275 -142 -400 394 423 54 491 -127 328 -28 -977 -870 -164 -1171 284 55 -681 -106 -200 -177 -609 -97 96 858 -343 157 69 655 -563 616 -358 -348 -334 -310 -425 -167 -500 -415 -105 -565 17 -461 409 -1206 90 -648 -232 -625 148 -1173 -121 45 538 1036 655 279 -32 -90 -19 950 -864 481 -129 469 933 897 923 663 553 830 -46 308 515 -155 98 8 221 203 477 -766 56 260 -84 -840 630 -842 -955 -1549 -394 -515 -273 488 82 393 928 714 114 1314 405 444 401 -184 -163 -585 -848 44 -608 -1228 -1305 -1309 -608 -166 194 -55 -652 405 956 686 159 1086 521 -169 -973 -521 -216 256 281 184 567 1392 1721 208 -70 524 -571 565 -365 -335 -24 -125 915 -914 -609 -296 -786 776 SS 20240906T062107.2Z 9015.264666 84 1 50.10 2 74.84 97.14 107.78 84.12 0.00 1 0.00 1 0 25 1.260e-01 7.198e-03 1.214e-01 4.034e-03 4.870782e-01 2.047504e-03 5.780352e-03 -6.000000e+00 7.050882e-02 228.98 -2.00 3.62 -2.00 320.00 0.00e+00 3.300524e-04 5.682294e-04 2.712221e-04 -6.000000e+00 2.828552e-03 276.06 -2.00 20.00 -2.00 319.68 0.00e+00 3.754 0.001 302.00 328.00 3 4.5483e+00 5.7282e-03 4.0749e-02 -6.0000e+00 1.7713e-01 5.8329e-02 6.8395e-03 2.6175e-02 -6.0000e+00 1.9320e-01 -1.1028e-02 6.5675e-03 1.3568e-02 -6.0000e+00 1.1341e-01 -2.2465e-03 3.5141e-03 4.1548e-03 -6.0000e+00 4.7573e-02 1.3507e-04 -3.0382e-04 1.1206e-04 4.2207e-05 -6.0000e+00 3.1872e-03 7.8061e-03 0.0000e+00 11 9 0 11 8 0 96.62 15.05 0.21 0.00781 0.00552 17 3 1 8 0 2946.400 14.99 15.05 18.71 20.56 20.87 29.0 835.29 -38287 102535 -24846 34262 -48992 -29497 -15297 -10123 -36669 17050 -10907 -6696 -10471 -14263 1819 -13183 1930 -3270 1133 -3456 21236 -11932 12733 -9850 1221 -16807 692 -14725 1643 -4143 2909 3598 7299 -188 -5760 -785 -8479 1716 -2526 4009 -4492 1268 -4596 2943 -1100 1282 -3459 -611 27 -746 2357 -572 1618 1044 3042 95 999 -498 684 -2271 3593 -766 3938 -236 999 994 1195 155 887 -109 -224 107 265 1182 -463 677 -898 2356 -1047 67 -1568 -1509 -1993 -665 -1063 27 -775 665 948 2507 872 -816 1817 714 617 319 665 -936 -143 -608 -569 -403 1280 -1115 -1361 -1114 -694 -197 -128 119 -52 472 -241 273 170 557 156 396 -936 -131 -350 271 130 795 402 483 698 549 171 -141 207 -67 389 149 249 -397 279 -461 69 -501 -2 -179 -557 425 -357 262 -752 -403 -206 -151 -757 226 -196 -133 -267 -440 60 -542 78 -150 53 -176 849 -669 601 -640 76 -1305 44 -1030 96 -281 214 302 657 -18 -544 -74 -1002 225 -423 722 -951 266 -1052 627 -247 283 -804 -140 6 -189 643 -175 523 361 1069 36 375 -185 244 -843 1349 -336 1839 -122 493 460 544 76 498 -66 -144 68 172 705 -251 327 -423 1135 -607 45 -1144 -1207 -1685 -590 -1017 27 -812 690 951 2305 750 -661 1480 604 594 350 825 -1232 -188 -753 -666 -428 1345 -1306 -1697 -1447 -903 -273 -195 197 -91 806 -393 410 240 780 230 620 -1570 -220 -569 423 196 1135 551 657 962 800 278 -248 380 -122 736 302 532 -869 618 -1031 148 -1025 -3 -333 SS 20240906T063115.3Z 9015.271705 86 1 52.20 2 73.13 99.06 106.14 85.99 0.00 1 0.00 1 0 25 2.739e-02 5.036e-03 8.006e-03 5.239e-04 4.450782e-01 2.628603e-04 5.351839e-03 -6.000000e+00 1.532309e-02 228.98 -2.00 3.62 -2.00 319.52 0.00e+00 5.800254e-04 6.405365e-05 2.055364e-04 -6.000000e+00 6.146712e-04 276.06 -2.00 20.00 -2.00 319.20 0.00e+00 3.394 0.001 302.00 328.00 3 1.2061e+00 7.2689e-04 3.6990e-02 -6.0000e+00 3.8494e-02 3.1909e-02 8.4311e-04 2.3811e-02 -6.0000e+00 4.1985e-02 -6.6867e-03 7.3133e-04 1.2110e-02 -6.0000e+00 2.4645e-02 -5.7358e-03 3.9571e-04 3.6094e-03 -6.0000e+00 1.0339e-02 5.4383e-03 -2.1192e-04 1.4481e-05 3.5422e-05 -6.0000e+00 6.9257e-04 7.2515e-03 0.0000e+00 10 0 0 10 0 0 66.37 15.06 0.20 0.00725 0.00566 677 138 2 8 0 73.610 15.00 15.06 19.09 20.56 20.87 29.1 837.23 -5320 -8989 -7139 -9777 -10635 -11019 -9020 -8124 -5044 -8372 -10005 -5391 -5671 -1630 -2417 -1324 -1970 49 -1564 1268 -1697 572 -1286 -1053 -2241 -1527 -2280 -1704 -2488 -186 -447 687 1058 -2893 -1546 -2305 -1101 -1429 -962 -1912 -1549 -1396 -1089 -667 -535 -769 -447 -494 -318 952 523 870 924 946 854 1142 497 787 855 1244 1423 1443 1536 594 73 605 30 874 446 -54 110 -375 212 26 164 284 -140 151 -266 -793 -621 -1892 -1299 -992 -718 -367 -242 200 242 582 717 750 1160 1016 409 577 560 -86 -365 -125 -373 193 74 -936 -1183 -787 -716 -57 -95 45 -175 200 67 259 589 659 293 -3 -483 -675 -241 23 -96 414 191 802 1435 563 328 194 35 48 99 -135 -210 -26 37 -242 -409 -54 -199 283 -94 -180 -143 -183 -184 -195 -177 -183 -123 -219 -270 -158 -204 -69 -121 -73 -118 3 -106 87 -121 40 -98 -87 -201 -141 -206 -144 -208 -16 -46 79 134 -372 -184 -289 -158 -252 -205 -471 -410 -386 -309 -189 -153 -221 -128 -143 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